Infrared transmission spectroscopy of carbonate samples of biotic origin relevant to Mars exobiological studies

Because it is possible that Mars experienced an ancient climate warmer and wetter than the present one, it is reasonable to suppose that simple forms of life developed there, in the underground or at the surface, as in the terrestrial primitive biosphere. In this work we have performed infrared (IR) transmission spectroscopic analyses directed to examine the reaction to heat treatments of biotic (fresh and fossil materials) and abiotic particulate samples composed of calcium carbonate (aragonite or calcite). The aim is to check if IR spectroscopy can be a useful tool for discriminating between abiotic and biotic (fossil) carbonate samples collected on the martian surface, during in situ or sample-return missions. An important result we found is that, after thermal processing, it is possible to distinguish, by means of IR spectroscopy, abiotic aragonite from aragonite of recent biological origin. In addition we have found that the spectral behaviour of all the analysed fossil samples after heat treatment is the same as that of fresh biotic material irrespective of the original structure (whether aragonite or calcite).     

The Piànico tephra: an early Middle Pleistocene record of intraplate volcanism in the Mediterranean

ABSTRACT Distal tephra are a valuable record of the volcano-tectonic evolution of an area under study. Here, we document the case of the Early Middle Pleistocene rhyolitic tephra of Piànico, discovered in the Southern Italian Alps. The geochemical characteristics of Piànico are unique among the distal tephra outcropping in Italy and indicate an intraplate volcanism at the source. The alkali composition and trace elements show a striking resemblance with the rhyolitic complex of the Euganean Hills, located 170 km from Piànico. However, these rhyolites are much older (Oligocene). Alternatively, the source of this intraplate volcanic episode could be located in the southern Tyrrhenian Sea.     

Evaluating Duero's basin (Spain) response to the NAO phases: spatial and seasonal variability

In this study, we analysed the influence of the North Atlantic Oscillation (NAO) on the hydrological response of the Duero River (central Spain) and its tributaries. We identified the positive and negative phases of the winter NAO for the period 1961–2006 and related precipitation and river discharge anomalies. Significant differences in precipitation and river discharge were found between the positive and negative NAO phases with negative anomalies (dry conditions) during positive NAO periods, and positive anomalies (wet conditions) during negative NAO periods. Marked differences were also found in the precipitation and river discharge response times to the NAO episodes, with an immediate response for precipitation but a lag and more sustained response for river discharges. Differing patterns were also identified in the response of river discharge to the NAO throughout the Duero basin. The physical characteristics of watersheds (including area, altitude and permeability explained most of the differences in the timing and magnitude of anomalies in the river discharge in response to the NAO. The findings highlight the great variability in the hydrological response of rivers to the NAO episodes. Copyright © 2010 John Wiley & Sons, Ltd.     

Chronic oil pollution harms Magellanic penguins in the Southwest Atlantic

Petroleum pollution is a problem for seabirds along the Southwest Atlantic coast. Twenty-five groups from Salvador, Brazil (12 degrees 58'S) to San Antonio Oeste, Argentina (40 degrees 43'S) survey or rehabilitate sick or oiled seabirds. Four groups, one each in Brazil and Uruguay, and two in Argentina, kept counts of birds found alive and in need of rehabilitation. An average of 63.7% of the seabirds found were Magellanic penguins (Spheniscus magellanicus), with 3869 reported since 1987. Mainly adult penguins were found in Argentina (1605 of 2102 penguins of known age class) and Uruguay (158 of 197). Juveniles were most common in Brazil (234 of 325). Oil fouling was the most frequent cause of injury or sickness. The number of oiled penguins reported in their wintering range has greatly increased since the early 1990s and is strongly correlated with petroleum exports from Argentina. Our results show that chronic petroleum pollution is a problem for wildlife from Southern Brazil through Northern Argentina, and regulations and enforcement are failing to protect living resources.     

