Behavior of uranium under conditions of interaction of rocks and ores with subsurface water

The behavior of uranium during interaction of subsurface water with crystalline rocks and uranium ores is considered in connection with the problem of safe underground insulation of spent nuclear fuel (SNF). Since subsurface water interacts with crystalline rocks formed at a high temperature, the mineral composition of these rocks and uranium species therein are thermodynamically unstable. Therefore, reactions directed toward the establishment of equilibrium proceed in the water-rock system. At great depths that are characterized by hindered water exchange, where subsurface water acquires near-neutral and reducing properties, the interaction is extremely sluggish and is expressed in the formation of micro- and nanoparticles of secondary minerals. Under such conditions, the slow diffusion redistribution of uranium with enrichment in absorbed forms relative to all other uranium species is realized as well. The products of secondary alteration of Fe- and Ti-bearing minerals serve as the main sorbents of uranium. The rate of alteration of minerals and conversion of uranium species into absorbed forms is slow, and the results of these processes are insignificant, so that the rocks and uranium species therein may be regarded as unaltered. Under reducing conditions, subsurface water is always saturated with uranium. Whether water interacts with rock or uranium ore, the equilibrium uranium concentration in water is only ≤10^?8 mol/l. Uraninite ore under such conditions always remains stable irrespective of its age. The stability conditions of uranium ore are quite suitable for safe insulation of SNF, which consists of 95% uraninite (UO₂) and is a confinement matrix for all other radionuclides. The disposal of SNF in massifs of crystalline rocks at depths below 500 m, where reducing conditions are predominant, is a reliable guarantee of high SNF stability. Under oxidizing conditions of the upper hydrodynamic zone, the rate of interaction of rocks with subsurface water increases by orders of magnitude and subsurface water is commonly undersaturated with uranium. Uranium absorbed by secondary minerals, particularly by iron hydroxides and leucoxene, is its single stable species under oxidizing conditions. The impact of oxygen-bearing water leads to destruction of uranium ore. This process is realized simultaneously at different hypsometric levels even if the permeability of the medium is variable in both the lateral and vertical directions. As a result, intervals containing uranyl minerals and relics of primary uranium ore are combined in ore-bearing zones with intervals of completely dissolved uranium minerals. A wide halo of elevated uranium contents caused by sorption is always retained at the location of uranium ore entirely destroyed by weathering. Uranium ore commonly finds itself in the aeration zone due to technogenic subsidence of the groundwater table caused by open-pit mining or pumping out of water from underground mines. The capillary and film waters that interact with rocks and ores in this zone are supplemented by free water filtering along fractures when rain falls or snow is thawing. The interaction of uranium ore with capillary water results in oxidation of uraninite, accompanied by loosening of the mineral surface, formation of microfractures, and an increase in solubility with enrichment of capillary water in uranium up to 10^?4 mol/l. Secondary U(VI) minerals, first of all, uranyl hydroxides and silicates, replace uraninite, and uranium undergoes local diffusion redistribution with its sorption by secondary minerals of host rocks. The influx of free water facilitates the complete dissolution of primary and secondary uranium minerals, the removal of uranium at the sites of groundwater discharge, and its redeposition under reducing conditions at a greater depth. It is evident that the conditions of the upper hydrodynamic zone and the aeration zone are unfit for long-term insulation of SNF and high-level wastes because, after the failure of containers, the leakage of radionuclides into the environment becomes inevitable.     

带深桩基础高层建筑结构的地震动输入问题

带深桩基础高层建筑结构的地震反应分析通常按刚性地基假定选择地震动输入,其合理性一直受到工程界关注。本文探讨了此类结构考虑桩-土-结构相互作用的整体有限元分析的地震激励施加、单元网格划分、积分步长确定、边界处理等问题,通过整体有限元分析模型和常规分析模型的算例分析对比,探讨了常规地震动输入方法的合理程度。结果表明,常规输入法总体偏于安全,是基本可行的,但可能低估结构底部几层的地震反应,应引起注意。     

Earthquake distribution and volcanism in Kamchatka,Kurile Islands,and Hokkaido Part 3: Southern Kuriles and Hokkaido

Summary The morphology of the Wadati-Benioff zone in the region of Southern Kuriles and Hokkaido, based on the distribution of 4015 earthquake foci, verified the existence of an intermediate depth aseismic gap and its relation to active andesitic volcanism. A paleosubduction zone activated by an intermediate depth collision with the active subduction zone was found and described.

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u Wadati-Benioff amu uu - u a¶rt;, aa a an¶rt;uu 4015 a mu, nm¶rt;ua mau n¶rt; au u amu a¶rt;um au. a a¶rt;a u nuaa a na¶rt;uu, amuuuaa nmu mu amu ¶rt;uu.

     

On the universal character of particle transfer in a field of turbulence

Summary With the aid of elementary methods of the theory of dimensionality we approach the problem of existence of invariants in the process of mixing particles of a passive admixture in a field of turbulence.     

Morphology of the Wadati-Benioff zone,andesitic volcanism,and active fracture zones in Central America

Summary The morphology of the Wadati-Benioff zone in the region of Central America, based on the distribution of 1377 earthquake foci, verified the existence of an intermediate aseismic gap and its relation to active andesitic volcanism, and the non-uniformity of subduction due to the hampering effect of the main structural features of the subducting Cocos plate. Four deep seismically active fracture zones, genetically connected with the process of subduction, and three fracture zones manifesting the possible boundary between the Americas and Caribbean plates were identified in the continental wedge.     

Comments on the definition of turbulence

Zusammenfassung Es werden Gründe erläutert, die zur Äusserung einer auf dem Begriff der Ergodizität beruhenden Definition der Turbulenz führen. Wir gehen von der Theorie der Unstabilität der Strömung bei Wirkung einer Störung der endlichen Amplitude aus. Es wird das Ergodenproblem im Landauschen Modell der entwickelten Turbulenz behandelt und einige mit der Ergodenhypothese zusammenhängende Folgen erörtert. Als ein Anfangselement gilt für uns der Begriff der Transitivität. Wir beachten auch die Beziehung zwischen der metrischen Transitivität und der Eigenschaft des Durchmischens der Bewegungen sowie die Relation zwischen dem energetischen Storungsspektrum und der Ergodenhypothese.