Subsurface thermal conductivity assessment in Calabria (southern Italy): a regional case study

Determining the suitability of a local area at a regional or local scale for the geothermal application of low enthalpy systems requires the knowledge of rock thermal conductivity values to evaluate the possibility of low-enthalpy heat exchange. A digital cartographic tool is also needed to synthesize the thermal properties of the underground. This tool should be easily accessible and upgradeable and thus suitable for territorial planning and environmental control. In order to address these key issues, a methodological approach was developed within the framework of the national VIGOR Project, dedicated to evaluating the geothermal potential in southern Italy. In this paper the region of Calabria was selected as a case study. Around 70 samples that were representative of the main geological formations were collected from all over the area. Thermal property tests were carried out both in dry and wet conditions, using a thermal device in accordance with the modified transient plane source method. The thermal conductivity values were then compared with data from the international literature. In order to consider the influence of the entire stratigraphic sequence on the thermal conductivity parameters, a geostatistical analysis of the available lithostratigraphic data was performed using the MATLAB toolbox Modalstrata, specially developed for this purpose. A comprehensive geothermal subsurface characterization of Calabria was thus obtained.     

Hazard assessment at San Martín volcano based on geological record, numerical modeling, and spatial analysis

The San Martín shield volcano, located in the Los Tuxtlas Volcanic Field, has experienced effusive shield-building activity, as well as explosive eruptions, as evidenced by direct observations during the last eruption in 1793. The threat to the surrounding villages consists principally of lahars, especially because of the tropical climate in the region. Ash fallout and lava flows represent additional hazards. In addition, the surrounding Quaternary monogenetic field includes more than 300 scoria cones and about 40 explosion craters (mainly maars) that also represent a hazard source. In the present study we constructed hazard maps using field data, orthophotos, spatial analysis, and specialized software (LAHARZ and HAZMAP) to deliminate lahar inundation zones, areas that could potentially be affected by ash fallout (including the evaluation of houses prone to roof collapse due to ash load), and the most susceptible areas for hosting future monogenetic vent formation.     

High precision symplectic integrators for the Solar System

Using a Newtonian model of the Solar System with all 8 planets, we perform extensive tests on various symplectic integrators of high orders, searching for the best splitting scheme for long term studies in the Solar System. These comparisons are made in Jacobi and heliocentric coordinates and the implementation of the algorithms is fully detailed for practical use. We conclude that high order integrators should be privileged, with a preference for the new $(10,6,4)$ method of Blanes et al. (2013).     

Vestan lithologies mapped by the visual and infrared spectrometer on Dawn

We present global lithological maps of the Vestan surface based on Dawn mission's Visible InfraRed (VIR) Spectrometer acquisitions with a spatial sampling of 200 m. The maps confirm the results obtained with the data set acquired by VIR with a spatial sampling of 700 m, that the reflectance spectra of Vesta's surface are dominated by pyroxene absorptions that can be interpreted within the context of the distribution of howardites, eucrites, and diogenites (HEDs). The maps also partially agree with the ground and Hubble Space Telescope observations: they confirm the background surface being an assemblage of howardite or polymict eucrite, as well as the location of a diogenitic‐rich spot; however, there is no evidence of extended olivine‐rich regions in the equatorial latitudes. Diogenite is revealed on the Rheasilvia basin floor, indicating that material of the lower crust/mantle was exposed. VIR also detected diogenites along the scarp of Matronalia Rupes, and the rims of Severina and a nearby, unnamed crater, and as ejecta of Antonia crater. The diogenite distribution is fully consistent with petrological constraints; although the mapped distribution does not provide unambiguous constraints, it favors the hypothesis of a magma ocean.     

GOLD’s coating and testing facilities for ISSIS-WSO

The interaction between Ricci scalar curvature and the baryon number current, dynamically breaks CPT in an expanding universe and leads to baryon asymmetry. Using this kind of interaction and study the gravitational baryogenesis in the Bianchi type I universe. We find out the effect of anisotropy of the universe on the baryon asymmetry for the case which the equation of state parameter, ω, varies with time.     

Assessing spectral evidence of aqueous activity in two putative martian paleolakes

We evaluate the evidence for the presence of mineral spectral signatures indicative of the past presence of water at two putative paleolakes on Mars using observations by the Mars Reconnaissance Orbiter (MRO) Compact Reconnaissance Image Spectrometer for Mars (CRISM). CRISM spectra of both sites are consistent with laboratory spectra of Mg-rich phyllosilicates. Our analysis represents the first detailed evaluation of these locations. The spatial occurrence and association with topographic features within the craters is distinctly different for the two sites. The occurrence of these minerals supports the conclusion that water was once active in the areas sampled by these craters. The distribution of the phyllosilicates in Luqa does not provide distinctive evidence for the presence of a previous standing body of water and is consistent with either impact emplacement or post-impact alteration. For Cankuzo, the phyllosilicate distribution provides evidence of a layer in the crater wall indicative of aqueous activity, but does not require a paleolake.     

Explicit adaptive symplectic integrators for solving Hamiltonian systems

We consider Sundman and Poincaré transformations for the long-time numerical integration of Hamiltonian systems whose evolution occurs at different time scales. The transformed systems are numerically integrated using explicit symplectic methods. The schemes we consider are explicit symplectic methods with adaptive time steps and they generalise other methods from the literature, while exhibiting a high performance. The Sundman transformation can also be used on non-Hamiltonian systems while the Poincaré transformation can be used, in some cases, with more efficient symplectic integrators. The performance of both transformations with different symplectic methods is analysed on several numerical examples.     

Anodic Oxidation as Green Alternative for Removing Diethyl Phthalate from Wastewater Using Pb/PbO2 and Ti/SnO2 Anodes

The electrochemical oxidation (EO) of diethyl phthalate (DEP) in aqueous solution was studied at Pb/PbO₂ and Ti/SnO₂ anode materials under galvanostatic‐experimental conditions. Results obtained clearly demonstrated that the anode plays a significant role for the optimization of the oxidation process, deciding the mechanisms and by‐products formed. DEP and by‐products of oxidation were also analyzed during various stages of the electrolysis reaction by HPLC and GC/MS techniques. Before the analysis by GC/MS technique, the samples were treated by solid phase microextraction (SPME) in order to concentrate the compounds from the reaction solution and identify all electrolysis intermediates. Current efficiencies (instantaneous current efficiency; ICE and total current efficiency; TCE) achieved during EO experiments were dependent on anode used and current density (20–40 mA cm^?2) at 40°C. The results obtained demonstrated that the environmental electrochemical methods can be a feasible alternative for the wastewater treatment containing hazardous phthalates.     

Solar-Terrestrial Signal Record in Tree Ring Width Time Series from Brazil

This work investigates the behavior of the sunspot number and Southern Oscillation Index (SOI) signal recorded in the tree ring time series for three different locations in Brazil: Humaitá in Amaz?nia State, Porto Ferreira in S?o Paulo State, and Passo Fundo in Rio Grande do Sul State, using wavelet and cross-wavelet analysis techniques. The wavelet spectra of tree ring time series showed signs of 11 and 22?years, possibly related to the solar activity, and periods of 2–8?years, possibly related to El Ni?o events. The cross-wavelet spectra for all tree ring time series from Brazil present a significant response to the 11-year solar cycle in the time interval between 1921 to after 1981. These tree ring time series still have a response to the second harmonic of the solar cycle (5.5?years), but in different time intervals. The cross-wavelet maps also showed that the relationship between the SOI x tree ring time series is more intense, for oscillation in the range of 4–8?years.