Vegetation and cloud cover shape semi-arid carbonate landform development

We study the relationships among precipitation, vegetation, and morphological characteristics of watersheds draining either side of the Dhofar Mountains in southeastern Oman to understand the geomorphic signature of water availability in a semi-arid carbonate landscape. Water availability is expressed in terms of vegetation and cloud cover. The integral and the statistical moments of the hypsometric curve were used to determine whether hyper-arid, inland-draining watersheds are significantly different from seasonally wet watersheds on the coast side of the mountain range. We demonstrate that the vegetation and cloud cover are correlated, with locations with longer cloud periods also having a longer period with a vegetation canopy. The analysis shows that the hypsometric curve and its statistical moments capture the morphological difference between wet watersheds shaped by groundwater sapping and dry watersheds with fluvial morphology. Specifically, the curves exhibit two shapes: watersheds with more vegetation and cloud cover are characterized by higher convexity, and those with less vegetation and cloud cover are characterized by higher concavity. A variance analysis of cloud cover, vegetation, and hypsometric integral shows that they are significantly different between the wet and dry watersheds. The link between hydrology and morphology is not strong at the scale of a single watershed, but it is significant when the watersheds are aggregated in zones. The statistical moments of the hypsometric curve in the range of values of the integral and skewness show good separation between watersheds dominated by sapping and fluvial erosion processes. We can separate the watersheds draining the mountain range in two distinct groups on the basis of their bimodal hydrological and morphological characteristics. Our findings support other studies that hypothesize a trade-off from chemical- to mechanical-dominated denudation in carbonate terranes as precipitation decreases.     

Inverse modeling of coastal aquifers using tidal response and hydraulic tests

Remediation of contaminated aquifers demands a reliable characterization of hydraulic connectivity patterns. Hydraulic diffusivity is possibly the best indicator of connectivity. It can be derived using the tidal response method (TRM), which is based on fitting observations to a closed-form solution. Unfortunately, the conventional TRM assumes homogeneity. The objective of this study was to overcome this limitation and use tidal response to identify preferential flowpaths. Additionally, the procedure requires joint inversion with hydraulic test data. These provide further information on connectivity and are needed to resolve diffusivity into transmissivity and storage coefficient. Spatial variability is characterized using the regularized pilot points method. Actual application may be complicated by the need to filter tidal effects from the response to pumping and by the need to deal with different types of data, which we have addressed using maximum likelihood methods. Application to a contaminated artificial coastal fill leads to flowpaths that are consistent with the materials used during construction and to solute transport predictions that compare well with observations. We conclude that tidal response can be used to identify connectivity patterns. As such, it should be useful when designing measures to control sea water intrusion.     

Environmental factors controlling the spatiotemporal distribution of microbial communities in a coastal, sandy aquifer system (Doñana, southwest Spain)

Currently, aquifers are considered to be ecosystems that interchange materials and energy with other systems located in their surroundings. The aquifer system of Doñana (southwest Spain) has been studied over recent decades from a hydrogeological point of view, although nothing is known about its biological or ecological aspects. In order to describe the general characteristics of its microbial communities, bacterial abundance, cell biomass, bacterial biomass and microbial activities of functional groups were investigated by sampling, over a 2-year period, 13 wells located in the vicinity of four very productive shallow lakes in the most superficial part of this coastal, sandy aquifer system. Multivariate analysis of variance (MANOVA) indicated differences in abundance and biomass variables among sampling locations, seasons and sampling locations × seasons. Principal component analysis showed that temperature and dissolved oxygen appeared to be the most important factors controlling the temporal variability of microbial communities. Hydrological connectivity between surface water and groundwater was important in the control of the spatiotemporal distribution of microbial communities. Due to this hydrological connection, the aquifer system and the wetlands constitute a unique entity, a unique ecosystem, called the “hydroecosystem”, where microbial communities could play a central ecological role.     

Ranching and the new global range: Amazônia in the 21st century

This paper seeks to understand how the Brazilian Amazon, which many thought unsuitable for agricultural development, has yielded to a dynamic cattle economy in only a few decades. It does so by embedding the Thunian model of location rents within the regime of capital accumulation that has driven the Brazilian economy since the mid-20th century. The paper addresses policies that have created location rents in Amazônia, the effect of these rents on land managers, and the spatial implications of their behavior on forests. Thus, the paper connects macro-processes and structures to agents on the ground, in providing a political ecological explanation relevant to land change science. The policy discussion focuses on reductions in transportation costs, improvements in animal health, and monetary and trade reforms. To illustrate the impact of policy, the paper presents data on the geography of Amazonian herd expansion, on the growth of Amazonian exports, and on the profitability of the region’s cattle economy. It follows the empirical presentation with more abstract consideration of the spatial relations between cattle ranching and soy farming, and implications for deforestation. The paper concludes on a speculative note by considering the likelihood of forest transition in the region, given the transformation of Amazônia into a global resource frontier.