Limitations of Monitoring Wells for the Detection and Quantification of Petroleum Products in Soils and Aquifers

Theoretical analysis and laboratory column experiments were carried out to investigate the conditions required for petroleum products (oil) to flow into a well installed through a sandy porous medium contaminated with the oil. The results indicated that oil would flow into a well only after a layer of "free oil" is formed in the adjacent porous medium. Because significant quantities of oil could be stored in the porous medium under the influence of capillary suction prior to the formation of the zone of free oil, the presence of oil in a well would indicate an advanced stage of oil contamination of the subsurface. While monitoring wells could be used to delineate the extent of the free-oil plume and the plume of dissolved petroleum constituents, they are not useful for delineating the extent of capillary held oil.
The experimental results also indicated that the ratio of the oil-layer thickness in the well to that in the porous medium is not a constant as is sometimes assumed in practice. Further, estimates of the oil thickness in the medium based on the oil thickness in wells and on capillary properties measured in the laboratory were sensitive to the values of the parameters used in these estimates. The measured thickness of the oil layer in a monitoring well alone may not yield reliable estimates of the amount of oil in the subsurface, and assuming that the oil-thickness ratio is a constant can lead to inadequate site assessments and inappropriate remedial plans.     

Global spectra of energy and enstrophy and their fluxes during July 1979

Transient and stationary spectra of kinetic energy (KE), available potential energy (APE) and enstrophy (EN), and their spectral fluxes as a function of the two-dimensional wavenumbern were computed for July 1979. Triangular truncation at zonal wavenumber 42 was used for computation. The slopes of various spectra in the wavenumber range 14≤n≤25 were obtained by fitting a straight line in log-log scale by the least square method. The transientKE, APE andEN spectra in the lower (upper) troposphere had slopes −2·21 (−2·30), −2·65 (−2·64) and −0·36 (−0·46), respectively. The effect of stationary and divergent motion on the slope values was investigated. The possible correlation between the slope and percentage of transient component in the combined energy and enstrophy was examined to identify the transient motion of the atmosphere with the two-dimensional homogeneous isotropic turbulence. The vertically averaged slope of kinetic energy and enstrophy in the lower (upper) troposphere was close to the value at 700 (200) hPa level. The spectral fluxes of kinetic energy and enstrophy in the wavenumber range 14≤n≤25 satisfied, to a very rough approximation, the criteria of inertial subrange. The stationary fluxes were small. The estimated stationary-transient component of flux was larger, comparable and less than the corresponding transient flux of APE, KE and EN. Representative levels for computation of energy and enstrophy spectra and their fluxes in the lower and upper troposphere were identified.     

Magnetic fabrics of the Bloodgood Canyon and Shelley Peak Tuffs,southwestern New Mexico: implications for emplacement and alteration processes

Anisotropy of magnetic susceptibility (AMS) of the middle Tertiary Bloodgood Canyon and Shelley Peak Tuffs of the Mogollon-Datil volcanic field has been used to (1) evaluate the ability of AMS to constrain flow lineations in low-susceptibility ash-flow tuffs; (2) establish a correlation between magnetic fabric, magnetic mineralogy, tuff facies, and characteristics of the depositional setting; and (3) constrain source locations of the tuffs. The tuffs are associated with the overlapping Bursum caldera and Gila Cliff Dwellings basin. The high-silica Bloodgood Canyon Tuff fills the Gila Cliff Dwellings basin and occurs as thin outcrops outside of the basin. The older Shelley Peak Tuff occurs as thin outcrops both along the boundary between the two structures, and outside of the complex. AMS data were collected from 16 sites of Bloodgood Canyon Tuff basin fill, 19 sites of Bloodgood Canyon Tuff outflow, and 11 sites of Shelley Peak Tuff. Sites were classified on the basis of within-site clustering of orientations of principal susceptibility axes, based on the categories of Knight et al. (1986). Most microscopically visible oxide minerals in the Bloodgood Canyon Tuff outflow and basin fill, and in the Shelley Peak Tuff are members of the hematite-ilmenite solid solution series. However, IRM acquisition data indicate that Bloodgood Canyon Tuff basin fill and Shelley Peak Tuff have magnetic mineralogy dominated by single- or pseudo-single-domain magnetite, and that the magnetic mineralogy of the Bloodgood Canyon Tuff outflow is dominated by hematite. Hematite in Bloodgood Canyon Tuff outflow is likely to be the result of deuteric and/or low-temperature alteration of magnetite and iron silicate minerals. Bulk magnetic susceptibility is higher in magnetite-dominated ash-flow tuff (Bloodgood Canyon Tuff basin fill and Shelley Peak Tuff) than it is in hematite-dominated ash-flow tuff (Bloodgood Canyon Tuff outflow). Bloodgood Canyon Tuff outflow has the highest total anisotropy (H) of the three units, followed by Shelley Peak Tuff and Bloodgood Canyon Tuff basin fill. All three ash-flow tuffs are genearlly characterized by oblate susceptibility ellipsoids, with those of the Bloodgood Canyon Tuff basin fill nearest to spherical. At high values of total anisotropy, Shelley Peak Tuff susceptibility ellipsoids attain a prolate shape; those of Bloodgood Canyon Tuff outflow attain an increasingly oblate shape. Three factors may influence differences in total anisotropy and susceptibility ellipsoid shape: (1) ash which travelled the greatest distance before deposition may show the best development of magnetic fabric, particularly of magnetic lineation; (2) deposition of ash in a closed basin may inhibit laminar flow throughout the sheet and the resulting development of flow textures; and (3) replacement of magnetite and iron silicates preferentially oriented within the foliation plane by hematite with strong crystalline anisotropy may enhance the magnetic susceptibility within that plane. Scatter in AMS axis orientation within sites may result from: (1) greater orientation inaccuracy in block-sampled than in fielddrilled samples; (2) rheomorphism; and (3) low accuracy of AMS measurement in low-susceptibility ashflow tuffs. Evaluation of flow lineation based on AMS of sites with well-clustered K ₁ axes indicates that (1) Bloodgood Canyon Tuff basin fill flowed along a generally northwest-southeast azimuth; (2) Shelley Peak Tuff located on the boundary of the Bursum caldera and the Gila Cliff Dwellings basin flowed along a nearly east-west azimuth; and (3) Bloodgood Canyon Tuff outflow sites have K ₁ susceptibility axes generally radial to the Bursum-Gila Cliff Dwellings complex, but within-site scatter of K ₁ orientations is generally too large to draw conclusions about flow lineation orientation. Limited petrographic work on pilot thin sections adds flow direction information to AMS-derived flow lineation information.     

