赣东北地区矽卡岩典型矿物形成与演化的光谱证据:以朱溪钨多金属矿为例SCIEI北大核心CSCD

朱溪是近年来在江西塔前-赋春成矿带发现的一个世界级超大型钨铜矿床。本文采用短波红外+热红外光谱技术对矿区13个钻孔进行了光谱测量,结合岩石-矿物地球化学分析,探讨了朱溪矿床矽卡岩中典型蚀变矿物的形成与演化过程,厘定了矽卡岩形成不同阶段矿物组合的光谱特征,构建了朱溪矿床的短波红外+热红外光谱勘查模型。研究发现:(1)区内不同矿物组合形成了明显的蚀变分带,由内向外依次为绢云母(富Si)+长石(岩体顶层蚀变,多期流体叠加综合作用)→外矽卡岩:钙铝榴石+透辉石+(绢云母)→透辉石+蛇纹石+绿泥(帘)石+滑石→绢云母(富Al)+绿泥(帘)石(基底不整合面蚀变);(2)Al-OH波长的移动可指示成矿流体压力、温度及pH值的变化;(3)研究区透辉石的形成、演化与矿体之间关系密切,虽然富矿体赋存于矽卡岩形成早期的透辉石-石榴子石蚀变带,但大量矿体则赋存于矽卡岩退蚀变阶段的蛇纹石-绿泥石蚀变带;(4)矿体的形成与流体的混合作用关系极大,伊利石光谱吸收特征能够指示外部冷水(大气降水或地下水)的灌入轨迹。     

沙澧河流域两场大暴雨过程的对比分析

利用常规观测资料、自动站资料和NCEP1°×1°再分析资料对2007年7月5日和14日沙澧河流域两场大暴雨过程进行了诊断对比分析.结果表明:不同影响系统下产生的大暴雨过程其动力机制有所差异.垂直螺旋度计算结果显示:两次过程700hPa等压面上正垂直螺旋度中心的移向和强度变化与降水落区及趋势变化有很好的对应关系,暴雨区出现在正垂直螺旋度中心移动的前方,对流域大暴雨的落区有一定的指示意义.5日呈现中低层正、高层负的垂直螺旋度配置,动力条件更有利于大暴雨的发生.湿位涡演变分析发现,5日中低层既存在对流不稳定,又存在对称不稳定,有利于垂直对流和倾斜对流发生,造成流域大暴雨.14日中低层大气处于对流稳定状态,但边界层和中层存在对流不稳定,同时中层还存在较强的对称不稳定,垂直涡度得到较大增长,导致上升运动的加强和水汽的垂直输送,有利于降水增幅.     

引入积温效应预测夏季西安市电力气象负荷

利用2010—2012年6—8月西安市逐日电力负荷资料及对应时段地面观测站数据,分析了高温天气过程中日最大电力负荷的变化特征。结果发现,3年间西安地区共发生晴热天气过程5次,闷热天气过程4次,其中晴热天气过程发生在6月,闷热天气过程发生在7、8月,且闷热天气过程的电力负荷增长更加明显;利用日最高气温变化跟踪气象负荷的变化发现,日最高气温33℃为西安市气象负荷初始气温敏感点,35℃为强气温敏感点,38℃为极强气温敏感点;引入积温累积效应,建立了多元回归的电力气象负荷预测模型,经2013年夏季模型应用检验表明,日最大电力负荷预测平均误差为6.0%,能较好的模拟电力负荷的实际变化,对西安市夏季电力气象服务工作有指导意义。     

渤海的海冰数值预报

根据渤海气候和冰情特点,在已有海冰模式研究基础上,提出模拟海冰增长、消融和漂移的动力－热力学模式。模式冰厚分布由开阔水、平整冰和堆积冰三要素表示。该模式已与数值天气预报模式、大气边界层模式、潮流模式联结,并于１９９０年到１９９６年在国家海洋环境预报中心进行渤海和北黄海冰情预报。其数值预报产品包括冰厚、密度集、冰速、冰外缘线、冰脊参数、局地冰厚以及接近石油平台的冰漂移轨迹等,传送到国家海洋预报台和渤海石油公司等有关用户。为了客观评价模式和检验预报结果,在逐日预报后进行统计检验。本文概述渤海冰情、卫星遥感应用、冰模式及其预报结果和检验。     

