Reconstructing the 3-D Trajectories of CMEs in the Inner Heliosphere

A method for the full three-dimensional (3-D) reconstruction of the trajectories of coronal mass ejections (CMEs) using Solar TErrestrial RElations Observatory (STEREO) data is presented. Four CMEs that were simultaneously observed by the inner and outer coronagraphs (COR1 and 2) of the Ahead and Behind STEREO satellites were analysed. These observations were used to derive CME trajectories in 3-D out to ～?15?R _⊙. The reconstructions using COR1/2 data support a radial propagation model. Assuming pseudo-radial propagation at large distances from the Sun (15?–?240?R _⊙), the CME positions were extrapolated into the Heliospheric Imager (HI) field-of-view. We estimated the CME velocities in the different fields-of-view. It was found that CMEs slower than the solar wind were accelerated, while CMEs faster than the solar wind were decelerated, with both tending to the solar wind velocity.     

Evaluating the meaning of “layer” in the martian north polar layered deposits and the impact on the climate connection

Using data from the High Resolution Imaging Science Experiment (HiRISE) aboard the Mars Reconnaissance Orbiter, we reassess the methods by which layers within the north polar layered deposits (NPLD) can be delineated and their thicknesses measured. Apparent brightness and morphology alone are insufficient for this task; high resolution topographic data are necessary. From these analyses, we find that the visible appearance of layers depends to a large degree on the distribution of younger, mantling deposits (which in turn is partially influenced by inherent layer properties) and on the shape and location of the particular outcrop. This younger mantle partially obscures layer morphology and brightness and is likely a cause of the gradational contacts between individual layers at this scale. High resolution images reveal that there are several layers similar in appearance to the well-known marker bed discovered by Malin, M., Edgett, K., 2001. J. Geophys. Res. 106, 23429-23570. The morphology, thicknesses , and separation distances of these marker beds, as gleaned from a high resolution stereo digital elevation model, lend insight into the connection between stratigraphy and climate.     

A diatom-inferred record of reduced effective precipitation during the Last Glacial Coldest Phase (28.8–18.0?cal kyr BP) and increasing Holocene seasonality at Lake Pupuke, Auckland, New Zealand

A continuous, 1,420-cm sediment record from Lake Pupuke, Auckland, New Zealand (37°S) was analysed for diatom taxonomy, concentration and flux. A New Zealand freshwater diatom transfer function was applied to infer past pH, electrical conductivity, dissolved reactive phosphorus and chlorophyll a. A precise, mixed-effect regression model of age versus depth was constructed from 11 tephra and 13 radiocarbon dates, with a basal age of 48.2?cal kyr BP. Diatom-inferred changes in paleolimnology and climate corroborate earlier inferences from geochemical analyses (Stephens et al. 2012), with respect to the timing of marked climate changes in the Last Glacial Coldest Phase (LGCP; 28.8?C18.0?cal kyr BP), the Last Glacial Interglacial Transition (LGIT; 18.0 to ca. 12?C10?cal kyr BP) and the Holocene, the onset of which is difficult to discern from LGIT amelioration, but which includes an early climatic optimum (10.2?C8.0?cal kyr BP). The LGCP is readily defined by a reduction in lake level and effective precipitation, whereas the LGIT represents a period of rising lake level, with greater biomass during the Holocene. There was limited change in diatom assemblage structure, influx or inferred water quality during a Late Glacial Reversal (LGR; 14.5?C13.8?cal kyr BP), associated with heightened erosional influx. In contrast, an LGIT peak in paleoproductivity is recorded by increased diatom influx from 13.8 to 12.8?cal kyr BP. Changes in sediment influx and biomass record complex millennial-scale events attuned to the Antarctic Cold Reversal (ACR; 14.5?C12.8?cal kyr BP). Additional millennial-scale environmental change is apparent in the Holocene, with marked changes in lake circulation beginning at 7.6?cal kyr BP, including the onset of seasonal thermal stratification and rapid species turnover at 5.7?cal kyr BP. The most rapid diatom community turnover accompanied widely varying nutrient availability and greater seasonality during the last 3.3?cal kyr. Rising seasonality appears to have been linked to strengthened Southern Westerlies at their northern margins during the middle and late Holocene.     

