Removal of Cu(Ⅱ) from Wastewater Using Acidified Sewage Sludge Ash

Sewage sludge ash (SSA), the waste generated in sewage sludge incineration, was obtained from Wuhan Sewage Treatment Plant and used as a low-cost sorbent for removing Cu(Ⅱ) from wastewaters. The sorbent was first modified with 5 % sulfuric acid to increase its sorption capacity. The specific surface area, porosity, cation-exchange capacity (CEC) and pHZPC of the sorbent were measured. Batch experiments were made to study the effect of contact time, solution pH value and temperature on sorption. Both Langmuir and Freundlich models well described the Cu(Ⅱ) sorption process, with correlation coefficient (R2) values of 0.993 4 and 0.989 9 respectively. And the sorption process follows the Lagergren first order kinetic model. The equilibrium sorption capacity of acidified SSA to Cu(Ⅱ) is estimated to be 7.78 mg/g under optimal conditions.     

Geochronology and petrogenesis of the post-orogenic Cu–Ni sulfide-bearing mafic–ultramafic complexes in Jilin Province, NE China

Northeastern (NE) China is a well-documented example of a collisional zone characterized by widespread post-orogenic granites and mafic–ultramafic complexes. Based on a study of the Hongqiling and Piaohechuan Cu–Ni sulfide-bearing mafic–ultramafic complexes in central Jilin province, we present geological, petrological, geochemical and geochronological data which indicates their post-orogenic origin.The Hongqiling complex comprises pyroxenite, olivine websterite, lherzolite, gabbro and leucogabbro. Zircon U–Pb SHRIMP analyses on a leucogabbro of the Hongqiling complex yield a weighted mean ²⁰⁶Pb–²³⁸U age of 216±5 Ma. The Piaohechuan complex is composed of gabbro, pyroxenite and dolerite, exposed as dikes. A plagioclase-bearing pyroxenite has a U–Pb zircon weighted mean ²⁰⁶Pb–²³⁸U age of 217±3 Ma, identical to that of the Hongqiling complex. These ages are coeval with the emplacement of A-type granites in the area, but slightly younger than the regional metamorphism (240 Ma) and syn-orogenic granitic magmatism (246±4 Ma). This suggests that these mafic–ultramafic complexes are post-orogenic in origin. The age data also indicated a short period of lithospheric stabilization of about 30 Ma after cessation of orogenic activity.Geochemical investigation indicates that the primary mafic magma was a lithospheric mantle-derived basalt resulting from the upwelling of asthenosphere due to lithospheric delamination during post-orogenic processes. The magmatic source was contaminated by a small amount of crustal material, and subsequent crystal fractionation resulted in the Cu–Ni mineralization.The widespread occurrence of mafic–ultramafic complexes in the Xing'an–Mongolian Orogenic Belt of NE China and in the Altay–Tianshan–Junggar Orogenic Belt of Northern Xinjiang indicates that mafic intrusions are an important magmatic suite that evolved during post-orogenic processes. Portions of this mafic magma could have underplated the lower crust, and served as the heat source for associated late-stage granitic magmas.     

Continental crustal growth and the supercontinental cycle: evidence from the Central Asian Orogenic Belt

Studies of supercontinental cycle are mainly concentrated on the assembly, breakup and dispersal of supercontinents, and studies of continental crustal growth largely on the growth and loss (recycling) of the crust. These two problems have long been studied separately from each other. The Paleozoic–Mesozoic granites in the Central Asian Orogenic Belt have commonly positive Nd values, implying large-scale continental crustal growth in the Phanerozoic. They coincided temporally and spatially with the Phanerozoic Pangea supercontinental cycle, and overlapped in space with the P-wave high-V anomalies and calculated positions of subducted slabs for the last 180 Ma, all this suggests that the Phanerozoic Laurasia supercontinental assembly was accompanied by large-scale continental crustal growth in central Asia. Based on these observations, this paper proposes that there may be close and original correlations between a supercontinental cycle, continental crustal growth and catastrophic slab avalanches in the mantle. In this model we suggest that rapid continental crustal growth occurred during supercontinent assembly, whereas during supercontinental breakup and dispersal new additions of the crust were balanced by losses, resulting in a steady state system. Supercontinental cycle and continental crustal growth are both governed by changing patterns of mantle convection.     

Pelecinid wasps (Insecta, Hymenoptera, Proctotrupoidea) from the Cretaceous of Russia and Mongolia

