考虑渗透率变化的煤层气储层数值模拟及参数敏感性研究

煤层气开采过程中储层渗透率的变化对产气量影响较大,通过引入S＆D渗透率变化模型,建立了考虑渗透率变化的煤储层三维气水两相渗流数学模型,完成模型检验后应用所编制软件研究了煤储层参数、吸附参数及渗透率模型特征参数对开发效果的影响。结果表明,煤层气产量随着初始含气量、煤层有效厚度、裂缝渗透率和Langmuir压力的增大而增大,随储层原始压力、裂缝孔隙度和Langmuir体积的增大而减小,而解吸时间对产气量影响不大;裂缝渗透率随着杨氏模量和基质收缩/膨胀系数的增大而增大,随泊松比和裂缝压缩系数的增大而减小。引入S＆D模型后计算的累积产气量要比常规模型低1.3%,因此不可忽视煤层气产出过程中渗透率的变化。     

辽东早元古代裂谷多金属硫铁矿地质及其成矿规律

辽东早元古代地层内赋存着一系列多金属硫铁矿床。矿床的形成与分布主要受裂谷盆地演化及含矿建造控制。在不同的演化阶段分别形成了含钴黄铁矿 含铜黄铁矿 含硬石膏黄铁矿矿床系列和含硼（镁电气石）磁黄铁矿 含铅锌黄铁矿 重晶石闪锌黄铁矿矿床系列。依据成矿特征可分为海底火山喷气沉积与海底喷气沉积两种成因类型。成矿作用受裂谷、次级盆地、一定含矿层位和特殊容矿岩石相互联系与配套的控矿因素制约。在对成矿规律研究的基础上将该区多金属硫铁矿划分为６个成矿远景区。     

Archaean high-K granitoids produced by remelting of earlier Tonalite–Trondhjemite–Granodiorite (TTG) in the Sangmelima region of the Ntem complex of the Congo craton,southern Cameroon

We present a geochemical and isotopic study that, consistent with observed field relations, suggest Sangmelima late Archaean high-K granite was derived by partial melting of older Archaean TTG. The TTG formations are sodic-trondhjemitic, showing calcic and calc-alkalic trends and are metaluminous to peraluminous. High-K granites in contrast show a potassic calc-alkaline affinity that spans the calcic, calc-alkalic, alkali-calcic and alkalic compositions. The two rock groups (TTG and high-K granites) on the other hand are both ferroan and magnesian. They have a similar degree of fractionation for LREE but a different one for HREE. Nd model ages and Sr/Y ratios define Mesoarchaean and slab-mantle derived magma compositions respectively, with Nb and Ti anomalies indicating a subduction setting for the TTG. Major and trace element in addition to Sr and Nd isotopic compositions support field observations that indicate the derivation of the high-K granitic group from the partial melting of the older TTG equivalent at depth. Geochemical characteristics of the high-K granitic group are therefore inherited features from the TTG protolith and cannot be used for determining their tectonic setting. The heat budget required for TTG partial melting is ascribed to the upwelling of the mantle marked by a doleritic event of identical age as the generated high-K granite melts. The cause of this upwelling is related to linear delamination along mega-shear zones in an intracontinental setting.     

蔚县盆地中更新世哺乳动物化石新发现

1 研究目的(Objective) 蔚县盆地为典型的冀西北山间盆地,与阳原盆地仅一山之隔,二者共同组成了广义的"泥河湾盆地",盆地内广泛出露中更新统郝家台组(Qp2h)河-湖相沉积物.相比阳原盆地,蔚县盆地古生物化石研究程度较低.20世纪80年代,盆地北部(大南沟一带)出土具有上新世—早更新世面貌的小型哺乳动物化石,近...     

一种求解旅行商问题的改进蚁群算法

蚁群算法作为一种新型的优化算法,具有很强的适应性和鲁棒性,已广泛的应用于系统控制、人工智能、模式识别等工程领域。由于蚁群算法在搜索过程中易于陷入局部最优解,存在着加速收敛和早熟停滞现象的矛盾。文章针对这些问题,在基本蚁群算法的基础上,从参数的动态调整、信息量的更新规则、局部搜索策略进行相应的改进,引入信息素平滑机制,以求在加快收敛和防止早熟停滞之间取得较好的平衡。旅行商问题的仿真表明:改进后的蚁群算法具有较好的收敛性和稳定性,能够克服算法中早熟和停滞现象的过早出现。     