The effect of chemical composition and oxygen fugacity on the electrical conductivity of dry and hydrous garnet at high temperatures and pressures

The in situ electrical conductivity of hydrous garnet samples (Py₂₀Alm₇₆Grs₄–Py₇₃Alm₁₄Grs₁₃) was determined at pressures of 1.0–4.0 GPa and temperatures of 873–1273 K in the YJ-3000t apparatus using a Solartron-1260 impedance/gain-phase analyzer for various chemical compositions and oxygen fugacities. The oxygen fugacity was controlled by five solid-state oxygen buffers (Fe₂O₃ + Fe₃O₄, Ni + NiO, Fe + Fe₃O₄, Fe + FeO, and Mo + MoO₂). Experimental results indicate that within a frequency range from 10⁻² to 10⁶ Hz, electrical conductivity is strongly dependent on signal frequency. Electrical conductivity shows an Arrhenius increase with temperature. At 2.0 GPa, the electrical conductivity of anhydrous garnet single crystals with various chemical compositions (Py₂₀Alm₇₆Grs₄, Py₃₀Alm₆₇Grs₃, Py₅₆Alm₄₃Grs₁, and Py₇₃Alm₁₄Grs₁₃) decreases with increasing pyrope component (Py). With increasing oxygen fugacity, the electrical conductivity of dry Py₇₃Alm₁₄Grs₁₃ garnet single crystal shows an increase, whereas that of a hydrous sample with 465 ppm water shows a decrease, both following a power law (exponents of 0.061 and −0.071, respectively). With increasing pressure, the electrical conductivity of this hydrous garnet increases, along with the pre-exponential factors, and the activation energy and activation volume of hydrous samples are 0.7731 ± 0.0041 eV and −1.4 ± 0.15 cm³/mol, respectively. The results show that small hopping polarons ( \textFe_\textMg ^· ) \left( {{\text{Fe}}_{\text{Mg}}^{ \cdot } } \right) and protons ( \textH ^· {\text{H}}^{ \cdot } ) are the dominant conduction mechanisms for dry and wet garnet single crystals, respectively. Based on these results and the effective medium theory, we established the electrical conductivity of an eclogite model with different mineral contents at high temperatures and high pressures, thereby providing constraints on the inversion of field magnetotelluric sounding results in future studies.     

基于Vulcan软件的山东莱州留村金矿区三维建模及资源量估值北大核心CSCD

留村金矿位于山东莱州市城区西南12 km的留村断裂带上,是发育于古老变质岩中的小型石英脉型金矿。为深入研究该矿区地层、构造与矿体在地下的延伸分布情况,加快后续数字化矿山建设,山东黄金集团应用Vulcan矿业软件对矿区开展三维地质建模。在收集相关地质实物资料的基础上,通过建立地质数据库、数据转换、地质解译等系列功能操作建立了矿区地表、岩体、构造及矿体模型,并对其进行任意剖割划分,实现了矿区地层岩性、地质构造、矿体的三维可视化,促进了本区矿体赋存规律的研究以及三维空间的成矿预测。同时利用软件强大的数据处理功能对资源量进行估值,本次估值的金资源量为1984.18 kg,与原详查报告中提交的金资源量2009.34 kg误差仅为1.25%。经估值后的每个矿块段都被赋予了精确的资源量数据,为后续矿山采矿设计与排产计划提供了准确的数据支撑,助力实现数字化、智能化矿山建设。     

我国地下水质量分布特征浅析

以新一轮《全国地下水资源评价》项目为依托,以几十年地下水化学资料和水文地质资料为基础,对我国地下水质量进行了综合评价,阐述了我国地下水质量分布特征,简要分析了其成因,并提出了预防地下水水质恶化的建议。我国地下水质量总体状况较好,但局部质量低下,区域分布差异很大,是自然地理、地质、水文地质条件、人类活动等因素共同作用的结果。作者认为要想改善地下水质量就要合理开发利用地下水资源,合理布局工农业,并建立和完善地下水质量监测和预警系统。     

