New type of possible high-pressure polymorphism in NiAs minerals in planetary cores

The nickel arsenide (B8₁) and related crystal structures are among the most important crystallographic arrangements assumed by Fe and Ni compounds with light elements such as Si, O, S, and P, expected to be present in planetary cores. Despite the simple structure, some of these materials like troilite (FeS) exhibit complex phase diagrams and rich polymorphism, involving significant changes in interatomic bonding and physical properties. NiP (oP16) represents one of the two principal structure distortions found in the nickel arsenide family and is characterized by P–P bonding interactions that lead to the formation of P₂ dimers. In the current study, the single-crystal synchrotron X-ray diffraction technique, aided by first principles density functional theory (DFT) calculations, has been applied to examine the compression behavior of NiP up to 30 GPa. Two new reversible displacive phase transitions leading to orthorhombic high-pressure phases with Pearson symbols oP40 and oC24 were found to occur at approximately 8.5 and 25.0 GPa, respectively. The oP40 phase has the primitive Pnma space group with unit cell a = 4.7729(5) Å, b = 16.6619(12) Å, and c = 5.8071(8) Å at 16.3(1) GPa and is a superstructure of the ambient oP16 phase with multiplicity of 2.5. The oC24 phase has the acentric Cmc2₁ space group with unit cell a = 9.695(6) Å, b = 5.7101(9) Å, and c = 4.7438(6) Å at 28.5(1) GPa and is a superstructure of the oP16 phase with multiplicity of 1.5. DFT calculations fully support the observed sequence of phase transitions. The two new phases constitute logical next stages of P sublattice polymerization, in which the dilution of the P₃ units, introduced in the first high-pressure phase, decreases, leading to compositions of Ni₂₀(P₃)₄(P₂)₄ and Ni₁₂(P₃)₄, and provide important clues to understanding of phase relations and transformation pathways in the NiAs family.     

Analytic properties of Hansen coefficients

Hansen’s coefficients in the theory of elliptic motion with eccentricity e are studied as functions of the parameter η = (1 − e ²)^1/2. Their analytic behavior in the complex η plane is described and some symmetry relations are derived. In particular, for every Hansen coefficient, multiplication by suitable powers of e and η results in an entire analytic function of η. Consequently, Hansen’s coefficients can be in principle computed by means of rapidly convergent series in powers of η. A representation of Hansen’s coefficients in terms of two entire functions of e ² follows.      

Automated placement of supplementary contour lines

Supplementary contour lines are placed between regular contour lines to visualize small but important forms that regular contour lines are unable to show. On topographic maps, typical forms are hillcrests, depressions, saddles, terraces, banks, and levees. No automated method for the selection of supplementary contour lines has been described so far. We document cartographic design principles for the selection of supplementary contour lines for topographic maps, and present an automated method for their placement. Results of the automated method are similar to manually placed supplementary contour lines. Our method helps map authors to create contour line maps that more effectively illustrate relevant small details in maps showing terrain elevation or other scalar fields.     

SphinX: The Solar Photometer in X-Rays

Solar Photometer in X-rays (SphinX) was a spectrophotometer developed to observe the Sun in soft X-rays. The instrument observed in the energy range ≈?1?–?15 keV with resolution ≈?0.4 keV. SphinX was flown on the Russian CORONAS–PHOTON satellite placed inside the TESIS EUV and X telescope assembly. The spacecraft launch took place on 30 January 2009 at 13:30 UT at the Plesetsk Cosmodrome in Russia. The SphinX experiment mission began a couple of weeks later on 20 February 2009 when the first telemetry dumps were received. The mission ended nine months later on 29 November 2009 when data transmission was terminated. SphinX provided an excellent set of observations during very low solar activity. This was indeed the period in which solar activity dropped to the lowest level observed in X-rays ever. The SphinX instrument design, construction, and operation principle are described. Information on SphinX data repositories, dissemination methods, format, and calibration is given together with general recommendations for data users. Scientific research areas in which SphinX data find application are reviewed.     

Evapotranspiration capture and stream depletion due to groundwater pumping under variable boreal climate conditions: Sudogda River Basin,Russia

Groundwater pumping and changes in climate-induced recharge lead to lower groundwater levels and significant changes in the water balance of a catchment. Water previously discharged as evapotranspiration can become a source of pumpage. Neglecting this effect leads to overestimated streamflow depletion. A small river basin (Sudogda River Basin, Russia) with a boreal climate and with long-term records of groundwater head and streamflow rate (showing that the measured stream depletion is less than the pumping rate) was investigated. The role of evapotranspiration in the water balance was analyzed by a hydrogeological model using MODFLOW-2005 with the STR package; the annual variation in recharge was obtained with the codes Surfbal and HYDRUS. The Sudogda River Basin was classified according to landscape and unsaturated-zone texture classes, and for each classified zone, the unsaturated-zone flow simulation was used to calculate the annual recharge dynamics for the observation period. Calibration of the regional flow model was conducted using flow and head observations jointly for two steady-state flow conditions—natural (before pumping started) and stressed (pumping). The simulations showed that pumped water originates from three sources: intercepted baseflow (75% of the annual total pumping rate), the capture of groundwater evapotranspiration discharge plus increased groundwater recharge (17%), and induced stream infiltration (8%). Additionally, multi-year precipitation records were analyzed to detect any long-term recharge and pumping water-budget changes. The results showed that increasing groundwater recharge by natural precipitation leads to (1) decreased intercepted baseflow and induced streamflow infiltration and (2) increased intercepted evapotranspiration discharge, thereby reducing stream depletion.     

Parameterization of iron and manganese cycling in the Black Sea suboxic and anoxic environment

New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σ_t16.2) and anoxic layers (σ_t16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σ_t16.2±0.2 kg m⁻³. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σ_t16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate.     

Population-level genotyping of coat colour polymorphism in woolly mammoth (Mammuthus primigenius)

Patterns in the spatial or temporal distribution of genotypes may be indicative of natural selection. Previous work on the woolly mammoth melanocortin-1 receptor (Mc1r) gene identified three polymorphic positions that suggest Pleistocene populations may have harboured both light- and dark-haired mammoths (Rompler et al., 2006, 313: 62). Here, we extend this work and present the first population-level analysis of a functional gene in an extinct species. We genotyped the Mc1r gene in 47 woolly mammoth samples excavated from sites across the central portion of the woolly mammoths’ former range to examine the extent of variation of this polymorphism through time and across space. Only one individual was found to be heterozygous, indicating that the frequency of the ‘light’ mutant allele was very low. We conclude that light-coloured woolly mammoths would have been very rare, and may even have been non-existent if the ‘light’ mutant allele was strongly selected against in its homozygotic form. With the increasing availability of large-scale sequencing technologies, population-level datasets capable of identifying local adaptation will become increasingly attainable.