High spatial resolution sampling of metals in the sediment and water column in Port Jefferson Harbor, New York

Eighteen sediment samples and six water-column samples were collected in a small (6 km²), coastal embayment (Port Jefferson Harbor, New York) to define a high-resolution spatial distribution of metals and to elucidate sources of contaminants to the harbor. Sediment metal (Ag, Cu, Fe, Ni, Pb, V, and Zn) concentrations varied widely, reflecting differences in sediment grain size, with higher metal concentrations located in the fine-grained inner harbor sediments. Calculated enrichment factors for these sediments show that Ag, Pb, Cu, and Zn are elevated relative to both crustal abundances and their respective abundances in sediments in central Long Island Sound. Metal concentrations were 1.2 to 10 fold greater in water from the inner harbor compared to water from Long Island Sound collected outside the mouth of the harbor. Spatial variations in trace metals in surface waters within the bay parallel the spatial variations of trace metals in sediments within the harbor. Elevated water-column metal concentrations appear to be partially derived from a combination of diagenetic remobilization from contaminated sediments (e.g., Ag) and anthropogenic sources (e.g., Cu and Zn) within the southern portions of the harbor. Although the National Status and Trends Program had reported previously that sediment metal concentrations in Port Jefferson Harbor were low, the results of this study show sediment metals have high spatial variability and are enriched in the inner harbor sediments at levels comparable to more urbanized western north shore Long Island harbors.     

Origin and interaction of mafic and felsic magmas in an evolving late orogenic setting: the Early Paleozoic Terra Nova Intrusive Complex, Antarctica

The Abbott Unit (∼508 Ma) and the Vegetation Unit (∼475 Ma) of the Terra Nova Intrusive Complex (northern Victoria Land, Antarctica) represent the latest magmatic events related to the Early Paleozoic Ross Orogeny. They show different emplacement styles and depths, ranging from forcible at 0.4–0.5 GPa for the Abbott Unit to passive at ∼0.2 GPa for the Vegetation Unit. Both units consist of mafic, felsic and intermediate facies which collectively define continuous chemical trends. The most mafic rocks from both units show different enrichment in trace element and Sr-Nd isotopic signatures. Once the possible effects of upper crustal assimilation-fractional crystallisation (AFC) and lower crustal coupled AFC and magma refilling processes have been taken into account the following features are recognised: (1) the modelled primary Abbott Unit magma shows a slightly enriched incompatible element distribution, similar to common continental arc basalts and (2) the modelled primary Vegetation Unit magma displays highly enriched isotope ratios and incompatible element patterns. We interpreted these major changes in magmatic affinity and emplacement style as linked to a major change in the tectonic setting affecting melt generation, rise and emplacement of the magmas. The Abbott Unit mafic melts were derived from a mantle wedge above a subduction zone, with subcontinental lithospheric mantle marginally involved in the melting column. The Vegetation Unit mafic melts are regarded as products of a different source involving an old layer of subcontinental lithospheric mantle. The crustal evolution of both types of mafic melts is marked by significant compositional contrasts in Sr and Nd isotopes between mafic and associated felsic rocks. The crustal isotope signature showed an increase with felsic character. Geochemical variations for both units can be accounted for by a similar two-stage hybridisation process. In the first stage, the most mafic magma evolved mainly by fractional crystallisation coupled with assimilation of metasedimentary rocks having crustal time-integrated Sr and Nd compositions similar to those of locally exposed metamorphic basement. The second stage involves contaminated products mixing with independently generated crustal melts. Petrographic, geochemical and isotope data also provide evidence of significant compositional differences in the felsic end-members, pointing to the involvement of metaigneous and metasedimentary source rocks for the Abbott granite and Vegetation leucogranite, respectively. Received: 31 March 1998 / Accepted: 3 May 1999     

