The crystal structure of loparite: a new acentric variety

Mineralogy and Petrology - The crystal structure of a new structural variety of loparite (Na0.56Ce0.21La0.14Ca0.06Sr0.03Nd0.02Pr0.01)Σ=1.03(Ti0.83Nb0.15)Σ=0.98O3 from the Khibiny alkaline...     

Review of the Permian Camptoneuritidae (Insecta:Grylloblattida)

<正>The Permian family Camptoneuritidae(Insecta:Grylloblattida)is reviewed.New synonymies are proposed:Camptoneuritidae Martynov,1930=Demopteridae Carpenter,1950,syn.nov.,=Jabloniidae Kukalova, 1964,syn.nov.Key to genera of Camptoneuritidae is given.All genera are redescribed and illustrated. Camptoneurites soyanensis sp.nov.from Soyana locality(Middle Permian,Kazanian Stage;Arkhangelsk Region, Russia)and Tyulkinia bashkuevi gen.et sp.nov.from Tyulkino locality(Lower Permian,Kungurian Stage;Perm Region,Russia)are described.     

Mineral-fluid equilibria in the system CaO–MgO–SiO<Subscript>2</Subscript>–H<Subscript>2</Subscript>O–CO<Subscript>2</Subscript>–NaCl and the record of reactive fluid flow in contact metamorphic aureoles

Phase equilibria in the system CaO–MgO–SiO₂–CO₂–H₂O–NaCl are calculated to illustrate phase relations in metacarbonates over a wide-range of P–T–X[H₂O–CO₂–NaCl] conditions. Calculations are performed using the equation of state of Duan et al. (Geochim Cosmochim Acta 59:2869–2882, 1995) for H₂O–CO₂–NaCl fluids and the internally consistent data set of Gottschalk (Eur J Mineral 9:175–223, 1997) for thermodynamic properties of solids. Results are presented in isothermal-isobarical plots showing stable mineral assemblages as a function of fluid composition. It is shown that in contact-metamorphic P–T regimes the presence of very small concentrations of NaCl in the fluid causes almost all decarbonation reactions to proceed within the two fluid solvus of the H₂O–CO₂–NaCl system. Substantial flow of magma-derived fluids into marbles has been documented for many contact aureoles by shifts in stable isotope geochemistry of the host rocks and by the progress of volatile-producing mineral reactions controlled by fluid compositions. Time-integrated fluid fluxes have been estimated by combining fluid advection/dispersion models with the spatial arrangement of mineral reactions and isotopic resetting. All existing models assume that minerals react in the presence of a single phase H₂O–CO₂ fluid and do not allow for the effect that fluid immiscibility has on the flow patterns. It is shown that fluids emanating from calc-alkaline melts that crystallize at shallow depths are brines. Their salinity may vary depending mainly on pressure and fraction of crystallized melt. Infiltration-driven decarbonation reactions in the host rocks inevitably proceed at the boundaries of the two fluid solvus where the produced CO₂ is immiscible and may separate from the brine as a low salinity, low density H₂O–CO₂ fluid. Most parameters of fluid–rock interaction in contact aureoles that are derived from progress of mineral reactions and stable isotope resetting are probably incorrect because fluid phase separation is disregarded.     

A Comparison of Greenland Ice and Baltic Sea Sediment Record—A Contribution to Climate Change Analysis

Modern methods on the Theory of Dynamical Systems, time series analysis and multidimensional statistics allow us to extract crucial information about behavior of dynamical systems from observed natural records. We applied some of these methods to two geo-climatic records from Greenland ice and Baltic Sea sediments. Decomposed and noise-free signals demonstrate the presence of ‘global’ components with concordant periodicities of about 900, 500 and 400 years in both records. Both signals correspond to complex periodical (non-chaotic) behavior. The main governing processes belong to the class of dynamical systems with weak dissipation of energy. The observed climate variability gives us an option for the correct stochastic prediction which would be impossible in the case of chaotic behavior of a climatic system.     

