Radial growth rates and Pb ages of hydrothermal massive sulfides from the Juan de Fuca Ridge

Activities of ²³⁸U, ²²⁸Ra, ²²⁶Ra and ²¹⁰Pb were determined in submarine hydrothermal massive sulfides by nondestructive, gamma-ray spectrometry. The samples were collected by the manned submersible DSRV “Alvin” from active hydrothermal fields on the Endeavour Segment and Axial Seamount of the Juan de Fuca Ridge. ²¹⁰Pb activities are mostly below the equilibrium level with ²²⁶Ra, which is linearly correlated with the concentration of Ba, Sr and Ca in the deposits. The ratios of²²⁶Ra to the alkaline earth elements indicate that hydrothermal alteration of the underlying oceanic crust is the dominant source of Ra in the sulfide deposits.The ²¹⁰Pb/Pb ratios measured in many of the sulfides are higher than the ratio obtained for a basalt source of ²¹⁰Pb, probably because of ²¹⁰Pb ingrowth from ²²⁶Ra within the sulfide deposits. An isochron approach employing ratios of ²¹⁰Pb/Pb and ²²⁶Ra/Pb yielded an initial ²¹⁰Pb/Pb ratio in the range of 0–0.57 dpm/μg Pb, implying that the crustal residence time of the hydrothermal fluid in the Endeavour Segment is very short ( < 10 years) and that basalt alteration is the only source of the ²¹⁰Pb and Pb. For the hydrothermal fluid in Axial Seamount, a residence time of 10–20 years is estimated on the basis of the initial ²¹⁰Pb/Pb and ²²⁸Ra/²²⁶Ra ratios of a sulfide chimney. Both residence time estimates are consistent with the results of previous studies. We have estimated the upper limits of sample ages ranging from tens to a hundred years for 12 samples, with the remaining seven samples indicating ages close to or older than 150 years, the practical limit of the ²¹⁰Pb/Pb dating technique.A concentrically sectioned sulfide chimney from Axial Seamount yielded mean radial growth rates ranging from a few tenths to a few mm/year based on gradients of ²¹⁰Pb/Pb and ²²⁸Ra/²²⁶Ra activity ratios, whereas a similarly sectioned chimney from the Endeavour Segment, although collected from the top of an active “black smoker” vent, displayed no ²¹⁰Pb or ²²⁸Ra activity. Our results have implications for the duration and periodicity of hydrothermal circulation and associated mineral deposition at mid-ocean ridges.     

Demersally drifting invertebrates from Kongsfjorden,Svalbård (Arctic Ocean)–a comparison of catches from drift-pump and drift-nets

Demersally drifting organisms were collected at Ny Ålesund (Svalbård–Arctic Ocean) to study the taxon composition and relative abundances in the Arctic summer. Catch potentials of two collection devices for demersal drift were compared. A lowvolume submersible drift-pump and a drift-net unit were employed for the collection of demersally drifting biota, particularly for shallow aquatic habitats. With the exception of Appendicularia, Chaetognatha, Coelenterata, and Ctenophora, which were damaged at times, the pump catches were in good condition and sufficient for identification and quantification of less mobile fauna. A comparison of the two devices revealed that the drift-pump collected more specimens than the drift-net. However, the drift-net may have caused an underestimation of the abundances of invertebrates. No differences in identified taxon number and indices of richness, evenness and diversity were found. However, the proportion of invertebrate animals in the two devices was different for the three groups: zooplankton, macrofauna and meiofauna. At Svalbård, zooplankton, larvae of macrofauna, and meiofauna were successfully collected by the two collecting devices. However, the catchibility of the two devices in collecting various invertebrate taxa was different and, therefore, a sound ‘Device Effect’ was revealed.     

Effects of natural and calcined oyster shells on Cd and Pb immobilization in contaminated soils

In Korea, soils adjacent to abandoned mines are commonly contaminated by heavy metals present in mine tailings. Further, the disposal of oyster shell waste by oyster farm industries has been associated with serious environmental problems. In this study, we attempted to remediate cadmium (Cd)- and lead (Pb)-contaminated soils typical of those commonly found adjacent to abandoned mines using oyster shell waste as a soil stabilizer. Natural oyster shell powder (NOSP) and calcined oyster shell powder (COSP) were applied as soil amendments to immobilize Cd and Pb. The primary components of NOSP and COSP are calcium carbonate (CaCO₃) and calcium oxide (CaO), respectively. X-ray diffraction, X-ray fluorescence and scanning electron microscope analyses conducted in this study revealed that the calcination of NOSP at 770°C converted the less reactive CaCO₃ to the more reactive CaO. The calcination process also decreased the sodium content in COSP, indicating that it was advantageous to use COSP as a liming material in agricultural soil. After 30 days of incubation, we found that the 0.1 N HCl-extractable Cd and Pb contents in soil decreased significantly as a result of an increase in the soil pH and the formation of metal hydroxides. COSP was more effective in immobilizing Cd and Pb in the contaminated soil than NOSP. Overall, the results of this study suggest that oyster shell waste can be recycled into an effective soil ameliorant.     

Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.     

