南海边缘海多金属结核与大洋多金属结核对比

本文通过系统对比分析前人研究成果,研究了南海边缘海多金属结核的成矿特征,结果表明：南海边缘海结核的矿物组成与大洋结核相似,均主要由锰相矿物和铁相矿物组成,其中锰相矿物主要为水羟锰矿和钡镁锰矿,铁相矿物主要以无定型铁氧化/氢氧化物形式存在,另外南海边缘海结核中含有大量硅酸盐矿物,表明在南海结核成矿过程中受到大量的陆源碎屑矿物混杂;相对于大洋主要经济成矿区的多金属结核,南海边缘海多金属结核中主要的经济元素如Mn、Cu、Co、Ni和Zn质量分数较低,而亲陆源性元素如Fe、Ti、P、Nb、Pb、Rb、Sc、Ta、Sr、Th和REY（REE和Y）等质量分数较高;南海边缘海多金属结核的元素地球化学特征和REE配分模式显示其为水成成因,并呈现更低的Mn/Fe值;同时南海边缘海结核也具有较快的平均生长速率及较高的δCe正异常,表明其生长在更为氧化的海水环境。虽然较快的沉积物沉积速率和动荡的海水环境影响了南海边缘海结核的成矿,但大量陆源物质进入海洋也为南海边缘海结核提供了丰富的成矿物质来源,便于南海边缘海结核的快速生长成矿。南海边缘海结核富集有Fe、Ti、Pb、Rb、Th和REY等金属元素,同样可以作为极具潜力的海洋矿产资源。南海边缘海多金属结核具有其独特的地球化学特征,与大洋多金属结核存在着明显差异。     

基于决策树特征提取的支持向量机在岩性分类中的应用

由于支持向量机属于黑箱模型,因此在进行模型学习时无法直接对特征进行选择,而决策树模型在递归创建的过程中自身具有一定的特征选择能力。针对岩性分类问题,本文将决策树和支持向量机结合,通过决策树的建立,在考虑特征重要性的前提下,利用树节点的高度对特征进行提取,并将具有更高分类能力的特征送入支持向量机进行岩性分类。结果表明:通过决策树的特征提取,减少了支持向量机模型的输入特征,从而有效控制了模型的复杂度,使得模型更加稳定并具有更高的分类精度,测试集精度能够提升10%以上。     

济南市玉符河多水源回灌岩溶水水质风险评价

济南以泉城而闻名,保泉和供水安全问题是其面临的巨大挑战,利用多水源进行岩溶水回灌是解决问题的有效措施之一,但是补给水源水质相对岩溶水而言较差,回灌到地下可能存在一定健康和环境风险,需要对回灌系统的水质进行风险评价。本文对比地下水质量标准和地下水水质背景值,重点选择地表源水超标和劣于背景值的风险源监测指标,借鉴澳大利亚含水层补给管理指南,对玉符河多水源回灌岩溶含水层工程运行期的水质风险进行评价。2015年对黄河水、卧虎山水库两种水源多次回灌期间的源水、孔隙水和岩溶水的22项指标进行水质监测和指标分析,风险残余评价结果表明黄河水回灌补源期间,平均浊度的标准指数源水是1.4,孔隙水1.7,岩溶水0.93,硫酸盐平均含量的标准指数源水是0.93,孔隙水0.9,岩溶水0.73,氯离子虽没有超过地下水III类标准,但是在源水中含量是地下水含量的2倍多;卧虎山水库水回灌补源期间,平均浊度的标准指数源水是2.4,孔隙水1.1,岩溶水0.43,硫酸盐平均含量的标准指数在源水0.75,孔隙水0.84,岩溶水0.66,氨氮的平均含量的标准指数源水1.14,孔隙水1.47,岩溶水1.35。因此,浊度、硫酸盐和溶质在裂隙岩溶含水层迁移较快为两种水源玉符河回灌补源工程的共同高风险项和关键控制点。此外,黄河水补源还需注意盐度,卧虎山水库水补源还需控制营养物的污染风险。基于以上评价,还提出了限制回灌量占区域岩溶水资源量比例等建议。      

