Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.     

环境大气对积云发展的影响

为了能更实际客观地模拟天气的发展变化，在胡志晋教授的一维时变积云数值模式的基础上考虑了环境大气与积云群的发生、发展及降水之间的相互作用，保留了原模式所有的微物理过程，建立了一维积云时变套柱模式。此模式不仅能模拟积云，还可以模拟积云在层状云中发展变化，以及模拟环境大气具有辐合辐散场时积云的发展。     

气候波动和人类活动对南水北调中线工程典型流域径流影响的定量评估

以南水北调中线工程典型流域汉江上游流域和滦河流域为研究对象,采用敏感性分析法、降水?径流双累积曲线法、累积量斜率变化率比较法定量评估了气候波动和人类活动对流域径流变化的影响。结果表明：汉江上游流域和滦河流域变异Ⅰ/Ⅱ期年均径流深相对于基准期分别减少了29.5% / 19.1%和49.8% / 70.0%;对于汉江上游流域,1991-1999年（变异Ⅰ期）气候波动是径流减少的主要影响因素,2000-2008年（变异Ⅱ期）人类活动则是径流减少的主要影响因素,且人类活动对汉江上游流域径流减少的影响逐步增加;对于滦河流域,1980-2010年（变异Ⅰ/Ⅱ期）人类活动一直是径流减少的主要影响因素,且气候波动和人类活动对径流减少的影响贡献率基本保持不变。     

Influence of coastal wind on surface ozone and nitrogen oxides in suburban Shanghai

Surface ozone, NO, NO₂, and NO _x were measured at a coastal site (Shihua) and a nearby inland site (Zhujing) in suburban Shanghai for the whole year of 2009. More days with ozone pollution in a longer time range were observed at the coastal site than the inland site. The diurnal variations of NO _x concentrations were obviously higher at Zhujing station, while those of ozone concentrations were higher at Shihua station, indicating their different air pollution conditions. Coastal wind has significant influence on the levels and characteristics of the air pollutants. The ozone concentrations during maritime winds (MW) were much higher than those during continental winds (CW) at each of the site, while the NO and NO₂ concentrations were both opposite. The ozone concentrations at Shihua station were much higher than those at Zhujing station, while the NO and NO₂ concentrations were both opposite. The ozone concentrations at both of the two sites showed a distinct “weekend effects” and “weekdays effects” patterns during CW and MW, respectively. Correlation analysis of the pollutants showed that, the compounds during MW were more age than those during CW, and the compounds at Shihua were more age than those at Zhujing. The air pollutions at both of the two sites are mainly associated with the pollutants emitted in this region instead of long range transport.     

汉江流域极端水文事件时空分布特征

利用1960-2012年汉江流域15个气象站点的日降雨资料和3个水文站同时期日径流资料,分析了9个极端降雨指数的空间分布规律,运用广义极值分布（GEV）、Gamma分布两种极值统计模型对各站点的最大1 d降雨、最大3 d降雨极值样本进行拟合,遴选描述降雨极值分布规律最优概率模型,进而推算给定重现期下的降雨设计值,并分析其空间分布规律;选用Gumbel、Clayton和Frank这3种Copula函数建立降雨-洪量极值联合分布模型,优选最合适的Copula函数,由此计算给定重现期下的洪量设计值。结果表明：GEV分布模型能更好地模拟降雨极值序列,不同重现期下的降雨极值在空间上均呈西低东高的特征;3种Copula函数中,Frank Copula函数能更好地拟合降雨-洪量相关关系,由此推求的洪量设计值大于单变量拟合设计值。     

联合平差中大地测量观测值的数学模型

本文引入了摄影测量与非摄影测量观测值联合平差中大地测量观测值的严密数学模型——三维大地测量模型和常规的近似模型,针对这两种模型的局限性,提出了适合于联合平差的准三维大地测量模型。     

