Kinetic,equilibrium and thermodynamic studies of thiamethoxam adsorption by multi-walled carbon nanotubes

Because of their high adsorption capacity, carbon nanotubes have caught the attention of the scientific community and a number of experimental results confirmed their ability to adsorb many toxins from water. The aim of this work was to study the kinetics, equilibrium and thermodynamics of thiamethoxam adsorption by multi-walled carbon nanotubes in aqueous solutions. To further elucidate the influence of nanotube structure on the adsorption mechanism, the experiments were performed on both fresh (pristine) and nitric acid-modified multi-walled carbon nanotubes. The results of the kinetic studies were analyzed using three kinetic models, while the adsorption equilibrium was tested against four different adsorption models. Based on the results, and the physico-chemical properties of the adsorbent and adsorbate, it is proposed that the dominant mechanism for thiamethoxam molecules attaching to multi-walled carbon nanotubes is caused by aromatic π–π interactions (electron donor–acceptor interactions). The results of thermodynamic calculations based on the adsorption data indicate the exothermic nature of the process, regardless of the carbon nanotube type used. The decrease in entropy and the consequent negative change in Gibbs free energy, as expected, confirm the spontaneity of thiamethoxam adsorption on both pristine and functionalized multi-walled carbon nanotubes.     

New seismic images of the crust in the central Trans-Hudson Orogen of Saskatchewan

A reprocessing program to enhance the correlation between the surface geology and the seismic data has been completed for seismic line 9 (eastern 100 km) and line 10 in the central region of the Trans-Hudson Orogen of Saskatchewan, Canada. The new seismic images through lateral continuity of reflectivity provide sufficient detail to resolve the discrepancy between the low-dipping, layer-parallel and dextral-reverse nature of the Sturgeon-Weir shear zone (line 9) observed in the field and its steeply dipping (apparent) normal displacement character interpreted on the basis of the initial processing. Furthermore, the new interpretation provides a strong confirmation of the role of Pelican Thrust as a major detachment zone — the main `sole thrust' — along which juvenile allochthons have been carried across the Archaean microcontinental block. The images are also refined enough to suggest: (a) a boundary within the Pelican Thrust between its internal and external suites; (b) a possible boundary separating a lower (older?) Archaean basement from its upper (younger?) counterpart; and (c) sub-Moho events (M2) which reveal possible involvement of the upper mantle in the collisional tectonic process in addition to the well defined Moho (M1) which probably represents the youngest of the post-collisional detachments.     

Controlling factors of groundwater hydrochemistry in a small island’s aquifer

Factor analysis was applied to the hydrochemical data set of Manukan Island in order to extract the principal factors corresponding to the different sources of variation in the hydrochemistry. The application of varimax rotation was to ensure the clear definition of the main sources of variation in the hydrochemistry. The geochemical data of dissolved major, minor and trace constituents in the groundwater samples indicates the main processes responsible for the geochemistry evolution. By using Kaiser normalization, principal factors were extracted from the data for each location. The analysis reveals that there are four sources of solutes: (1) seawater intrusion; (2) leaching process of underlying rock mediated by pH; (3) minerals weathering process and (4) dissolution of carbonate minerals characterized by high loadings of Ca, Zn and Mg. Such processes are dominated by the significant role of anthropogenic impact from the over abstraction of fresh water from the aquifer. Those factors contributed to the changes of the groundwater geochemistry behavior explain the effect of rising extraction of freshwater from the aquifer.     

Paleoproterozoic accretion in the Northeast Siberian craton: Isotopic dating of the Anabar collision system

Geochronological database considered in the work and characterizing the Anabar collision system in the Northeast Siberian craton includes coordinated results of Sm-Nd and Rb-Sr dating of samples from crustal xenoliths in kimberlites, deep drill holes, and bedrock outcrops. As is inferred, collision developed in three stages dated at 2200–2100, 1940–1760, and 1710–1630 Ma. The age of 2000–1960 Ma is established for substratum of mafic rocks, which probably originated during the lower crust interaction with asthenosphere due to the local collapse of the collision prism. Comparison of Sm-Nd and Rb-Sr isochron dates shows that the system cooling from ≈700 to ≈300°C lasted approximately 300 m.y. with a substantial lag relative to collision metamorphism and granite formation. It is assumed that accretion of the Siberian craton resulted in formation of a giant collision mountainous structure of the Himalayan type that was eroded by 1.65 Ga ago, when accumulation of gently dipping Meso-to Neoproterozoic (Riphean) platform cover commenced.     

Palaeomagnetic results from the ca. 1130 Ma Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, Antarctica, and tectonic implications

Detailed palaeomagnetic and rock magnetic analyses provide improved palaeomagnetic results from 23 sites in the Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, East Antarctica. These intrusions are of similar age to their host, the ca. 1130 Ma Ritscherflya Supergroup (RSG). A mean direction of D=235.4°, I=−7.6° with k=45.9 and α₉₅=4.5° was obtained from this study. When combined with previously reported results from 11 sites in the same region, including sites from the Ritscherflya Supergroup, it gives an overall mean direction for 34 sites from the igneous suite with D=236.5°, I=−3.6°, k=27.9 and α₉₅=4.8°. Isothermal remanent magnetization (IRM) experiments on several specimens suggest magnetite or titanomagnetite as the primary remanence carrier, while high temperature magnetic susceptibility experiments indicate the presence of single domain particles. These observations, together with field evidence and the high coercivities and unblocking temperatures, support a primary origin for the observed characteristic remanence. The Borgmassivet palaeomagnetic pole lies at 54.5°E, 8.3°N with A₉₅=3.3°. If Antarctica is moved to its Gondwanan position adjacent to southeast Africa, the Borgmassivet pole (BM) coincides with that of the African well-established, well-dated (1100 Ma) Umkondo Large Igneous Province pole, supporting the hypothesis that the Grunehogna craton of Dronning Maud Land was part of the Kalahari craton of southern Africa at ca. 1100 Ma.     