初探绿色GDP核算方法及实证分析 --以山西省大同市为例

传统GDP未将资源、环境要素纳入国民经济核算体系,不能准确地表现经济发展与资源、环境之间的相互关系。因此用传统GDP衡量一个国家经济发展程度,存在明显不足。绿色GDP是指国家或地区在扣除自然资源及环境污染损耗后新创造的真实国民财富的总量,它能较准确地反映一个国家或地区国民收入水平的状况。文章依据狭义绿色GDP涵义,以山西省大同市为例,结合当地生态资源环境现状,构建资源环境账户虚数指标体系,探讨了绿色GDP的核算方法,并估算了该市2002年的绿色GDP。结果表明：2002年大同市的自然资源损耗为63.86亿元,占GDP的29.29%;环境污染损耗22.18亿元,占GDP的10.18%;绿色GDP为131.33亿元,仅占当年GDP的60.24%,说明该地区经济发展中资源与环境问题十分突出,亟待解决。建议科学、适度、合理地开发利用各类资源,树立市场经济的资源价值观;严格控制污染物排放,加强环境保护治理。     

内蒙古黄旗海不同粒级湖泊沉积物Rb、Sr组成与环境变化

Based on the geochemical elements Rb and Sr in sediments with three different grain size fractions from profile H3 on the northern lacustrine bottomland 13 m above the Huangqihai Lake surface in 1986,the paper investigates the record of palaeolake stand state, sedimentary environmental evolution,and winter monsoon change.First,these samples are separated into three different grain size fractions,i.e.,total sediments,77-20μm and〈20μm. Second,the chemical elements-Rb and Sr-of the grain size separation were tested and analyzed systematically in this paper.Then the elements compositions of these samples are measured using VP-320 mode fluorescence spectrum instrument,respectively.The magnetic susceptibility of these samples is measured using Kappabridge KLY-3 mode instrument made in Czech AGICO Company.The results showed the elements and the ratios varied regularly with the grain size.But the ratio of Rb/Sr in the sediments〈20μm correlates positively with the magnetic susceptibility of these samples.Therefore,the ratio of Rb/Sr in the fraction〈20 μm from the lake sediments reflected the strengthening of the weathering in the deposition sites.It is a good indicator of the summer monsoon-induced weathering and pedogenesis fluctuations and can be used to reconstruct the conditions of the paleoclimate and paleoenvironment.     

西苕溪流域不同土地类型下氮元素输移过程

以西苕溪流域为研究对象,选择最有代表性的5种土地类型,模拟天然大暴雨,通过3次重复实验研究不同形态氮素随暴雨径流及径流沉积物的迁移过程,估算氮素在流域内不同土地利用/土地覆被条件下的损失率。研究结果表明,在相同的降雨条件下,氮素的流失速率和流失量随土地利用/土地覆被类型的不同表现出明显差异,地表径流水相总氮的流失量桑林最大,水田最小。水相不同形态的氮素流失量亦有所不同,悬浮颗粒态氮占地表径流水相总氮的70 %~90 %,水相溶解态氮的流失量以松林为最高,竹林、桑林和水田接近而且较低,不同类型的水相溶解态氮也随土地利用类型的不同表现出各自的特征。各土地类型单位面积、表层10 cm土壤氮素流失高达4.66~9.40 g·m-2,其中随径流沉积物相迁移的氮素占绝大部分(90 % 以上)。估算出的各土地利用类型总氮流失速率,地表径流水相为2.68~14.48 mg·m-2·min-1,径流沉积物相高达100.01~172.67 mg·m-2·min-1。     

Implications of diverse sedimentation patterns in Hala Lake, Qinghai Province, China for reconstructing Late Quaternary climate

Hala Lake is located in the Qilian Mountains, Qinghai Province, China, at 4,078?m a.s.l. Its sediments contain an archive of climate and hydrologic changes during the Late Quaternary, as it is located close to the area influenced by the East-Asian summer monsoon and westerly-driven air masses. Sedimentation patterns and depositional conditions within the lake were investigated using eight sediment cores from different water depths, and this information was used to evaluate the feasibility of using a single core to reconstruct past climate and hydrological conditions. Long core H7, from the center of the lake (65?m water depth) and core H8 from a western, near-shore location (20?m water depth), were compared in detail using sediment composition and geochemical data (X-ray fluorescence, loss-on-ignition and CNS analysis). Age models were constructed using 17 AMS radiocarbon dates and indicate negligible reservoir error for sediments from the lake center and?~1,000?year errors for the near-shore sediment core. Cores H1?CH5 and HHLS21-1 revealed a sediment succession from sand and silty clay to laminated clay on the southern side of the lake. Undisturbed, finely laminated sediments were found at water depths???15?m. Core H5 (2.5?m long), from 31?m water depth, yielded abundant green algal mats mixed with clayey lake deposits and was difficult to interpret. Algae occurred between 25 and 32?m water depth and influenced the dissolved oxygen content of the stratified lake. Comparison of cores H7 and H8 yielded prominent mismatches for different time periods, which may, in part, be attributed to internal lacustrine processes, independent of climate influence. We thus conclude that data from a single sediment core may lead to different climate inferences. Common shifts among proxy data, however, showed that major climate shifts, of regional to global significance, can be tracked and allow reconstruction of lake level changes over the last 24,000?years. Results indicate advance of glaciers into the lake basin during the LGM, at which time the lake experienced lowest levels, 25?C50?m below present stage. Stepwise refilling began at ca. 16 kyr BP and reached the ?25?m level during the B?lling/Aller?d warm phase, ca. 13.5 kyr BP. A desiccation episode falls within the Younger Dryas, followed by a substantial lake level rise during the first millennium of the Holocene, a result of climate warming, which promoted glacier melt. By ca. 7.6 kyr BP, the lake reached a stable high stand similar to the present level, which persisted until ca. 6 kyr BP. Disturbed sediments in core H7 indicate a single mass flow that was most likely triggered by a major seismic event?~8.5 kyr BP. Subsequent lake development remains unclear as a consequence of data mismatches, but may indicate a general trend to deteriorating conditions and lake level lowstands at ca. 5.0?C4.2, 2.0 and 0.5 kyr BP.     

