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941.
942.
四川乌斯河铅锌矿床成矿物质来源及矿床成因:来自原位S-Pb同位素证据 总被引:1,自引:0,他引:1
乌斯河铅锌矿床位于扬子板块西南缘,是川滇黔铅锌矿集区代表性大型铅锌矿床之一,估算资源量超过370万吨,Pb+Zn平均品位~15.7%。该矿床铅锌矿体主要呈层状、似层状、透镜状产于震旦系灯影组的白云岩地层中,其围岩蚀变较弱,以白云石化和方解石化为主。矿石类型主要包括块状、条带状、角砾状、脉状和浸染状等,其中矿物组成相对简单,以闪锌矿、方铅矿、白云石和方解石为主,含少量沥青和黄铁矿。该矿床地质地球化学研究程度相对较低,其成矿物质来源不清,致使该矿床存在热水沉积成因、喷流沉积-后期热液叠加改造以及MVT型等多种成因争议,难以建立统一成矿模式。本文对乌斯河铅锌矿床不同成矿阶段的硫化物(包括黄铁矿、闪锌矿和方铅矿),开展原位硫和铅同位素地球化学研究,以查明该矿床的成矿物质来源、还原硫的形成机制和示踪成矿过程,为认识该类矿床铅锌成矿作用提供新地球化学依据。原位S同位素分析结果显示,乌斯河铅锌矿床硫化物的还原硫存在不同硫来源,成矿早阶段硫化物δ34S值较低,介于+1.3‰~+14.2‰之间,暗示可能有来自于赋矿地层圈闭古油气系统中的H2S;主成矿阶段硫化物相对富集重硫同位素,δ34S值在+11.0‰~+23.3‰之间,表明其为赋矿地层的蒸发岩的热化学还原作用的产物。此外,硫化物的LA-MC-ICPMS原位Pb同位素组成分析显示,该矿床成矿金属元素主要来源于变质基底地层,水岩反应可能使赋矿地层贡献少量的成矿物质。综合矿区地质特征和已有的地球化学研究成果,本文认为乌斯河铅锌矿床属于MVT铅锌矿床,富Pb、Zn等成矿元素的流体与富H2S的流体混合是该矿床金属硫化物沉淀的主要机制。
相似文献943.
A combined in situ SIMS and LA-(MC)-ICPMS study of U-Pb ages, trace elements, O and Lu-Hf isotopes was conducted for zircon from eclogite-facies metamorphic rocks in the Sulu orogen. The two microbeam techniques sampled various depths of zircon domains, revealing different element and isotope relationships between residual magmatic cores and new metamorphic rims and thus the geochemical architecture of metamorphic zircons which otherwise cannot be recognized by the single microbeam technique. This enables discrimination of metamorphic growth from different subtypes of metamorphic recrystallization. Magmatic cores with U-Pb ages of 769 ± 9 Ma have positive δ18O values of 0.1-10.1‰, high Th/U and 176Lu/177Hf ratios, high REE contents, and steep MREE-HREE patterns with negative Eu anomalies. They are interpreted as crystallizing from positive δ18O magmas during protolith emplacement. In contrast, newly grown domains have concordant U-Pb ages of 204 ± 4 to 252 ± 7 Ma and show negative δ18O values of −10.0‰ to −2.2‰, low Th/U and 176Lu/177Hf ratios, low REE contents, and flat HREE patterns with weak to no Eu anomalies. They are interpreted as growing from negative δ18O fluids that were produced by metamorphic dehydration of high-T glacial-hydrothermally altered rocks during continental subduction-zone metamorphism. Differences in δ18O between different domains within single grains vary from 0.8‰ to 12.5‰, suggesting different degrees of O isotope exchange between the positive δ18O magmatic core and the negative δ18O metamorphic fluid during the metamorphism. The magmatic zircons underwent three subtypes of metamorphic recrystallization, depending on their accessibility to negative δ18O fluids. The zircons recrystallized in solid-state maintained positive δ18O values, and REE and Lu-Hf isotopes of protolith zircon, but their U-Pb ages are lowered. The zircons recrystallized through dissolution exhibit negative δ18O values similar to the metamorphic growths, almost completely reset U-Pb ages, and partially reset REE systems. The zircons recrystallized through replacement show variably negative δ18O values, and partially reset REE, and U-Pb and Lu-Hf isotopic systems. Therefore, this study places robust constraints on the origin of metamorphic zircons in eclogite-facies rocks and provides a methodological framework for linking the different types of metamorphic zircons to petrological processes during continental collision. 相似文献
944.
945.
Effects of cold eddy on phytoplankton production and assemblages in Luzon strait bordering the South China Sea 总被引:6,自引:0,他引:6
Yuh-Ling Lee Chen Houng-Yung Chen I. -I. Lin Ming-An Lee Jeng Chang 《Journal of Oceanography》2007,63(4):671-683
The biochemical effects of a cold-core eddy that was shed from the Kuroshio Current at the Luzon Strait bordering the South
China Sea (SCS) were studied in late spring, a relatively unproductive season in the SCS. The extent of the eddy was determined
by time-series images of SeaWiFS ocean color, AVHRR sea surface temperature, and TOPEX/Jason-1 sea surface height anomaly.
