Microstructures of coarse-grained marbles,analyzed using a new technique based on the bireflectance of calcite

A new approach to quantify microstructures of coarse-grained marbles is presented. This technique is based on the intensity of light reflectance in dependence of the crystallographic orientation of calcite grains. The technique setup consists of a high-resolution camera, a strong light source and the polished sample in reflection position. Microstructural data obtained with this method are comparable with those obtained by light microscopy or by secondary electron microscopy. However, the new approach reflects the grain size distribution even more accurately than in the case of other techniques, because it allows an easy quantification of larger sample surfaces. Therefore, in contrast to established techniques, microstructural analysis and statistics can also be performed for coarse-grained samples with grains that exceed diameters of 1 cm. With this new technique, coarse-grained mylonitic microstructures from Naxos were quantified, which in turn allowed relating different microfabrics to different strain localization episodes within a large-scale shear zone complex.     

Welcoming a monster to the world: Myths,oral tradition,and modern societal response to volcanic disasters

Volcanic eruptions can overwhelm all senses of observers in their violence, spectacle and sheer incredibility. When an eruption is catastrophic or unexpected, neither individuals nor communities can easily assimilate the event into their world view. Psychological studies of disaster aftermaths have shown that trauma can shake the very foundations of a person's faith and trigger a search – supernatural, religious, or scientific – for answers. For this reason, the ability to rapidly comprehend a traumatic event by “accepting” the catastrophe as part the observer's world represents an important component of community resilience to natural hazards. A relationship with the event may be constructed by adapting existing cosmological, ancestral, or scientific frameworks, as well as through creative and artistic expression. In non-literate societies, communal perceptions of an event may be transformed into stories that offer myth-like explanations. As these stories make their way into oral traditions, they often undergo major changes to allow transmission through generations and, in some cases, to serve political or religious purposes. Disaster responses in literate societies are no different, except that they are more easily recorded and therefore are less prone to change over time.     

Developing probabilistic eruption forecasts for dormant volcanoes: a case study from Mt Taranaki,New Zealand

The majority of continental arc volcanoes go through decades or centuries of inactivity, thus, communities become inured to their threat. Here we demonstrate a method to quantify hazard from sporadically active volcanoes and to develop probabilistic eruption forecasts. We compiled an eruption-event record for the last c. 9,500 years at Mt Taranaki, New Zealand through detailed radiocarbon dating of recent deposits and a sediment core from a nearby lake. This is the highest-precision record ever collected from the volcano, but it still probably underestimates the frequency of eruptions, which will only be better approximated by adding data from more sediment core sites in different tephra-dispersal directions. A mixture of Weibull distributions provided the best fit to the inter-event period data for the 123 events. Depending on which date is accepted for the last event, the mixture-of-Weibulls model probability is at least 0.37–0.48 for a new eruption from Mt Taranaki in the next 50 years. A polymodal distribution of inter-event periods indicates that a range of nested processes control eruption recurrence at this type of arc volcano. These could possibly be related by further statistical analysis to intrinsic factors such as step-wise processes of magma rise, assembly and storage.     

Consequences of artificially opening coastal lagoons on their fish assemblages

The consequences of artificially opening lagoon entrances on the fish assemblages of coastal lagoons in south-eastern Australia were investigated. Impacts of lagoon opening were assessed by comparing changes in the fish assemblages of Werri and Shellharbour Lagoons, both of which intermittently opened to the sea with that of Lake Illawarra, a third coastal lagoon which remained closed during the study period. Numbers of fish species and individuals did not differ significantly after lagoon openings at Werri Lagoon and Shellharbour Lagoon. However, higher numbers of species and individuals were found in Lake Illawarra before the other lagoons had opened. Abundances of some economically significant species (namelyMugil cephalus, Myxus elongatus andLiza argentea) significantly increased after openings, mainly due to small juveniles (<40 mm FL) recruiting to the seagrass beds. In contrast, these species were caught as larger juveniles (>70 mm FL) in Lake Illawarra. Furthermore, their abundance in Lake Illawarra declined during successive months, coinciding with declining salinity. Abundances of resident species (such asPseudomugil olorum andAfurcagobius tamarensis) remained largely unchanged after openings. Although it was clear that marine-spawning species must benefit from lagoon openings, the number and composition of species able to move into lagoons from adjacent waters may be dependent upon the frequency, duration and time of year that the entrance is connected to the sea. The present study thus provides data which may be useful for fisheries management in intermittently open lagoons. However, these results should not be cited as reason to artificially open lagoon entrances as further detailed studies of other aspects of lagoon biota, such as their invertebrate and avian faunas, are also needed to provide sufficient basis for broader management frameworks.     

An ocean observation system for monitoring the affects of climate change on the ecology and sustainability of pelagic fisheries in the Pacific Ocean

Climate change presents an emerging challenge to the sustainable management of tuna fisheries, and robust information is essential to ensure future sustainability. Climate and harvest affect tuna stocks, populations of non-target, dependent species and the ecosystem. To provide relevant advice we need an improved understanding of oceanic ecosystems and better data to parameterise the models that forecast the impacts of climate change. Currently ocean-wide data collection in the Pacific Ocean is primarily restricted to oceanographic data. However, the fisheries observer programs that operate in the region offer an opportunity to collect the additional information on the mid and upper trophic levels of the ecosystem that is necessary to complement this physical data, including time-series of distribution, abundance, size, composition and biological information on target and non-target species and mid trophic level organisms. These observer programs are in their infancy, with limited temporal and spatial distribution but recent international and national policy decisions have been made to expand their coverage. We identify a number of actions to initiate this monitoring including: consolidating collaborations to ensure the use of best quality data; developing consistency between sub-regional observer programmes to ensure that they meet the objectives of ecosystem monitoring; interrogating of existing time series to determine the most appropriate spatial template for monitoring; and exploring existing ecosystem models to identify suitable indicators of ecosystem status and change. The information obtained should improve capacity to develop fisheries management policies that are resilient and can be adapted to climate change.     

