Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ56Fe = 0.83 ± 0.07 and δ57Fe = 1.20 ± 0.13, δ65Cu = 0.57 ± 0.06, and δ66Zn = ?0.79 ± 0.12 and δ68Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ56Fe = 0.15 ± 0.07, δ57Fe = 0.22 ± 0.10, δ65Cu = 0.12 ± 0.08, δ66Zn = 0.17 ± 0.13, and δ68Zn = 0.34 ± 0.26 (2s). 相似文献
The propagation of hydraulic fracture in elastic rocks has widely been investigated. In the paper, we shall focus on numerical modeling of hydraulic fracturing in a class of porous rocks exhibiting plastic deformation. The plastic strain of porous rocks is described by a non-associated plastic model based on Drucker–Prager criterion. The plastic deformation is coupled with fluid pressure evolution described by the lubrication theory. An extended finite element method is used for modeling the propagation of fracture. The fracture propagation criterion is based on the J-integral. The proposed numerical model is validated by comparisons with numerical and analytical results. The influence of plastic deformation on fracture propagation process is investigated.
Acta Geotechnica - This work presents the results from a series of plane strain compression experiments on medium-density sands. In these experiments, a new type of plane strain experimental... 相似文献
The first-stage of an ecological conservation and restoration project in the Three-River Source Region (TRSR), China, has been in progress for eight years. However, because the ecological effects of this project remain unknown, decision making for future project implementation is hindered. Thus, in this study, we developed an index system to evaluate the effects of the ecological restoration project, by integrating field observations, remote sensing, and process-based models. Effects were assessed using trend analyses of ecosystem structures and services. Results showed positive trends in the TRSR since the beginning of the project, but not yet a return to the optima of the 1970s. Specifically, while continued degradation in grassland has been initially contained, results are still far from the desired objective, ‘grassland coverage increasing by an average of 20%–40%’. In contrast, wetlands and water bodies have generally been restored, while the water conservation and water supply capacity of watersheds have increased. Indeed, the volume of water conservation achieved in the project meets the objective of a 1.32 billion m3 increase. The effects of ecological restoration inside project regions was more significant than outside, and, in addition to climate change projects, we concluded that the implementation of ecological conservation and restoration projects has substantially contributed to vegetation restoration. Nevertheless, the degradation of grasslands has not been fundamentally reversed, and to date the project has not prevented increasing soil erosion. In sum, the effects and challenges of this first-stage project highlight the necessity of continuous and long-term ecosystem conservation efforts in this region. 相似文献