洱海湖滨带水生植物多样性及分布现状

湖滨带水生植物对湖泊生态系统健康的维持具有重要作用。为了解当前洱海湖滨带水生植物现状,本研究于2020—2021年间每季度对洱海湖滨带水生植物进行调查。调查结果表明:(1)洱海湖滨带现有水生植物206种,属56科156属,其中湿生植物149种,挺水植物24种,沉水植物21种,漂浮植物7种,浮叶植物5种;常见种有狗牙根(Cynodon dactylon)、菰(Zizania latifolia)、苦草(Vallisneria natans)、菱(Trapa bispinosa)等,偶见种为忍冬(Lonicera japonica)、披碱草(Elymus dahuricus)等。(2)从区系分布来看,洱海湖滨带物种主要为世界分布(83种)和热带分布(55种)两种类型,分别占总物种数比例的40.28%和26.71%。(3)在植物群落方面,洱海湖滨带共有18个主要植物群落类型,其中湿生植物群落4种,挺水植物群落3种,沉水植物群落9种,浮叶植物群落2种;以狗牙根群落、菰群落、苦草群落、菱群落为主。通过与历史文献结果的对比分析得出,近年来洱海湖滨带水生植物多样性有了显著提高,但目前存在挺水植物群落...     

气温对太湖蓝藻复苏和休眠进程的影响

利用2005 2014年每日的卫星数据、气象站和浮标站观测资料研究复苏期和休眠期的平均气温、稳定通过界限温度初终日、周有效积温与太湖蓝藻休眠和复苏时间的关系,探讨气温是否是影响蓝藻休眠和复苏时间进程的关键因子.分析结果显示:太湖蓝藻复苏早晚与春季(3 5月)气温密切相关,春季气温越高,蓝藻复苏时间越早;太湖蓝藻休眠时间与秋、冬季(11次年1月)气温密切相关,秋、冬季气温越高,蓝藻休眠时间越晚.此外根据分析结果发现,太湖首次出现蓝藻水华的时间一般是气温稳定通过9℃初日之后的1个月左右,但上一周期的休眠与下一周期的复苏之间气温异常偏高会导致蓝藻水华首次出现时间早于稳定通过9℃初日;最后一次蓝藻水华出现时间与气温稳定通过4℃的终日相近;在复苏期,湖水中的叶绿素a浓度随周有效积温变化而变化,二者相关系数为0.9.     

阿尔金山两侧盐湖物质来源、成钾作用及其控制因素研究

塔里木盆地东部的罗布泊盐湖和柴达木盆地西部的盐湖分别位于阿尔金山两侧,均产出有大量富钾卤水,在油气藏开采中还伴随产出富钾油田水。为探讨阿尔金山两侧盐类资源富集机制及其控制因素,综合分析了罗布泊盐湖、柴达木盆地西部盐湖以及油田水的水化学和氢氧同位素地球化学特征,发现:富钾卤水的形成除依靠地表汇入水体的蒸发浓缩作用外,罗布泊晶间水、柴达木晶间水和油田水氢氧同位素均可演化至δD=-30‰,δ¹⁸O=7.5‰左右,可能是深部流体上涌补给的结果。同时,根据⁸⁷Sr/⁸⁶Sr值并结合δ¹¹B、³He/⁴He同位素特征确认了盐湖成矿与深部流体有关,且指示罗布泊盐湖更具深源特征。深部流体对于两侧盆地成盐富钾有关键性作用,罗布泊盐湖可能接受深部流体补给,柴达木盆地西部富钾盐湖卤水多数可接受油田水的补给,而少部分可能接受深部流体补给。     

柴达木盆地那棱格勒河及其尾闾盐湖锂成矿物源：来自水化学和锶、硫同位素证据

柴达木盆地那棱格勒河尾闾盐湖(一里坪干盐滩、东台吉乃尔盐湖、西台吉乃尔盐湖和察尔汗盐湖别勒滩区段)赋存了我国目前最大的卤水锂矿床。那棱格勒河及其尾闾盐湖锂的物源仍存在一定争议,主要有围岩风化、古湖残留、含盐系地层淋滤、油田水、深部水等,目前缺乏有力的地球化学证据。本文系统采集了那棱格勒河流域及其尾闾盐湖不同水体样品16件,分析了其主、微量元素含量及锶、硫同位素组成。结合前人的研究成果,对区域水体中锂的来源进行了探讨,得出结论如下:那棱格勒河水锂含量(0.45～0.79 mg/L)比楚拉克阿拉干河支流(0.00～0.05 mg/L)高出一个数量级,其高锂含量主要受洪水河支流的补给;洪水河高锂含量与其上游热泉水的补给有关,该热泉水锂、锶含量高、⁸⁷Sr/⁸⁶Sr比值偏高,δ³⁴S值偏低,与青藏高原典型热泉水地球化学特征(锂含量0.4～34.8 mg/L,锶含量0.07～4.24 mg/L,⁸⁷Sr/⁸⁶Sr比值0.71224～0.71259,δ³⁴S值-10....