Trace metals and dissolved organic carbon in an estuary with restricted river flow and a brown tide bloom

This study was designed to establish the distributions of trace metals (Cd, Co, Cu, Ni, Pb, and Zn), dissolved organic carbon (DOC), and inorganic nutrients (PO₄ and H₄SiO₄) in the water column of the small, relatively pristine Peconic River estuary. We were also able to examine the effects of a harmful microalgal bloom, known as the brown tide, which occurred in the area during our study. Because river inflow to the Peconic estuary is restricted by a small dam at the head of the estuary, direct evaluation of the relative importance of riverine inputs on estuarine metal distributions was possible. The simultaneous analyses of geochemical carrier metals (Al, Fe, and Mn), an indicator of sewage (Ag), and other ancillary parameters (e.g., suspended particulate matter, dissolved O₂, chlorophylla) were used to describe the major processes controlling metal concentrations in the dissolved phase. The trace metal distributions indicated two distinct biogeochemical regimes within the estuary: an anthropogenically perturbed region with high metal levels (e.g., Ag, 165 pM; Cu, 51 nM; Zn, 57 nM) at the head (Flanders Bay), and a larger outer region with relatively low metal concentrations. The very similar distributions of some metals (e.g., Mn, Ni) in the Peconic estuary compared to those in estuaries having much higher river flow demonstrated the dominant role of internal processes (e.g., diagenetic remobilization) in controlling these metal patterns. An inverse relationship between dissolved Fe and DOC with cell counts of the brown tide microalgaeAureococcus anophagefferens in our field study suggested a close association with the bloom, although a similar relationship was observed between dissolved Al and brown tide cell counts, implying that removal of Fe could be due to particle scavenging rather than biological uptake.     

In‐plane strength of unreinforced masonry piers

The definition of adequate simplified models to assess the in‐plane load‐bearing capacity of masonry piers, in terms of both strength and displacement, plays a fundamental role in the seismic verification of masonry buildings. In this paper, a critical review of the most widespread strength criteria present in the literature and codes to interpret the failure modes of piers (rocking, crushing, bed joint sliding or diagonal cracking) are proposed. Models are usually based on an approximate evaluation of the stress state produced by the external forces in a few points/sections and on its assessment with reference to a limit strength domain. The aim of the review is to assess their reliability by discussing the hypotheses, which they are based on (assumed stress states; choice of reference points/sections on which to assess the pier strength; characteristics of the limit strength domain) and to verify the conditions for their proper use in practice, in terms of both stress fields (depending on the geometry of the pier, boundary conditions and applied loads) and types of masonry (i.e. regular brick masonry vs rubble stone masonry). In order to achieve these objectives, parametric nonlinear finite element analyses are performed and different experimental data available in the literature are analysed and compared. Copyright © 2008 John Wiley & Sons, Ltd.     

Modelling Gravitational Instabilities: Slab Break–off and Rayleigh–Taylor Diapirism

A non-standard new code to solve multiphase viscous thermo–mechanical problems applied to geophysics is presented. Two numerical methodologies employed in the code are described: A level set technique to track the position of the materials and an enrichment of the solution to allow the strain rate to be discontinuous across the interface. These techniques have low computational cost and can be used in standard desktop PCs. Examples of phase tracking with level set are presented in two and three dimensions to study slab detachment in subduction processes and Rayleigh–Taylor instabilities, respectively. The modelling of slab detachment processes includes realistic rheology with viscosity depending on temperature, pressure and strain rate; shear and adiabatic heating mechanisms; density including mineral phase changes and varying thermal conductivity. Detachment models show a first prolonged period of thermal diffusion until a fast necking of the subducting slab results in the break–off. The influence of several numerical and physical parameters on the detachment process is analyzed: The shear heating exerts a major influence accelerating the detachment process, reducing the onset time to one half and lubricating the sinking of the detached slab. The adiabatic heating term acts as a thermal stabilizer. If the mantle temperature follows an adiabatic gradient, neglecting this heating term must be included, otherwise all temperature contrasts are overestimated. As expected, the phase change at 410 km depth (olivine–spinel transition) facilitates the detachment process due to the increase in negative buoyancy. Finally, simple plume simulations are used to show how the presented numerical methodologies can be extended to three dimensions.     

A critical-density closed universe in BransDicke theory

In a BransDicke (BD) cosmological model, the energy density associated with some scalar field decreases as a ^{2[( o +1/2)/( _o +1)]} with the scalefactor a ( t ) of the universe, giving matter with an equation of state In this model, the universe could be closed but still have a non-relativistic matter density corresponding to its critical value, _o =1. Different cosmological expressions, such as luminosity distance, angular diameter, number count and ratio of the redshift thicknessangular size, are determined in terms of the redshift for this model.     