A Comparison of Higher-Order Vertical Velocity Moments in the Convective Boundary Layer from Lidar with In Situ Measurements and Large-Eddy Simulation

We have analyzed measurements of vertical velocity w statistics with the NOAA high resolution Doppler lidar (HRDL) from about 390 m above the surface to the top of the convective boundary layer (CBL) over a relatively flat and uniform agricultural surface during the Lidars-in-Flat-Terrain (LIFT) experiment in 1996. The temporal resolution of the zenith-pointing lidar was about 1 s, and the range-gate resolution about 30 m. Vertical cross-sections of w were used to calculate second- to fourth-moment statistics of w as a function of height throughout most of the CBL. We compare the results with large-eddy simulations (LES) of the CBL and with in situ aircraft measurements. A major cause of the observed case-to-case variability in the vertical profiles of the higher moments is differences in stability. For example, for the most convective cases, the skewness from both LES and observations changes more with height than for cases with more shear, with the observations changing more with stability than the LES. We also found a decrease in skewness, particularly in the upper part of the CBL, with an increase in LES grid resolution.     

Thermal evolution of an ancient subduction interface revealed by Lu–Hf garnet geochronology,Halilbağı Complex (Anatolia)

The thermal structure of subduction zones exerts a major influence on deep-seated mechanical and chemical processes controlling arc magmatism, seismicity, and global element cycles. Accretionary complexes exposed inland may comprise tectonic blocks with contrasting pressure–temperature (P–T) histories, making it possible to investigate the dynamics and thermal evolution of former subduction interfaces. With this aim, we present new Lu–Hf geochronological results for mafic rocks of the Halilba?? Complex (Anatolia) that evolved along different thermal gradients. Samples include a lawsonite–epidote blueschist, a lawsonite–epidote eclogite, and an epidote eclogite (all with counter-clockwise P–T paths), a prograde lawsonite blueschist with a “hairpin”-type P–T path, and a garnet amphibolite from the overlying sub-ophiolitic metamorphic sole. Equilibrium phase diagrams suggest that the garnet amphibolite formed at ～0.6–0.7 GPa and 800–850 °C, whereas the prograde lawsonite blueschist records burial from 2.1 GPa and 420 °C to 2.6 GPa and 520 °C. Well-defined Lu–Hf isochrons were obtained for the epidote eclogite (92.38 ± 0.22 Ma) and the lawsonite–epidote blueschist (90.19 ± 0.54 Ma), suggesting rapid garnet growth. The lawsonite–epidote eclogite (87.30 ± 0.39 Ma) and the prograde lawsonite blueschist (ca. 86 Ma) are younger, whereas the garnet amphibolite (104.5 ± 3.5 Ma) is older. Our data reveal a consistent trend of progressively decreasing geothermal gradient from granulite-facies conditions at ～104 Ma to the epidote-eclogite facies around 92 Ma, and the lawsonite blueschist-facies between 90 Ma and 86 Ma. Three Lu–Hf garnet dates (between 92 Ma and 87 Ma) weighted toward the growth of post-peak rims (as indicated by Lu distribution in garnet) suggest that the HP/LT rocks were exhumed continuously and not episodically. We infer that HP/LT metamorphic rocks within the Halilba?? Complex were subjected to continuous return flow, with “warm” rocks being exhumed during the tectonic burial of “cold” ones. Our results, combined with regional geological constraints, allow us to speculate that subduction started at a transform fault near a mid-oceanic spreading centre. Following its formation, this ancient subduction interface evolved thermally over more than 15 Myr, most likely as a result of heat dissipation rather than crustal underplating.     

The Precambrian geology of the “Borborema”-Belt (States of Paraíba and Rio Grande do Norte; northeastern Brazil) and the origin of its mineral provinces