Baroclinic energetics and zonal plane distribution of monsoon disturbances

The adiabatic, quasi-geostraphic, 25-layer, numerical, linear model with Ekman boundary layer friction is utilised to perform the baroclinic stability analysis of the mean monsoon zonal wind profile. It is shown thec _i is a function of the resultant wavenumber alone. This relation is able to explain the effects of the lateral walls on the unstable waves.The energetics and zonal plane distribution of the short and long preferred viscous waves are computed. The upward motion of the short wave together with the warm (cold) core lies to the west of the surface trough position above (below) 850 mb. Further, it is shown that the main source of kinetic energy for the wave lies in the middle layer (850–700 mb) which is transported to the lower and upper layers. Computed is found to be in good agreement with observed values.     

Visual interpretation of F.C.C. satellite data for channel migration and water logging conditions along Ghaghra and Terhi rivers in part of district Gonda and Bahraich,U.P.

The conventional visual interpretation of landsat Imagery is potentially the most useful remote sensing tool for the study of channel migration & water logging conditions at different time spans; which were earlier not easy due to non availability of suitable evidences. The present study brings out, in exact terms & the extent of the utility of the false colour and black and white landsat data. The application of the false colour scanning method is also useful remote sensing tool for the study of direct & indirect hydrogeological regime by visual interpretation technique. The spectrum are favourable for detection of surface phenomenon, which is associated with the subsurface ground water environment. An area of about 3,500 Sq.Km. of U.P. along left bank of Ghaghra river and right bank of Terhi rivers have been taken for the study. The paper was designed to evaluate the fluvial action and ground water environments with the help of repetitive landsat data in ten years. The fluvial action of Ghaghra and Terhi rivers have been mainly contributing to the development of hydrogeomorphological units which have given exact references regarding fluctuation in hydrogeomorphological units and water logging with hydrological response of the ground water environment, by using landsat data of 1975 & 1984. Further the direct relationship between remote sensing measurement and physical properties of hydrogeological environments is brought out in the maps.     

Hysteresis‐based flood‐wave analysis using the concept of strain

Hysteresis represents a loop in a rating curve and is a phenomenon which closely resembles that occurring in stress–strain curves used for studying the elastic properties of solid substances in engineering mechanics. Earlier hysteresis‐based studies used for defining floodwave propagation in open channels have qualitatively shown that hysteresis is an index of energy loss during floodwave propagation. Using the concept of elasticity, this paper introduces a new term called flow strain (defined as the ratio of change in discharge to the initial discharge) for investigating hysteresis. The usefulness of this new term is evaluated with use of four dam‐break studies. The study reveals that:

• 1 flow strain is a function of three wave speeds, Seddon speed, Lagrange speed, and elastic speed;
• 2 a single linear reservoir concept frequently used in flood routing is a specific variant of the Seddon speed formula;
• 3 the non‐linear storage–discharge relationship, widely used in overland flow modelling, is a variant of the kinematic wave representation;
• 4 the discharge ordinates on the recession part of a hydrograph follow a simple first‐order autoregressive form;
• 5 the hysteresis, phase difference and logarithmic decrement all define attenuation and are indices of energy loss during floodwave propagation.

Copyright © 2001 John Wiley & Sons, Ltd.     

Evaluation of ground water potential in the environs of Jhansi city,Uttar Pradesh using hydrogeomorphological assessment by satellite remote sensing technique

An attempt has been made to delineate different hydrogeomorphological units in and around the immediate environs of Jhansi city with a view to attempt a correlation between the well yields and hydrogeomorphic units using satellite remote sensing technique. In general, a positive correlation is observed between the geomorphic units and the borewell yields with overlapping yields at the margin. The pediment residual hill complex is observed to provide wells with discharges ranging from 100 gallons per hour (gph) to 5000 gph, while the wells drilled in shallow weathered, buried pediplain has yields in the range of 2000 to 10000 gph moderately weathered, buried pediplain has discharges in the range of 8000 to 12000 gph, and deeply weathered, buried pediplain has discharges in excess of 12000 gph.     

Thermal stresses in an elastic layer due to an instantaneous plane heat source

Summary The solution of the title problem has been obtained for stress free boundaries of the layer.     

Scale invariant theory for Bianchi Type VIII and IX space-times with perfect fluid

In this paper we have taken an attempt to study the feasibility of scale invariant theory (Wesson, 1981a,b) in Bianchi type VIII and IX space-times with a time dependent gauge function (Dirac Gauge i.e. βα )and a matter field in the form of a perfect fluid. It is found that Bianchi type VIII (δ=1) space-time is feasible in this theory whereas Bianchi type IX (δ=-1) space-time is not feasible. In this feasible case a radiating model is constructed and its physical behaviour is discussed. This revised version was published online in July 2006 with corrections to the Cover Date.