Strategically Locating Wildlife Crossing Structures for Florida Panthers Using Maximal Covering Approaches

Crossing structures are an effective method for mitigating habitat fragmentation and reducing wildlife‐vehicle collisions, although high construction costs limit the number that can be implemented in practice. Therefore, optimizing the placement of crossing structures in road networks is suggested as a strategic conservation planning method. This research explores two approaches for using the maximal covering location problem (MCLP) to determine optimal sites to install new wildlife crossing structures. The first approach is based on records of traffic mortality, while the second uses animal tracking data for the species of interest. The objective of the first is to cover the maximum number of collision sites, given a specified number of proposed structures to build, while the second covers as many animal tracking locations as possible under a similar scenario. These two approaches were used to locate potential wildlife crossing structures for endangered Florida panthers (Puma concolor coryi) in Collier, Lee, and Hendry Counties, Florida, a population whose survival is threatened by excessive traffic mortality. Historical traffic mortality records and an extensive radio‐tracking dataset were used in the analyses. Although the two approaches largely select different sites for crossing structures, both models highlight key locations in the landscape where these structures can remedy traffic mortality and habitat fragmentation. These applications demonstrate how the MCLP can serve as a useful conservation planning tool when traffic mortality or animal tracking data are available to researchers.     

Flows within the Ekman layer during spin-up of a thermally stratified fluid

Abstract

Finite-difference numerical solutions were obtained to present the flow and temperature field details within the transient Ekman layer during spin-up of a thermally stratified fluid in a cylinder. This complements the earlier studies on stratified spin-up which examined the flows in the interior core region. As the stratification increases, the following changes in the flow field are noticeable. The radial velocity in the Ekman layer decreases in magnitude. The azimuthal flows adjust smoothly from the interior region to the endwall boundary, and the Ekman layer in the azimuthal flow field fades. Vertical motions are inhibited, resulting in a weakened Ekman pumping. The axial vorticity field behaves similarly to the azimuthal flows. The temperature deviation from the equilibrium profile decreases, and the heat transfer flux from the endwall to the fluid decreases. The thickness of the thermal layer is larger than the velocity layer thickness. Illustrative comparisons of the relative sizes of the terms in the governing equations are conducted in order to assess the stratification effect in the adjustment process of the fluid.     

Electric charge and magnetic flux on rotating black holes in a force-free magnetosphere

The electric charge on rotating black holes is calculated to be ∼ BJ in the force-free configuration of Ghosh, with a horizon flux of ∼ BM ². This charge is gravitationally weak for B ∼10¹⁵ G , so that the Kerr metric applies. Being similar to the electric charge of a magnetar, both electric charge and magnetic flux should be, in sign and order of magnitude, continuous during stellar collapse into a black hole. Extraction of the rotational energy from newly formed black holes may proceed by interaction with the magnetic field.     

Effect of doubling the ensemble size on the performance of ensemble prediction in the warm season using MOGREPS implemented at the KMA

Using the Met Office Global and Regional Ensemble Prediction System (MOGREPS) implemented at the Korea Meteorological Administration (KMA), the effect of doubling the ensemble size on the performance of ensemble prediction in the warm season was evaluated. Because a finite ensemble size causes sampling error in the full forecast probability distribution function (PDF), ensemble size is closely related to the efficiency of the ensemble prediction system. Prediction capability according to doubling the ensemble size was evaluated by increasing the number of ensembles from 24 to 48 in MOGREPS implemented at the KMA. The initial analysis perturbations generated by the Ensemble Transform Kalman Filter (ETKF) were integrated for 10 days from 22 May to 23 June 2009. Several statistical verification scores were used to measure the accuracy, reliability, and resolution of ensemble probabilistic forecasts for 24 and 48 ensemble member forecasts. Even though the results were not significant, the accuracy of ensemble prediction improved slightly as ensemble size increased, especially for longer forecast times in the Northern Hemisphere. While increasing the number of ensemble members resulted in a slight improvement in resolution as forecast time increased, inconsistent results were obtained for the scores assessing the reliability of ensemble prediction. The overall performance of ensemble prediction in terms of accuracy, resolution, and reliability increased slightly with ensemble size, especially for longer forecast times.     

Relative contributions of sulfate- and iron(III) reduction to organic matter mineralization and process controls in contrasting habitats of the Georgia saltmarsh

The objectives of this study were to partition out the predominant anaerobic respiration pathways coupled to C oxidation and to further elucidate the controls of anaerobic C respiration in three major saltmarsh habitats at Skidaway Island, GA; the short form of Spartina alterniflora (SS), the tall form of S. alterniflora (TS), and unvegetated, bioturbated creekbank (CB). Geochemical analysis of pore water and solid phase constituents revealed that the SS site experienced highly reducing conditions with two orders of magnitude higher pore water sulfide inventories (1.884 mmol m⁻²) than TS (0.003 mmol m⁻²) and CB (0.005 mmol m⁻²), respectively. Conversely, reactive Fe(III) inventories at TS (2208 mmol m⁻²) and CB (2881 mmol m⁻²) were up to 7–9 times higher than at SS (338 mmol m⁻²). Incubations and intact core experiments indicated that reduction accounted for 95% (SS), 37% (TS) and 66% (CB) of total anaerobic respiration. There was no detectable Fe(III) reduction at SS, while Fe(III) reduction accounted for up to 70% of C oxidation in the 3–6 cm depth interval at TS and 0–3 cm depth of CB, and on average, approximately 55% of C oxidation over two-thirds of marsh surface area. Laboratory manipulations provided further evidence for the importance of Fe(III) reduction as the accumulation rates of fermentation products were high when Fe(III) reduction was inhibited by removing the Fe(III) minerals from highly bioturbated CB sediments with higher Fe(III) mineral contents. Anaerobic C oxidation, - and Fe(III)-reduction rates appeared to be highest at the TS site during active plant growth in summer. Overall results suggest that bioturbation by macrofauna is the overriding factor in modulating the pathway of C mineralization in the saltmarsh, whereas availability of organic substrates from plants is a key factor in controlling the C oxidation rate.