基于脱钩模型的煤炭城市可持续发展动态分析——以徐州市为例

促进经济与环境协调是煤炭城市可持续发展的关键和核心。采用物质流分析、脱钩分析和分解分析等方法,深入分析了1995—2007年徐州市经济增长与资源环境之间的脱钩类型、可持续状态及驱动因素。结果表明:研究期内徐州市DMI和DPO的年均增长率分别为2.74%和0.91%,而GDP年均增长率为12.62%,二者之间呈较为明显的正相关关系,而物质代谢效率的提升又使其发展方式呈现向资源节约型、环境友好型发展模式转型的趋势;资源投入、废物排放与经济增长之间均出现弱脱钩现象,表明徐州经济系统正处于显著的弱可持续发展态势;经济规模扩大和技术效应抑制作用减弱是引起煤炭城市资源环境约束性增强、可持续发展降低的主要驱动因素。     

集中采灌条件下碳酸盐岩热储群井示踪试验

地热回灌是实现地热资源可持续开发的有力措施,在世界各国已获得广泛应用,在地热资源的保护、减少资源浪费、延长地热井寿命以及减少环境污染等方面具有重要意义.天津是我国开展地热回灌比较成熟的地区之一,截至2019年底,天津市基岩裂隙型热储回灌率已达79.61％.大规模集中采灌条件下热储层渗流场的变化以及是否会影响热储温度已成为热储系统研究的前沿课题.本文以天津市东丽湖地区为例,选取1,5-萘磺酸钠作为示踪剂,在2018～2019年供暖期集中采灌期间开展了群井示踪试验,结果显示,供暖期内地热井开采量(或回灌量)、水温没有明显变化,水位除受正常采灌影响外没有明显变化,热储系统基本处于稳定状态;试验中示踪剂回收率极低,开采井和回灌井之间水力联系较差,有限的优势通道中的最大流速为448.42 m/d,优势通道的方向主要集中于北东向,与区内主要控热断裂沧东断裂及其次生断裂的发育方向一致;在现状开发利用模式下,不会造成该热储层温度的显著变化.这些认识对于指导北方古潜山碳酸盐岩热储的科学开发利用具有一定的现实意义.     

页岩油的储层特征及其影响因素分析——以沾化凹陷罗家地区为例

为查明沾化凹陷罗家地区古近系沙河街组三段下亚段页岩油的储层特征及其影响要素,通过岩心、薄片、扫描电镜等多种资料综合分析,开展页岩油储层岩性、储层空间类型、影响因素及页岩油储层评价参数的研究。结果表明: 综合矿物成分和沉积构造2个因素,可将研究区页岩油储层岩性划分为7种类型; 不同岩性储集空间发育有较大差异,纹层状泥质灰岩和纹层状灰岩储集空间最为发育,纹层状灰质泥岩储集空间较发育,块状泥岩储集空间发育一般,块状泥质灰岩、块状灰质泥岩及纹层状粉砂岩储集空间发育较差; 研究区页岩油储层储集空间的发育主要受矿物成分、沉积构造、有机质含量和赋存方式以及成岩作用的影响。以此为基础,选取方解石含量、纹层状构造、总有机碳(Total Organic Carbon,TOC)含量、镜质体反射率(R_o)及孔隙度作为页岩油储层评价参数,将沾化凹陷罗家地区页岩油储层分为优质储层、有利储层和不利储层3类。