Phytoplankton pigments and epifluorescence microscopy as tools for ecological status assessment in coastal and estuarine waters, within the Water Framework Directive

Inverted microscopy is widespread employed for the analysis of phytoplankton composition within water quality monitoring networks. However, the analysis at the lowest taxonomical level is not always required for ecological status assessment. In addition, inverted microscopy can underestimate the small phytoplankton, and not always distinguish photoautotrophic from heterotrophic cells. In this study, as alternative tools, epifluorescence microscopy and High Performance Liquid Chromatography (HPLC) were employed to characterize phytoplankton communities within waters of different trophic condition. Epifluorescence microscopy confirmed its effectiveness to count the small phytoplankton. Furthermore, significant correlations between nutrients of anthropogenic origin and nanoplankton abundances were found. However, this technique resulted very time-consuming. HPLC together with the CHEMTAX program was more appropriate than inverted microscopy, in terms of cost-effectiveness. Also, the main variability patterns observed in the phytoplankton community structure by HPLC coincided with previous findings in the study area. Nevertheless, a rapid screening at the inverted microscope is recommended.     

Field Survey of the 27 February 2010 Chile Tsunami

On 27 February 2010, a magnitude M _w?=?8.8 earthquake occurred off the coast of Chile??s Maule region causing substantial damage and loss of life. Ancestral tsunami knowledge from the 1960 event combined with education and evacuation exercises prompted most coastal residents to spontaneously evacuate after the earthquake. Many of the tsunami victims were tourists in coastal campgrounds. The international tsunami survey team (ITST) was deployed within days of the event and surveyed 800?km of coastline from Quintero to Mehuín and the Pacific Islands of Santa María, Mocha, Juan Fernández Archipelago, and Rapa Nui (Easter). The collected survey data include more than 400 tsunami flow depth, runup and coastal uplift measurements. The tsunami peaked with a localized runup of 29?m on a coastal bluff at Constitución. The observed runup distributions exhibit significant variations on local and regional scales. Observations from the 2010 and 1960 Chile tsunamis are compared.     

Tephrochronological study in the quaternary Val d’Agri intermontane basin (Southern Apennines,Italy)

In the south-eastern depocentre of the Val d’Agri basin (Southern Apennines), a volcanic ash layer crops out interbedded within poorly structured alluvial fan deposits of Late Pleistocene age. Textural, depositional and pedological features of this weathered layer suggest a primary deposition from a pyroclastic fall-out of volcanic ash. Chemical analyses of feldspars show an alkali trachytic composition and accessory minerals association allow to correlate this tephra layer with the regionally dispersed Y-7 marine tephra layer (Tufo Verde Epomeo eruption, Ischia volcano), dated at 56 ± 4 ka. The Val d’Agri tephra here described for the first time was deposited during MIS Stage 3. Its recovery and characterization permit to contribute to regional correlation of the Mediterranean climatic and volcanic events from marine to continental successions and to describe landscape evolution of the Southern Apennines during glacial–interglacial cycles.     

Hydrogeological study of the intensely exploited aquifer of the Santa Croce leather-producing district, Tuscany (central Italy)

A hydrogeological study was undertaken to define the groundwater circulation in the Santa Croce area (Tuscany, central Italy) where the existing multilayered aquifer has long been intensively exploited. Investigations carried out on about 150 wells revealed the existence of a deep piezometric depression (to 20?m below sea level) which drains groundwater from the entire surrounding area. Samples from about 70 water points, collected twice in 2007, were analysed for major elements and stable isotope composition. Three major groups of waters, which mix in the study area, have been distinguished: (1) waters of the Ca?CMg?CHCO₃ type mainly flowing along the Arno River Plain; (2) waters of the Na?CK?CCl/Ca?CMg?CHCO₃?CSO_4, type with SO₄ content up to 275?mg/L, inflowing from the Pisane Hills; (3) relatively high-salinity waters mainly of the Na?CHCO₃ type which, with Cl concentrations up to 750?mg/L, likely arise from a normal fault located at the foot of the northern hills. The characteristics of the different components are greatly affected by significant modifying processes such as cation exchange and sulfate reduction. The achieved conceptual model suggests the southern hills as the main recharging area of the aquifer system from which water circulation, characterized by pathways of different length and depth, develops.     