Nutrient budgets, nitrate-based new production, primary production, and phytoplankton assemblages were compared between the
eddy and its surrounding Kuroshio and SCS waters. The enhanced productivity in the eddy was comparable to wintertime productivity
in the SCS basin, which is supported by upwelled subsurface nitrate under the prevailing Northeastern Monsoon. There were
more Synechococcus, pico-eucaryotes, and diatoms, but less Trichodesmium in the surface water inside the eddy than outside. Prochlorococcus and Richelia intracellularis showed no spatial differences. Water column-integrated primary production (IPP) inside the eddy was 2–3 times that outside
the eddy in the SCS (1.09 vs. 0.59 g C m−2d−1), as was nitrate-based new production (INP) (0.67 vs. 0.25 g C m−2d−1). INP in the eddy was 6 times that in the Kuroshio (0.12 g C m−2d−1). IPP and INP in the eddy were higher than the maximum production values ever measured in the SCS basin. Surface chlorophyll
a concentration (0.40 mg m−3) in the eddy equaled the maximum concentration registered for the SCS basin and was higher than the wintertime average (0.29
± 0.04 mg m−3). INP was 3.5 times as great and IPP was doubled in the eddy compared to the wintertime SCS basin. As cold core eddies form
intermittently all year round as the Kuroshio invades the SCS, their effects on phytoplankton productivity and assemblages
are likely to have important influences on the biogeochemical cycle of the region. 相似文献
946.
错流超滤技术在海水胶体态铀、钍、镭同位素和有机碳研究中的应用 总被引:14,自引:3,他引:14
建立了由预过滤装置、蠕动泵、中空纤维超滤膜(AmiconH10P10-20,标称截留分子量10KDa)和连接管组成的错流超滤系统,利用荧光标记的40KDa葡聚糖和已知放射性活度的234Th示踪剂评估了超滤膜的截留和吸附性质,探讨了234Th在超滤过程中的渗透行为,考查了该系统用于实际海水样品时铀、钍、镭同位素和有机碳的质量平衡状况.结果表明,10Kda中空纤维超滤膜对40Kda葡聚糖具有良好的截留效率(85%),而吸附损失率为18%.铀、钍、镭同位素和有机碳在超滤过程中均达到极佳的质量平衡,回收率R=95%~98%,优于大多数文献报道的值.234Th在超滤过程中的渗透行为可以很好地用渗透模型加以描述.研究组分胶体态含量占“溶解”态含量的份额大小顺序如下:钍同位素、有机碳、镭同位素约等于铀同位素,这与钍为强颗粒活性元素、铀和镭为水溶性元素的地球化学性质相吻合. 相似文献
947.
Evaluating the sensitivity of wetlands to climate change with remote sensing techniques 总被引:1,自引:0,他引:1 下载免费PDF全文
Wetlands are valuable ecosystems that provide many valuable services, yet many of these important ecosystems are at risk because of current trends in climate change. The Prairie Pothole Region (PPR) in the upper‐midwest of the United States and south‐central Canada, characterized by glacially sculpted landscapes and abundant wetlands, is one such vulnerable region. According to regional/global climate model predictions, drought occurrence will increase in the PPR region through the 21st century and thus will probably cause the amount of water in wetlands to decline. Water surface area (WSA) of Kidder County, ND, from 1984–2011 was measured by classifying TM/ETM+(Landsat Thematic Mapper / Enhanced Thematic Mapper Plus) images through the modified normalized difference water index. We then developed a linear model based on the WSA of these wetlands and historical climate data and used this to determine the wetland sensitivity to climate change and predict future wetlands WSA in the PPR. Our model based on Palmer drought severity index (PDSI) of the current year (PDSIt ? 0) and of the previous two years (PDSIt ? 2) can explain 79% of the annual wetland WSA variance, suggesting a high sensitivity of wetlands to drought/climate change. We also predicted the PPR wetlands WSA in the 21st century under A1B scenario (a mid‐carbon emission scenario) using simulated PDSI based on Intergovernmental Panel on Climate Change AR4 22‐model ensemble climate. According to our prediction, the WSA of the PPR wetlands will decrease to less than half of the baseline WSA (defined as the mean wetlands WSA of the 2000s) by the mid of the 21st century, and to less than one‐third by the 2080s, and will then slightly increase in the 2090s. This considerable future wetland loss caused only by climate change provides important implication to future wetland management and climate adaptation policy. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
948.
为加强浙东南山区滑坡灾害防治工作,在分析该区山外高速滑坡和南充高速滑坡的物质结构和和运动特征的基础上,总结该区高速滑坡的形成原因、致灾原因和致灾方式.高陡原始地形伴随人工切坡,岩体超深风化,台风引起超强降雨.以及峰残强度降差形成滑坡;高速和远程是致灾的主要原因;致灾方式包括堆积掩理、抛洒冲击和气浪推掀. 相似文献
949.
950.
Yu-Xin Fan Fa-Hu Chen Guo-Xiao Wei David B. Madsen Charles G. Oviatt Hui Zhao Xi Chun Li-Ping Yang Tian-Lai Fan Guo-Qiang Li 《Journal of Paleolimnology》2010,43(3):577-587
Lake Jilantai-Hetao, a megalake, was formed some time before 60–50 ka, along the Great North Bend of the Yellow River. The
basin is now dry, with most of the area covered by aeolian sand. We are investigating this profound hydrologic change using
a number of research approaches. Paleoshorelines of this megalake are best preserved in the Jilantai area in the southwestern
portion of the megalake basin. We collected aquatic mollusk shells from littoral sediments at different altitudes around Jilantai
and measured their strontium isotope compositions. 87Sr/86Sr ratios in shell carbonates are different between the high lake phase (~1,080–1,050 m altitude) and the low lake phase (~1,044–1,030 m
altitude), with a small shift in average strontium ratios to more radiogenic values during the low lake phase. Based on regional
hydrology and physical geography, we conclude that water from the Yellow River was the dominant water source supplying this
megalake. 87Sr/86Sr ratios of modern water samples suggest the Yellow River was the dominant water source during the high lake phase, but that
the relative contribution of Yellow River water to the megalake was reduced, and that the relative contributions of local
precipitation and groundwater increased, during the low lake phase. 相似文献