In the crystalline area of the “Borborema” in NE Brazil the final geologic event was a strong static recrystallization, which is manifest in regional granitization, hybride granite, or pegmatite veins. The manifestation varies within the mapped area, it depends on lithology, thickness and structure of the Precambrian metasediments. The age of this phase is between 550 and 450 M. years. Recrystallization is accompanied by weak folding of pre-existing anticlines as indicated by the structural control of the Borborema pegmatites. The principal phase of deformation and the accompanying regional metamorphism are considered to be older, approximately 850 M. years or more. This older regional metamorphism produced rocks of the almandine-staurolite subfacies of the amphibolite facies; locally higher (cordierite and sillimanite subfacies) or lower (greenschist facies) degree of metamorphism occurs. The pyroxene-hornfels facies, which is found in the contact aureoles of hybride granites, occurs exclusively in the tactites (metamorphic dolomitic marls). In clastic metasediments, high grade metamorphic facies is restricted to the contact aureole of a small hypersthene diorite stock. The structure is simple, and consists of synclines and anticlines the axial planes of which are vertical or, rarely, inclined. Faults are rare. The degree of lateral compression varies: low in the NW part of the area mapped, intermediate in die NE, and high in the southern part. The southern part belongs to the “Paraíba Transversal Zone”, an E-W striking fault zone along which the northern parts have been dislocated horizontally to the East. Stratigraphically the sequence is subdivided into three major groups by unconformities, which, however, are masked intensely by the principal tectonic events. These groups are: The oldest member occurs but locally in the cores of some anticlines; the youngest constitutes the cores of most synclines. The Caicó can be subdivided, in the most part, as follows: Florânia and Parelhas are essentially composed by unsorted clastic sediments (graywackes and arcoses). The Equador is a local lithofacies of the latter restricted to one anticline and a small part of another, and composed of well sorted clastics (muscovite quartzite). Another quartzite, locally developed at the top of the Florânia in the western part of the area, has been named “Member S. José do Seridó”. The Quixaba contains essentially carbonate rocks, but with intercalations of clastic sediments. The scheelite province of the area is generally connected with the Quixaba-Formation, the marbles of which served as transportation channels, whereas tactites were the receptors of the ore-bringing solutions, derived from some palingenetic granites and thus, indirectly, from the metasediments of the Parelhas. The deposition does not belong to the principal phase of contact metamorphism, but to a later-phase with hydrothermal paragenesis. Scheelite occurs also in common quartz-albite-veins. The famous pegmatite-province (Ta, Nb, Li, Be) cannot be considered as a product of magmatic differentiation, either. It must be the product of the statical recrystallization of the muscovite-rich Equador quartzite, by addition of thermal energy and K-rich solutions from the depth. Thus this province is only a special case of the general “granitization” with K-metasomatism: $$Quartz + Muscovite + K^ + \to Microclin + H^ + + Water.$$ The resulting fluids formed pegmatites in the rocks overlying the quartzite, i. e., generally in the micaschists of the Seridó-Group. Productive dykes always fill longitudinal or transversal tension cracks. The Borborema province of zoned pegmatites is thus an excellent example for the recent genetic hypothesis ofGresens, all requirements of it being fulfilled.     

Holocene climate of New England

Stratigraphic studies of pollen and macrofossils from six sites at different elevations in the White Mountains of New Hampshire demonstrate changes in the distributions of four coniferous tree species during the Holocene. Two species presently confined to low elevations extended farther up the mountain slopes during the early Holocene: white pine grew 350 m above its present limit beginning 9000 yr B.P., while hemlock grew 300–400 m above its present limit soon after the species immigrated to the region 7000 yr. B.P. Hemlock disappeared from the highest sites about 5000 yr B.P., but both species persisted at sites 50–350 m above their present limits until the Little Ice Age began a few centuries ago. The history of the two main high-elevation conifers is more difficult to interpret. Spruce and fir first occur near their present upper limits 9000 or 10,000 yr B.P. Fir persisted in abundance at elevations similar to those where it occurs today throughout the Holocene, while spruce became infrequent at all elevations from the beginning of the Holocene until 2000 yr B.P. These facts suggest a more complex series of changes than a mere upward shift of the modern environmental gradient. Nevertheless, we conclude that the minimum climatic change which would explain the upward extensions of hemlock and white pine is a rise in temperature, perhaps as much as 2°C. The interval of maximum warmth started 9000 yr B.P. and lasted at least until 5000 yr B.P., correlative with the Prairie Period in Minnesota.     