Thirteen new species referable to four genera, of which one is new, from the Cretaceous of Russia and Mongolia are established herein and assigned to the family Pelecinidae. Among the four genera, Protopelecinus gen. nov., including four new species, is referred to the subfamily Pelecininae, while Iscopinus Kozlov, including three new species, Eopelecinus Zhang, Rasnitsyn and Zhang, including five new species, and Scorpiopelecinus laetus sp. nov. are assigned to the subfamily Iscopininae. Of these new taxa, eight, namely Protopelecinus regularis, P. furtivus, Iscopinus simplex, ?I. suspectus, Eopelecinus exquisitus, E. scorpioideus, E. rudis and Scorpiopelecinus laetus, are from the Lower Cretaceous Zaza Formation of Baissa, Transbaikalia, Russia; two, E. minutus and E. fragilis, are from the basal Lower Cretaceous Tsagan-Tsab Formation of Khutel-Khara, Mongolia; two, P. dubius and P. deformis, are from the Lower Cretaceous (Aptian?) of Bon Tsagan, Mongolia; and one, I. separatus, is from the Upper Cretaceous (Cenomanian) Ola Formation of Obeshchayushchiy, Russia. A key to fossil pelecinid wasps is provided and a morphological analysis shows that the Pelecinidae might be paraphyletic with respect to the Proctotrupidae. The Chinese insect fauna from both the Yixian and Laiyang formations is dominated by Eopelecinus and Sinopelecinus whereas the Siberian + Mongolian fauna from the Zaza and Tsagan-Tsab formations is dominated by Eopelecinus and Iscopinus. Hence, Eopelecinus is common to both. The differences between the two faunas are likely to be the result of geographical variation in populations.     

Damage Evaluation of Agro-meteorological Hazards in the Maize-Growing Region of Songliao Plain,China: Case Study of Lishu County of Jilin Province

Agro-meteorological hazards such as drought, waterlogging and cool summer occur with very high frequency and affect maize production and social-economic development in the maize-growing region of Songliao Plain, China. Moreover, both the frequency of these hazards and loss from them are considered to be increasing with global warming. The purpose of this paper is to quantitatively analyze the relationships between the fluctuation of maize yield and drought, waterlogging and cool summer, and to evaluate the consequences of these hazards in the maize-growing area of Songliao Plain, taking Lishu county as a case study area based on GIS (Geographic Information System). Crop yield-climate analysis and regression analysis were employed to analyze and quantify relationships between the fluctuation of maize yield and drought, waterlogging and cool summer, and to evaluate the consequences of these hazards. The parameters and model of damage evaluation were presented using weighted comprehensive analysis, and the degree of damage of drought, waterlogging and cool summer to maize production was comprehensively evaluated and regionalized. It is shown that from 1949 to 1990, the negative value years of the fluctuation of maize yield due to meteorological hazards accounted for 55% of seasons, of which 14% was caused by drought, 30% by waterlogging, 4% by cool summer and drought, 9% by cool summer and waterlogging, 13% by drought and waterlogging, 30% by drought, waterlogging and cool summer. Studies on the instability and spatial variation of the fluctuations in maize yield in Lishu county showed that the middle plains are stable areas to climatic influence, while southeastern hills and low mountains, the low lands of the plains along the East Liao River and the western plain are unstable areas in terms of areas in maize yield. The synthetic index of the degree of damage to maize of drought, waterlogging and cool summer showed a strong positive correlation with the ratio of the amount damaged to the normal yield of maize. This suggests that this index can be used to evaluate such damage. The degree of damage of drought, waterlogging and cool summer to maize in Lishu county shows the regional characteristics, which increase gradually from the center to the west and east, this being almost identical with the spatial distribution of the fluctuation of maize yield due to these hazards. This study can be expected to provide the basis for developing strategies to mitigate agro-meteorological hazards and reducing the losses from them, and adjust the medium and long-term distribution of agricultural activities so as to adapt to environmental changes.     

“Three-Component” Digital Prospecting Method：A New Approach for Mineral Resources Quantitative Prediction and Assessment

“Three-component” method consists of three clase-connected aspects: geological anomaly,diversity of mineralization and mineral deposit spectrum. All these three concepts are not new separately, but it is a new approach to combine these three aspects in one single concept for quantitative mineral resources prediction and assessment and it is also the first time to conduct a more detailed study in each aspect. Investigation and clarification of geological anomalies, diversity of mineralization and spectrum of mineral deposits are realized by digitization and quantification of ore forming controlling factors, oreexisting symbols or marks, characteristics of mineralization and regulation of ore-genesis and laws of distribution. These procedures lead to construction of a “digital model“ for mineral resources prediction andassessment.     

GIS Spatial-Temporal Modeling of Water Systems in Greater Toronto Area, Canada

Modeling landscape with high-resolution digital elevation model (DEM) in a geographic information system can provide essential morphological and structural information for modeling surface processes such as geomorphologic process and water systems. This paper introduces several DEM-based spatial analysis processes applied to characterize spatial distribution and their interactions of ground and surface water systems in the Greater Toronto Area (GTA), Canada. The stream networks and drainage basin systems were derived from the DEM with 30 m resolution and the regularities of the surface stream and drainage patterns were modeled from a statistical/multifractal point of view. Together with the elevation and slope of topography, other attributes defmed from modeling the stream system, and drainage networks were used to associate geological, hydrological and topographical features to water flow in river systems and the spatial locations of artesian aquifers in the study area. Stream flow data derived from daily flow measurements recorded at river gauging stations for multi-year period were decomposed into “drainage-area dependent“ and “drainage-area independent“ flow components by two-step “frequency“ and “spatial“ analysis processes. The latter component was further demonstrated to relate most likely to the ground water discharge. An independent analysis was conducted to model the distribution of aquifers with information derived from the records of water wells. The focus was given on quantification of the likelihood of ground water discharge to river and ponds through flowing wells, springs and seepages. It has been shown that the Oak Ridges Moraine (ORM) is a unique glacial deposit that serves as a recharge layer and that the aquifers in the ORM underlain by Hilton Tills and later deposits exposed near the steep slope zone of the ridges of ORM provide significant discharge to the surface water systems (river flow and ponds) through flowing wells, springs and seepages. Various statistics (cross- and auto-correlation coefficients, fractal R/S exponent) were used in conjunction with GIS to demonstrate the influence of land types, topography and geometry of drainage basins on short- and long-term persistence of river flows as well as responding time to precipitation events. The current study has provided not only insight in understanding the interaction of water systems in the GTA, but also a base for further establishment of an on-line GIS system for predicting spatial-temporal changes of river flow and groundwater level in the GTA.     