Primary and diagenetic isotopic signals in fossils and hemipelagic carbonates: the Lower Jurassic of northern Spain

Stable isotope and trace element analyses of 230 Jurassic (Pliensbachian–Toarcian) samples from northern Spain have been performed to test the use of geochemical variations in fossils (belemnites and brachiopods) and whole‐rock hemipelagic carbonates as palaeoceanographic indicators. Although the succession analysed (Reinosa area, westernmost Basque–Cantabrian Basin) has been subject to severe thermal alteration during burial diagenesis, the samples appear to be well preserved. The degree of diagenetic alteration of the samples has been assessed through the application of integrated petrographic, chemical and cathodoluminescence analyses. It is demonstrated that brachiopods and whole‐rock carbonates, although widely used for palaeoceanic studies, do not retain their primary marine geochemical composition after burial diagenesis. In contrast, there is strong evidence that belemnite rostra preserve original isotopic values despite pervasive diagenesis of the host rock. Well‐preserved belemnite shells (non‐luminescent to slightly luminescent) typically show stable isotope values of +4·3‰ to –0·7‰δ¹³C, +0·7‰ to –3·2‰δ¹⁸O, and trace element contents of <32 μg g^–1 Mn, <250 μg g^–1 Fe, >950 μg g^–1 Sr and Sr/Mn ratios >80. This study suggests that the degree to which diagenesis has affected the preservation of an original isotopic composition may differ for different low‐Mg calcite fossil shells and hemipelagic bulk carbonates, behaviour that should be considered when marine isotopic signatures from other ancient carbonate rocks are investigated. Multiple non‐luminescent contemporaneous belemnite samples passed the petrographic and geochemical tests to be considered as palaeoceanic recorders, yet their δ¹³C and δ¹⁸O values exhibited moderate scatter. Such variability is likely to be related to the palaeoecological behaviour of belemnites and/or high‐frequency secular variations in sea‐water chemistry superimposed on the long‐term isotopic trend. A pronounced positive carbon‐isotope excursion (up to +4·3‰) is documented in the early Toarcian serpentinus biozone, which correlates with the Toarcian δ¹³C maximum reported in other European and Tethyan regions.     

Advancing tsunami risk assessment by improving spatio-temporal population exposure and evacuation modeling

Tsunamis are among the most destructive and lethal of coastal hazards. These are time-specific events, and despite directly affecting a narrow strip of coastline, a single occurrence can have devastating effects and cause massive loss of life, especially in urbanized coastal areas. In this work, in order to consider the time dependence of population exposure to tsunami threat, the variation of spatio-temporal population distribution in the daily cycle is mapped and analyzed in the Lisbon Metropolitan Area. High-resolution daytime and nighttime population distribution maps are developed using ‘intelligent dasymetric mapping,’ that is, applying areal interpolation to combine best-available census data and statistics with land use and land cover data. Workplace information and mobility statistics are considered for mapping daytime distribution. In combination with a tsunami hazard map, information on infrastructure, land use and terrain slope, the modeled population distribution is used to assess people’s evacuation speed, applying a geospatial evacuation modeling approach to the city of Lisbon. The detailed dynamic population exposure assessment allows producing both daytime and nighttime evacuation time maps, which provide valuable input for evacuation planning and management. Results show that a significant amount of population is at risk, and its numbers increase dramatically from nighttime to daytime, especially in the zones of high tsunami flooding susceptibility. Also, full evacuation can be problematic in the daytime period, even if initiated immediately after a major tsunami-triggering earthquake. The presented approach greatly improves tsunami risk assessment and can benefit all phases of the disaster management process.     

Magma intrusion as a driving mechanism for the seismic clustering following the 9 May 1989 earthquake swarms at the Canary Islands

On 9 May 1989 a M _L = 5.2 earthquake struck a region between the islands of Tenerife and Gran Canaria. We investigated the time-spatial evolution of seismic patterns affecting the Canary Islands region during 1989–1995, using a quantitative spatial fractal analysis method. This method allows quantitative investigation of subtle trends in seismicity distribution through time. The fractal analysis indicates that epicenters clustered around a large zone during the May 1989 sequence affected narrow zones during 1991–1993, but then larger zones during 1993–1995 with an overall trend to shallower focal depths. The spatial localisation of seismic data and its time evolution appear to be related to magmatic rather than tectonic activity. Spatial clustering properties of seismicity are consistent with a major intrusive episode in 1989, followed by a period of quiescence and renewed deep intrusive activity from 1993 onwards. This interpretation suggests an increasing probability of future volcanic hazard in the region investigated.     

Sex Offender Residential Movement Patterns: A Markov Chain Analysis

This article introduces a new approach to the analysis of changes in sex offender residences over time. Using a Markov chain framework, we analyze residential movement patterns of registered sex offenders in Hamilton County, Ohio, over a three-year period (2005–2007). Results indicate a 46 percent reduction in offenders violating spatial restriction zone policy as compared to a counterfactual case where offenders move as a function of housing distributions. Strong legacy effects are also found as offenders previously in violation of restriction policies move into other restricted zones at a higher rate than offenders who were previously in compliance with the policy. Parcels that previously were home to registered offenders also continue to attract offenders in future periods. Although we find differences in the probabilities of attracting offenders for parcels outside and inside restricted zones that are consistent with offender restrictive policies, these differences are actually significantly smaller than what holds under the counterfactual. Parcels in restricted zones continue to attract offenders at a higher rate than expected, despite the policy restrictions.