On Potential Spectroscopic Detection of Microfossils on Mars

There is much evidence about the ancient presence of water on Mars and it is reasonable to suppose that simple forms of life may have developed during the geological evolution of the planet. In such a case traces of this extinct life could still be present on the planet in form of microfossils included into some geological layer. The rover payloads planned for the next decades will include spectrometers in order to accomplish various scientific tasks. In this respect, we have developed a quantitative model for microfossil inclusions into a crystalline matrix. Such a method foresees some visible effects on measurements obtained via spectroscopic techniques such as infrared reflectance and Raman spectroscopy. In this work we present the quantitative model of the fossilization process and the effects that the microfossil inclusions should have in the real spectra, evaluated by means of computer simulations. Preliminary measurements, in order to provide examples of future model testing, have been performed on samples of homogeneous composition, but with detectable microfossils content, collected at the K–T sequence placed near Gubbio (Italy). The preliminary results are presented and discussed in order to investigate the potential application of such spectroscopic techniques for the detection of extinct life.     

Complex polynomials for the computation of 2D gravity anomalies

We present an efficient algorithm using a complex variables formulation for the computation of the gravity effect of 2D polygonal bodies having densities varying both laterally and with depth. The first derivatives of the gravity effect are also provided in order to enable the computation of the Jacobian matrix, which is necessary for linear inverse gravity problems. A geophysical example based on numerical assumptions about the density contrast on a well-studied basin area shows the applicability of the algorithm.     

The Crati Submarine Fan,Ionian Sea

The Crati Fan is located in the tectonically active submerged extension of the Apennines chain and foretrough. The small fan system is growing in a relatively shallow (200 to 450 m), elongate nearshore basin receiving abundant input from the Crati River. The fan is characterized by a short, steep, channelized section (inner or upper fan) and a smooth, slightly bulging distal section (outer or lower fan). The numerous subparallel channels head in the shelf or littoral zone and do not form branching distributary patterns. Sand and mud depositional lobes of the outer fan stretch over more than 60% of fan length.     

Impacts from decommissioning of hydroelectric dams: a life cycle perspective

Greenhouse gas (GHG) emissions from hydroelectric dams are often portrayed as nonexistent by the hydropower industry and have been largely ignored in global comparisons of different sources of electricity. However, the life cycle assessment (LCA) of any hydroelectric plant shows that GHG emissions occur at different phases of the power plant’s life. This work examines the role of decommissioning hydroelectric dams in greenhouse gas emissions. Accumulated sediments in reservoirs contain noticeable levels of carbon, which may be released to the atmosphere upon decommissioning of the dam. The rate of sediment accumulation and the sediment volume for six of the ten largest United States hydroelectric power plants is surveyed. The amount of sediments and the respective carbon content at the moment of dam decommissioning (100 years after construction) was estimated. The released carbon is partitioned into CO₂ and CH₄ emissions and converted to CO₂ equivalent emissions using the global warming potential (GWP) method. The global warming effect (GWE) due to dam decommissioning is normalized to the total electricity produced over the lifetime of each power plant. The estimated GWE of the power plants range from 128–380 g of CO₂eq./kWh when 11% of the total available sediment organic carbon (SOC) is mineralized and between 35 and 104 g of CO₂eq./kWh when 3% of the total SOC is mineralized. Though these values are below emission factors for coal power plants (890 g of CO₂eq./kWh), the amount of greenhouse gases emitted by the sediments upon dam decommissioning is a notable amount that should not be ignored and must be taken into account when considering construction and relicensing of hydroelectric dams.     

Sulphidizing reactions in the flotation of oxidized copper minerals,I. Chemical factors in the sulphidization of copper oxide

The rate and extent of the heterogeneous reaction that takes place between dissolved sodium sulphide and synthetic tenorite is studied for a wide range of sodium sulphide to copper oxide ratios. Besides the sulphidization with the formation of a copper-sulphide layer, a substantial oxidation of sulphide ions takes place at the surface of the solid. The extent of both types of reactions is quantitized by combining specific analytical methods.The results are discussed in terms of possible mechanisms and of their implications in the sulphidization process applied in the flotation of oxidized copper ores.