黑龙江七星河含煤盆地古近纪-新近纪沉积相及层序地层特征

黑龙江省东部七星河盆地是一新生代聚煤盆地,其含煤地层为古近系宝泉岭组、新近系富锦组。宝泉岭组由各级砂岩、泥岩、炭质泥岩以及褐煤组成,发育滨浅湖相、深-半深湖相、三角洲平原相,属于湖泊沉积体系、三角洲沉积体系。富锦组主要由泥岩、粉砂岩、中砂岩、含砾粗砂岩及煤层、炭质泥岩、硅藻岩组成,发育滨浅湖相、扇三角洲平原相,分别属于湖泊沉积体系和扇三角洲沉积体系。层序SI相当于宝泉岭组,发育低位体系域、湖侵体系域和高位体系域,煤层主要发育高位体系域中后期,成煤环境以滨浅湖淤积沼泽为主。层序SII相当于富锦组,主要发育湖侵体系域、高位体系域,局部地区发育低位体系域,煤层亦主要发育高位体系域中后期,成煤环境以扇三角洲淤积沼泽和滨浅湖淤积沼泽为主。层序SI、SII的高位体系域中后期,盆地基底沉降速率和物源供给处于相对平衡状态,主要发育了扇三角洲淤积沼泽、滨浅湖和滨浅湖淤积沼泽环境,发育可采煤层。     

云南前寒武纪基底形成与变质时代及其成矿作用年代学研究

新的同位素年代学、岩石学与地球化学研究表明云南前寒武纪各岩群普遍由跨越古、中和新元古代不同时代的构造片岩组成。哀牢山群和瑶山群是相连接的同一地层单元 ,主体岩石形成于 130 0～ 16 0 0Ma。昆阳群下亚群泥质碳酸盐沉积岩Pb Pb等时年龄在 170 0～ 16 0 0Ma之间 ,上亚群大营盘组为 12 6 0Ma。苍山群的变拉斑系列形成于岛弧环境 ,其钕模式年龄值在 15 0 0～ 2 0 0 0Ma ,Sm Nd等时年龄近于为 16 5 0Ma ,εNd(t) =+ 7.4。形成于板内环境的碱性系列玄武岩 ,钕模式年龄值在 10 0 0～ 110 0Ma。苴林群变拉斑玄武岩钕模式年龄为 16 0 0～ 170 0Ma ,εNd(t) =+ 6 .6 ;变碱性玄武岩样品为 80 0～ 10 0 0Ma ,可与苍山群相比较。钕模式年龄和Pb同位素填图表明昆阳群与大红山群 ,苴林群与苍山群分别归属于扬子和印支块体的准同时地层。成矿年龄测定表明前寒武纪地层中成矿作用表现为 70 0～ 90 0Ma的改造成矿 ,与大规模从基性到酸性的岩浆活动密切相联系。90 0～ 10 0 0Ma板内环境碱性玄武岩的广泛出现 ,标致着大陆裂解的开始。晋宁期花岗岩活动从早期 (80 0～ 830Ma)的偏中酸性到晚期 (6 80～ 780Ma)的酸性 ,表明构造环境从拉张向挤压环境发展 ,体现了Rodinia超大陆形成、裂解到冈瓦纳大陆形成的过程     

辽东的主要剪切带及其金矿化特征

辽东地区构造上位于辽中—吉南元古宙活动带西南部,为胶辽克拉通金矿床分布比较集中的地区。金矿化作用发生于古元古宙变质沉积岩和花岗片麻岩的韧性及脆-韧性剪切带之中,剪切活动与成金事件具同时性关系。矿化剪切带分为3大系统,其中近东—西向和北东—南西向两大系统发育于辽河群分布区,其受控于岩石非均匀性,分别借助于早(吕梁)期S₁(≈S₀)和S₂或D₃剪切带而形成,剪切活动(构造事件)与成金事件主要发生于印支运动;丹东韧性剪切带及其相关构造为本区最重要的含矿系统,矿床均顺主构造线分布,并规律性地受控于其次级构造,剪切带的形成和成金事件均在燕山运动时期。本区提供了一个特殊的克拉通成矿作用格局:容矿岩石时代老,成金事件时代新。     

Adsorption of anionic dye on magnesium hydroxide-coated pyrolytic bio-char and reuse by microwave irradiation

Magnesium hydroxide-coated pyrolytic bio-char composite was prepared by chemical precipitation, and the adsorption behavior of anionic dye (directly frozen yellow) onto magnesium hydroxide-coated pyrolytic bio-char was investigated in the batch mode. The Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy and X-ray fluorescence spectroscopy of adsorbents were characterized. Adsorption studies were performed at different pH, salt concentration, contacting time and dye concentration. The pH value of the solution influenced the adsorption capacity significantly, and adsorption is favored of pH 6–8. Salt coexisted in solution increased slightly directly frozen yellow adsorption capacity. The isotherm data were analyzed by Langmuir and Freundlich isotherm model, and Langmuir model was better to predict the equilibrium data. Thermodynamic calculations showed that the adsorption was a spontaneous and endothermic process. Exhausted magnesium hydroxide-coated pyrolytic bio-char was treated by microwave irradiation, and yield of regeneration was 98 % in the case of microwave irradiated time 5 min at 320 W. The magnesium hydroxide-coated pyrolytic bio-char can be reused.     

论卡以头组

卡以头组为介于宣威组和东川组之间的一个岩石地层单位 ,主要为黄绿色、灰绿色、褐黄色夹紫红色砂岩、砾岩和泥质岩组合 ,海相层底部夹少量灰岩 ,不含煤层和 Claraia。该组为晚二叠世—早三叠世沉积 ,海相多为早三叠世地层。建议以威宁哲觉剖面为卡以头组的标准剖面