Age of the Ust’-Gilyui sequence in the Stanovoi Complex of the Selenga-Stanovoi Superterrain, Central Asian fold belt

According to the results of U-Pb geochronological investigations, the age of the amphibolite protoliths (metabasalts) in the Ust??-Gilyui sequence within the Stanovoi Complex of the Amazar-Gilyui structural and formational zone in the Selenga-Stanovoi Superterrain of the Central Asian fold belt can be estimated at 193 ± 1 Ma. The Nd model age of the Ust??-Gilyui metasedimentary rocks is in the interval of t _Nd(DM) = 1.1?C3.1 Ga. This information along with the previously obtained geochronological data are indicative of the fact that the Ust??-Gilyui sequence consists of metasedimentary and metavolcanic rocks of various ages: (1) volcanic rocks with the age of 193 ± 1 Ma; (2) metasedimentary and metavolcanic rocks broken through by the Paleozoic granitoids dated to 370 Ma and characterized by minimum estimations of t _Nd(DM) = 1.1 Ga, i.e., rocks with an age of 1.1?C0.4 Ga. In addition, it is quite possible that this sequence also includes more ancient rocks. The SSS Amazar-Gilyui structural and formational zone is likely to be a tectonic mélange composed of the metasedimentary and metavolcanic rocks of the Mesozoic and, probably, Paleozoic and Early Precambrian ages. The studied zone was formed in the Mesozoic, most likely, in the course of the collision processes initiated by the closing up of the Mongol-Okhotsk Ocean.     

Composition, sources, and mechanism of continental crust growth in the Lake zone of the Central Asian Caledonides: I. Geological and geochronological data

Data on the composition, inner structure, and age of volcanic and siliceous-terrigenous complexes and granitoids occurring in association with them in the Caledonian Lake zone in Central Asia are discussed in the context of major relations and trends in the growth of the Caledonian continental crust in the Central Asian Foldbelt (CAFB). The folded structures of the Lake zone host basalt, basalt-andesite, and andesite complexes of volcanic rocks that were formed in distinct geodynamic environments. The volcanic rocks of the basalt complex are noted for high concentrations of TiO₂ and alkalis, occur in association with fine-grained siliceous siltstone and siliceous-carbonate rocks, are thus close to oceanic-island complexes, and were likely formed in relation to a mantle hotspot activity far away from erosion regions supplying terrigenous material. The rocks of the basalt-andesite and andesite complexes have lower TiO₂ concentrations and moderate concentrations of alkalis and contain rock-forming amphibole. These rocks are accompanied by rudaceous terrigenous sediments, which suggests their origin in island-arc environments, including arcs with a significantly dissected topography. These complexes are accompanied by siliceous-terrigenous sedimentary sequences whose inner structure is close to those of sediments in accretionary wedges. The folded Caledonides of the Lake zone passed through the following evolutionary phases. The island arcs started to develop at 570 Ma, their evolution was associated with the emplacement of layered gabbroids and tonalitetrondhjemite massifs, and continued until the onset of accretion at 515–480 Ma. The accretion was accompanied by the emplacement of large massifs of the tonalite-granodiorite-plagiogranite series. The postaccretionary evolutionary phase at 470–440 Ma of the Caledonides was marked by intrusive subalkaline and alkaline magmatism. The Caledonides are characterized by within-plate magmatic activity throughout their whole evolutionary history, a fact explained by the accretion of Vendian-Cambrian oceanic structures (island arcs, oceanic islands, and back-arc basins) above a mantle hotspot. Indicators of within-plate magmatic activity are subalkaline high-Ti basalts, alkaline-ultrabasic complexes with carbonatites and massifs of subalkaline and alkaline gabbroids, nepheline syenites, alkaline granites, subalkaline granites, and granosyenites. The mantle hotspot likely continued to affect the character of the lithospheric magmatism even after the Caledonian folded terrane was formed.     

Logarithmic density range and the percentage of stars in the cores of various subsystems of the globular clusters M56, M12, NGC 6535, NGC 6171, NGC 5466, and M92

Lower limits for the percentages of stars with various luminosities in the cores of six globular clusters are derived using stellar spatial density distributions f(r) to deep limiting B magnitudes obtained earlier. For NGC 6535 and NGC 5466, the logarithmic density range and Kholopov parameters D_f and D_r are also determined. These two parameters are correlated with the mean masses of stars of various subsystems and the total mass (number) of stars in the cluster.     

Numerical investigation of internal waves in jet streams including nonlinear effects

Internal waves in an atmospheric jet stream are discussed, using both linear and non-linear theory. In the former case., the wave phase-speeds depend only on the total static stability in the jet stream layer. In the latter case, the temperature profile curvature plays the main role in the behaviour of gravity-type waves.