The northern Walker Lane refraction experiment: Pn arrivals and the northern Sierra Nevada root

In May 2002, we collected a new crustal refraction profile from Battle Mountain, Nevada across western Nevada, the Reno area, Lake Tahoe, and the northern Sierra Nevada Mountains to Auburn, CA. Mine blasts and earthquakes were recorded by 199 Texan instruments extending across this more than 450-km-long transect. The use of large mine blasts and the ultra-portable Texan recorders kept the field costs of this profile to less than US$10,000. The seismic sources at the eastern end were mining blasts at Barrick's GoldStrike mine. The GoldStrike mine produced several ripple-fired blasts using 8000–44,000 kg of ANFO each, a daily occurrence. First arrivals from the larger GoldStrike blasts are obvious to distances of 300 km in the raw records. First arrivals from a quarry blast west of the survey near Watsonville, CA, located by the Northern California Seismic Network with a magnitude of 2.2, can be picked across the recording array to distances of 600 km. The Watsonville blast provides a western source, nearly reversing the GoldStrike blasts. A small earthquake near Bridgeport, CA. also produced pickable P-wave arrivals across the transect, providing fan-shot data. Arrivals from M5 events in the Mariana and Kuril Islands also appear in the records. This refraction survey observes an unexpectedly deep crustal root under the northern Sierra Nevada range, over 50 km in thickness and possibly centered west of the topographic crest. Pn delays of 4–6 s support this interpretation. At Battle Mountain, Nevada, we observe anomalously thin crust over a limited region perhaps only 150 km wide, with a Moho depth of 19–23 km. Pn crossover distances of less than 80 km support this anomaly, which is surrounded by observations of more normal, 30-km-thick crust. A 10-km-thick and high-velocity lower-crustal “pillow” is an alternative hypothesis, but unlikely due to the lack of volcanics west of Battle Mountain. Large mine and quarry blasts prove very effective crustal refraction sources when recorded with a dense receiver array, even over distances exceeding 600 km. New elastic synthetic seismogram modeling suggests that Pn can be strong as a first arrival, easing the modeling and interpretation of crustal refraction data. Fast eikonal computations of first-arrival time can match pickable Pn arrival times.     

In vitro enzymatic reduction kinetics of mineral oxides by membrane fractions from Shewanella oneidensis MR-1

This study documents the first example of in vitro solid-phase mineral oxide reduction by enzyme-containing membrane fractions. Previous in vitro studies have only reported the reduction of aqueous ions. Total membrane (TM) fractions from iron-grown cultures of Shewanella oneidensis MR-1 were isolated and shown to catalyze the reduction of goethite, hematite, birnessite, and ramsdellite/pyrolusite using formate. In contrast, nicotinamide adenine dinucleotide (NADH) and succinate cannot function as electron donors. The significant implications of observations related to this cell-free system are: (i) both iron and manganese mineral oxides are reduced by the TM fraction, but aqueous U(VI) is not; (ii) TM fractions from anaerobically grown, but not aerobically grown, cells can reduce the mineral oxides; (iii) electron shuttles and iron chelators are not needed for this in vitro reduction, documenting conclusively that reduction can occur by direct contact with the mineral oxide; (iv) electron shuttles and EDTA stimulate the in vitro Fe(III) reduction, documenting that exogenous molecules can enhance rates of enzymatic mineral reduction; and (v) multiple membrane components are involved in solid-phase oxide reduction. The membrane fractions, consisting of liposomes of cytoplasmic and outer membrane segments, contain at least 100 proteins including the enzyme that oxidizes formate, formate dehydrogenase. Mineral oxide reduction was inhibited by the addition of detergent Triton X-100, which solubilizes membranes and their associated proteins, consistent with the involvement of multiple electron carriers that are disrupted by detergent addition. In contrast, formate dehydrogenase activity was not inhibited by Triton X-100. The addition of anthraquinone-2,6-disulfonate (AQDS) and menaquinone-4 was unable to restore activity; however, menadione (MD) restored 33% of the activity. The addition of AQDS and MD to reactions without added detergent increased the rate of goethite reduction. The Michaelis-Menten K_m values of 71 ± 22 m²/L for hematite and 50 ± 16 m²/L for goethite were calculated as a function of surface area of the two insoluble minerals. V_max was determined to be 123 ± 14 and 156 ± 13 nmol Fe(II)/min/mg of TM protein for hematite and goethite, respectively. These values are consistent with in vivo rates of reduction reported in the literature. These observations are consistent with our conclusion that the enzymatic reduction of mineral oxides is an effective probe that will allow elucidation of molecular chemistry of the membrane-mineral interface where electron transfer occurs.