An iron isotope signature related to electron transfer between aqueous ferrous iron and goethite

We measured the Fe isotope fractionation during the reactions of Fe(II) with goethite in the presence and absence of a strong Fe(III) chelator (desferrioxamine mesylate, DFAM). All experiments were completed in an O₂-free glove box. The concentrations of aqueous Fe(II) ([Fe(II)_aq]) decreased below the initial total dissolved Fe concentrations ([Fe(II)_total], 2.15 mM) due to fast adsorption within 0.2 day. The concentration of adsorbed Fe(II) ([Fe(II)_ads]) was determined as the difference between [Fe(II)_aq] and the concentration of extracted Fe(II) in 0.5 M HCl ([Fe(II)_extr]) (i.e., [Fe(II)_ads] = [Fe(II)_extr] − [Fe(II)_aq]). [Fe(II)_ads] also decreased with time in experiments with and without DFAM, documenting that fast adsorption was accompanied by a second, slower reaction. Interestingly, [Fe(II)_extr] was always smaller than [Fe(II)_total], indicating that some Fe(II) was sequestered into a pool that is not HCl-extractable. The difference was attributed to Fe(II) incorporated into goethite structure (i.e., [Fe(II)_inc] = [Fe(II)_total] −[Fe(II)_extr]). More Fe(II) was incorporated in the presence of DFAM than in its absence at all time steps. Regardless of the presence of DFAM, both aqueous and extracted Fe(II) (δ^56/54Fe(II)_aq and δ^56/54Fe(II)_extr) became isotopically lighter than or similar to goethite (− 0.27‰) at day 7, implying that the isotope exchange occurred between bulk goethite and aqueous Fe. Consistently, the mass balance indicated that the incorporated Fe is isotopically heavier than extracted Fe. These observations suggested that (i) co-adsorption of Fe(II) with DFAM resulted in more pervasive electron transfer, (ii) the electron transfer from heavy Fe(II) in the adsorbed Fe(II) to light Fe(III) in goethite results in the fixation of heavy adsorbed Fe(III) on the surface and accumulation of Fe(II) within the goethite, and (iii) desorption of the reduced, light Fe from goethite does not necessarily occur at the same surface sites where adsorption occurred.     

Remediation of ground water containing chlorinated and brominated hydrocarbons, benzene and chromate by sequential treatment using ZVI and GAC

A laboratory experiment with two sequenced columns was performed as a preliminary study for the installation of a permeable reactive barrier (PRB) at a site where a mixed ground water contamination exists. The first column contained granular zero valent iron (ZVI), the second column was filled with granular activated carbon (GAC). Trichloromethane (TCM, 930 μg/l) and chlorobenzene (MCB, 260 μg/l) were added to the ground water from the site as the main contaminants. Smaller amounts (<60 μg/l) of benzene, 1,2-dichloroethane, 1,1,2-trichloroethane (1,1,2-TCA), 1,1-dichloroethene (1,1-DCE), trichloroethene (TCE), tetrachloroethene (PCE), 1,2-dichloropropane (1,2-DCP), bromodichloromethane (BDCM), dibromochloromethane (DBCM), tribromomethane (TBM), vinyl chloride and chromate were also added to the water to simulate the complex contamination pattern at the site of interest. PCE, TCE, 1,1-DCE, DBCM, BDCM, TBM, MCB and chromate were remediated in contact with ZVI, while the remaining contaminants showed incomplete degradation. A fraction of 8–16.5% TCM was converted to dichloromethane (DCM). Remaining contaminant concentrations were efficiently sorbed by the GAC until breakthrough of DCM was observed after 1,230 exchanged pore volumes in the GAC. The results show that the complex mixture of contaminants can be remediated by a sequenced PRB consisting of ZVI and GAC and that DCM sorption capacity is the critical parameter for the dimensions of the GAC reactor.     

Bemerkung zu den Vorträgen Backlund und Eskola

Ohne Zusammenfassung     

Millennial timescale resolution of rhyolite magma recharge at Tarawera volcano: insights from quartz chemistry and melt inclusions

Most rhyolite eruption episodes of Tarawera volcano have emitted several physiochemically distinct magma batches (∼1–10 km³). These episodes were separated on a millennial timescale. The magma batches were relatively homogeneous in temperature and composition at pumice scale (>4 cm), but experienced isolated crystallisation histories. At the sub-cm scale, matrix glasses have trace element compositions (Sr, Ba, Rb) that vary by factors up to 2.5, indicating incomplete mixing of separate melts. Some quartz-hosted melt inclusions are depleted in compatible trace elements (Sr, Ti, Ba) compared to enclosing matrix glasses. This could reflect re-melting of felsic crystals deeper in the crystal pile. Individual quartz crystals display a variety of cathodoluminescence brightness and Ti zoning patterns including rapid changes in melt chemistry and/or temperature (∼50–100°C), and point to multi-cycle crystallisation histories. The Tarawera magma system consisted of a crystal-rich mass containing waxing and waning melt pockets that were periodically recharged by silicic melts driven by basaltic intrusion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.