A Comparison of Nd Isotopes of Granitoids from the Central Asian Orogenic Belt and Qinling-Dabie Orogen,and Implications for Understanding of Crustal Growth from Accretion to Collision

正Orogens can generally be divided into two types:accretionary and collisional.The fundamental differences in deep-crustal compositions and architecture from accretion to collision and how to identify them is not well understood.This is one of the major aims of the IGCP 662 project (www.igcp662.org.cn).The Central Asian Orogenic Belt (CAOB) is a typical and the world's largest Phanerozoic accretionary orogenic belt and the     

山西新发现大理岩玉的宝石矿物学特征

山西北部六棱山地区新发现了一种玉石品种——大理岩玉,其主要有黄色和黄褐色两种颜色,结构较致密,透明度较好,是一种优质的饰面石材和玉雕原料。采用薄片观察、环境扫描电子显微镜、X射线粉末衍射、LA-ICP-MS和常规宝石学仪器等测试手段对该大理岩玉样品的宝石矿物学特征进行了测试与研究。结果显示,该大理岩玉为经变质作用形成的方解石大理岩,所含CaCO3的质量分数为96%～97%,推测Fe元素是该玉石的致色元素;微量的碳质和铁质粉末阻碍了柱状方解石的重结晶,形成条纹结构;方解石为不规则的多边形柱体,呈镶嵌的不规则他形变晶结构。通过分析大理岩玉的结构特征,认为平行于其层纹方向切磨,可使得其成品表面光洁度好,光泽强,不易破损。     

Results for Rarely Determined Elements in MPI-DING, USGS and NIST SRM Glasses Using Laser Ablation ICP-MS

New analytical results are reported for rarely determined elements Be, B, Ge, As, Mo, Rh, Pd, Ag, Cd, In, Sn, Sb, W, Re, Ir, Pt, Au, Tl and Bi in MPI‐DING and USGS (BCR‐2G, BHVO‐2G, BIR‐1G) silicate glasses and the NIST SRM 610‐614 synthetic soda‐lime glasses using 193 nm ArF excimer laser ablation and quadrupole ICP‐MS. The method used involved external calibration against GOR132‐G for Ir and NIST SRM 610 for other elements, internal standardisation using Ca, and ablation with a crater diameter of 160 μm and a pulsed laser repetition rate of 10 Hz. Small amounts of nitrogen (5 ml min^?1) were added to the central channel gas of the plasma to improve the limits of detection for most of these elements by a factor of 1.2–2.5 and to reduce the oxide interference level to 0.02% (ThO⁺/Th⁺). Under these conditions, the LODs for most of these rarely determined elements were within the range 0.1 to 10 ng g^?1. The operating conditions that were required to minimise ICP‐induced fractionation (U⁺/Th⁺≈ 1) in the mode without nitrogen were accompanied by a 50–60% reduction in sensitivity for elements such as Ca, Au and Pt. In contrast, ICP‐induced fractionation could be minimised (U⁺/Th⁺≈ 1) with no loss of analyte sensitivity in the nitrogen mode. Interferences of CuAr⁺, ZnAr⁺, Cd⁺, Pb²⁺ and Sn⁺ on Pd⁺, Rh⁺, Cd⁺ and In⁺ were corrected. Oxide interferences were not considered due to their lower production rate. Analytical precision, as given by one relative standard deviation (% RSD) was less than 15% for most of the elements present at concentrations greater than 0.1 μg g^?1. A significant negative correlation was found between logarithmic concentration and logarithmic RSD, with a correlation coefficient of ?0.76. This trend indicates that possible chemical heterogeneities for most of these elements are smaller than the analytical uncertainty. Our results for Be, B, Ge, Sb and W are generally in good agreement with their reference values. In contrast, other elements in many of the reference glasses have only information values, upper limits or even no values, which restrict any detailed evaluation of the accuracy of the determined values. However, concentrations from multiple isotopes of one element analysed in this study showed excellent agreement, which guarantee the quality of our data to a certain extent.