Effects of historical land use on sediment yield from a lacustrine watershed in central Chile

Sediment yield in the San Pedro Lake watershed, inferred from sedimentation in the lake, can be related to land use changes shown on aerial photographs taken during the period 1943–1994. In this watershed, which covers 4·5 km² of mountainous terrain in San Pedro County, central Chile, the area of native forest species decreased from 70 per cent in 1943 to 13 per cent in 1994. During this same period, the area of pine plantations increased from 4 to 46 per cent. To study effects of these changes, we took a core from the centre of the lake and estimated sedimentation rates by ²¹⁰Pb dating, which we checked with ¹³⁷Cs and pine pollen. The results show that sedimentation rate ranged from 5 mg cm⁻² a⁻¹ in the late 1800s to 60 mg cm⁻² a⁻¹ in the late 1960s. These rates, together with assumptions about the production and delivery of the sediment, give corresponding figures for sediment yields with maximum values close to 1 t ha⁻¹ a⁻¹. Sediment yield between 1955 and 1994 closely tracks the total land use change that can be detected, irrespective of land use type, on sets of aerial photographs taken four to 18 years apart. However, this measure of land use change, while convenient and successful as a predictor of historical erosion, may be unreliable because it probably excludes many changes that occurred in long intervals between successive photographs. Copyright © 2001 John Wiley & Sons, Ltd.     

On the determination of marine magnetotelluric receiver orientation using land magnetic observatory data

Marine magnetotelluric measurements using “free‐fall’’ instruments without effective compasses suffer from the problem of unknown orientation of the receivers at the seafloor. While past works indicate that marine magnetotelluric orientation of the instruments can be estimated by reference to land deployments of known orientation using the transfer tensor method, there is limited published information on how this is implemented in practice. We document this method and propose a set of new time‐ and frequency‐domain approaches to solve this orientation problem of the seafloor receivers. We test these methodologies in onshore and offshore magnetotelluric data whose orientations are well known and apply these techniques to marine magnetotelluric data with unknown orientation. For the controlled tests, both time‐ and frequency‐domain approaches produce overall comparable results. To investigate the effects of the subsurface structure distribution on the orientation process, a dimensionality analysis of a controlled dataset is carried out. In subsequent analysis using the available disoriented marine magnetotelluric data from offshore Brazil and from the Vassouras magnetic observatory on the mainland for remote referencing, frequency‐domain methods yield approximate orientation angles among themselves with low standard deviation each. Time‐domain results are consistent for most cases but differ from frequency‐domain results for some situations.     

Distributions of dissolved vitamin B12 and Co in coastal and open-ocean environments

Distributions of dissolved vitamin B₁₂ and total dissolved Co were measured to gain an understanding of the cycling of these interdependent micronutrients in six marine settings including; an upwelling location, a semi-enclosed bay, two urban coastal systems, and two open ocean locations. Along the coast of Baja California, Mexico, concentrations of B₁₂ and dissolved Co varied from 0.2 to 11 pM and 180 to 990 pM, respectively. At a nearby upwelling station, vitamin B₁₂ and Co concentrations ranged from 0.3 to 7.0 pM and 22 to 145 pM, and concentrations did not correlate with upwelling intensity. Concentrations of B₁₂ were highest within Todos Santos Bay, a semi-enclosed bay off the coast of Baja California, Mexico, during a dinoflagellate bloom, ranging from 2 to 61 pM, while Co concentrations varied between 61 and 194 pM. In the anthropogenically impacted Long Island Sound, NY, U.S.A., B₁₂ levels were between 0.1 and 23 pM and Co concentrations varied from 60 to 1900 pM. However, anthropogenic inputs were not evident in B₁₂ levels in the San Pedro Basin, located outside Los Angeles, Ca, U.S.A., where concentrations of B₁₂ were 0.2–1.8 pM, approximating observed open ocean B₁₂ concentrations. In the Southern Ocean and North Atlantic Ocean, B₁₂ levels were 0.4–4 pM and 0.2–2 pM, respectively. Total Co concentrations in the Southern Ocean and North Atlantic tended to be low; measuring 26–59 pM and 15–80 pM, respectively. These low Co concentrations may limit B₁₂ synthesis and its availability to B₁₂-requiring phytoplankton because the total dissolved Co pool is not necessarily entirely bioavailable.     

Recent contamination of mercury in an estuarine environment (Marano lagoon,Northern Adriatic,Italy)

The Marano Lagoon, in the northern Adriatic Sea (Italy), has been affected by mercury (Hg) contamination from industrial and mining activities. It has been estimated that 186,000 kg of Hg were deliberately discharged into the main drainage system (Aussa–Corno River) by a chlor-alkali plant (CAP) from 1940s to 1984. The lagoon has also experienced a secondary long-term Hg input, originated from mining activity in Idrija (Slovenia), due to the supply of fluvial suspended particles carried by the Isonzo River in the Gulf of Trieste. Since local fishing activities are extensively conducted, there is great concern on the risk posed by potentially harmful effects of Hg to the trophic chain.     

Show me the code: spatial analysis and open source

This paper considers the intersection of academic spatial analysis with the open source revolution. Its basic premise is that the potential for cross-fertilization between the two is rich, yet some misperceptions about these two communities pose challenges to realizing these opportunities. The paper provides a primer on the open source movement for academicians with an eye towards correcting these misperceptions. It identifies a number of ways in which increased adoption of open source practices in spatial analysis can enhance the development of the next generation of tools and the wider practice of scientific research and education.