Neodymium isotopic variations in Northwest Pacific waters

Four vertical profiles of the concentration and isotopic composition of Nd in seawater were obtained in the western North Pacific. Two profiles from the Kuroshio Current regime showed congruently that although the Nd concentration increases gradually with depth, its isotopic composition varies significantly with depth depending upon the water mass occupying the water column. The high-salinity Kuroshio waters originating from the North Pacific Tropical Water (NPTW) carry the least radiogenic Nd (?_Nd = −7.4 to −8.7) to this region at ∼250 m from the western margin continental shelves, most likely from the East China Sea. The Nd isotopic compositions in the North Pacific Intermediate Water (NPIW) that occurs at 600 to 1000 m in the subtropical region are fairly uniform at ?_Nd = −3.7. The profile data from the ∼38° to 40°N Kuroshio/Oyashio mixed water region off Sanriku of Honshu, Japan, also suggest that the newest NPIW with ?_Nd = −3.2 is formed there by the mixing of various source waters, and the radiogenic component of Nd is derived mainly from the Oyashio waters.In the Pacific Deep Water (PDW) below ∼1000 m, the Nd isotopic composition is neither vertically nor horizontally homogeneous, suggesting that it serves as a useful tracer for sluggish deep water circulation as well. Two profiles from the Izu-Ogasawara Trench showed a minimum ?_Nd value at ∼2000 m, suggesting that there exists a horizontal advective flow in the vicinity of Honshu, Japan. There is some evidence from other chemical properties to support this observation. The waters below 4000 m including those within the trench in the subtropical region have ?_Nd values of around −5, suggesting that the deep waters are fed from the south along the western boundary, ultimately from the Antarctic Bottom Water (AABW) in the South Pacific. This extends up to ∼40°N along the Japanese Islands. In the subarctic region (>∼42°N), the waters have more radiogenic Nd with ?_Nd > −4.0 throughout the water column, presumably due to the supply of Nd by weathering in such igneous provinces as the Kuril-Kamchatska-Aleutian Island chain. The lateral inhomogeneity of the Nd isotopic composition in PDW suggests that there may be different circulation and mixing regimes in the North Pacific Basin.     

Empirical garnet-muscovite-plagioclase-quartz geobarometry in medium- to high-grade metapelites

Based on the net transfer reactions among garnet, muscovite, plagioclase, and quartz (for both Mg and Fe end-member models), the garnet-muscovite-plagioclase-quartz (GMPQ) geobarometry was empirically calibrated under the physical conditions of P=1.0-11.4 kbar and T=505-745 °C for 128 natural metapelitic rock samples collected from the literature. The input temperatures and pressures were simultaneously determined by the garnet-biotite thermometer and the garnet-aluminosilicate-plagioclase-quartz (GASP) barometer. The GMPQ calibrations adopted the same asymmetric quaternary solid solution model of garnet and the same Al-avoidance asymmetric ternary model of plagioclase as the calibrations of the garnet-biotite geothermometer and the GASP geobarometer. A symmetric Fe-Mg-Al^VI ternary solid solution model of muscovite was adopted, and the Margules parameters of muscovite were obtained through regression. The Mg and Fe model reactions, along with the assumption of whether the ferric iron content in muscovite is 0% or 50%, resulted in four GMPQ barometry formulae. The GMPQ barometry formulae reproduce the input GASP pressures well within ±1.0 kbar (mostly within ±0.5 kbar). For both aluminosilicate-bearing and aluminosilicate-absent samples, the GMPQ barometry formulae yield identical pressures for every sample, whether the sample was included or not in calibrating the barometers. For each of the Mg or Fe model reaction, the formulae gave identical pressures within ±40 bars. The random error of the GMPQ barometry may be expected as ±1.4 kbar. The dP/dT slopes of these GMPQ formulae are close to that of the GASP barometer in the P-T space. Applications of the GMPQ barometry to aluminosilicate-absent metapelites within a limited geographic area without postmetamorphic structural discontinuity generally show no pressure difference. It may be concluded that the GMPQ barometry formulae derived in this work may be used as practical tools for metamorphic pelites under the conditions of 505-745 °C and 1-11.4 kbar, in the composition range of X_gros>3% in garnet and X_An>17% in plagioclase.