Split-step complex Padé-Fourier depth migration

We present a split-step complex Padé-Fourier migration method based on the one-way wave equation. The downward-continuation operator is split into two downward-continuation operators: one operator is a phase-shift operator and the other operator is a finite-difference operator. A complex treatment of the propagation operator is applied to mitigate inaccuracies and instabilities due to evanescent waves. It produces high-quality images of complex structures with fewer numerical artefacts than those obtained using a real approximation of a square-root operator in the one-way wave equation. Tests on zero-offset data from the SEG/EAGE salt data show that the method improves the image quality at the cost of an additional 10 per cent computational time compared to the conventional Fourier finite-difference method.     

Magnetic,paleomagnetic and palynologic studies of Paleolithic depositions of the Akhshtyrskaya cave (Russia)

The paper presents the results of experimental rock-magnetic, paleomagnetic and palynologic study of Paleolithic sediments sampled along two profiles in the Akhshtyrskaya cave, situated in the vicinity of Black Sea shore. In the upper part of profiles, some magnetite was observed; in the middle and lower parts, strongly oxidized non-stoichiometric magnetite and hematite prevail. Thin maghemite covers on the surface of fine magnetite grains are present in the majority of specimens. Natural remanence has one characteristic component (CHRM), mostly of chemical origin, although in few specimens containing magnetite it may be sedimentary. Directions of CHRM obtained by standard paleomagnetic methods revealed anomalous pattern only in layer 3/2, which is slightly older than the overlying layer 3/1 whose age was established as (35±2)×10³ years BP by the U-Th method. This suggests that this paleomagnetic anomaly (PMA) can be correlated with Kargapolovo excursion dated on about (45−39)×10³ years BP. In the remaining overlying and underlying layers, directions of CHRM are grouped around the present geomagnetic field. Depth distributions of scalar magnetic parameters generally coincide with the lithological division of the profiles. Palynologic study revealed the presence of 22 pollen zones. Five thermomers separated with colder periods were found in the middle and lower parts of profile. The non-magnetite composition of magnetic fraction of the majority of studied sediments — oxidized nonstoichiometric magnetite and hematite — resulted in the lack of correlations between paleoclimatic and scalar magnetic characteristics.     

Database of Comet Polarimetry: Analysis and Some Results

We present the electronic database (EAR-C-COMPIL-5-DB-COMET-POLARIMETRY-V1.0, NASA Planetary Data System) involving published and some unpublished results of cometary polarimetry. The database contains more than 2600 measurements of linear and circular polarization for 64 comets since 1940s. The narrow-band and wide-band measurements within the spectral region 0.3–2.2 micron are presented. The ranges of phase angles, helio- and geocentric distances of comets are 0.4–122°, 0.6–4.8 AU, 0.03–4.9 AU, respectively. We have comprised more than 60 references to the published papers and unpublished sources. The data we included are presented in a tabular format in the ASCII codes. The database can be used as the observational basis for detailed theoretical modeling, interpretation of the phase-angle and spectral dependence of polarization, classification of comets, laboratory simulating, and for selecting future space-mission targets. Analysis of the available data allowed us to summarize some observed characteristics of linearly and circularly polarized light and their phase-angle, heliocentric, spectral, and spatial dependencies.     

Buried palaeosols of the Nevado de Toluca: an alternative record of Late Quaternary environmental change in central Mexico

Buried palaeosols of central Mexico, not previously analysed from a palaeopedological standpoint, have helped to develop a reliable regional model of Late Quaternary climatic change. This paper focuses upon morphological and micromorphological properties, particle‐size distribution, and extractable Fe, Al and Si of seven palaeosols (named PT1–PT7) in the vicinity of the Nevado de Toluca volcano. The characteristics of Andic Cambisol PT1, similar to those of modern soils in semi‐arid environments, indicate a drier climate in the first half of the Holocene. Humic Andosols PT2–PT4 are analogous to modern volcanic soils of humid forest environments. They show evidence that a moist palaeoclimate prevailed during marine oxygen isotope stages (OIS) 2 and 3. Luvisols PT5 and PT6, which are assumed to have formed at the end of marine OIS 5 to marine OIS 4, also indicate humid conditions. We attribute the differences between Andosols PT2–PT4 and Luvisols PT5–PT7 to variations in the duration in the pedogenesis rather than to changes in palaeoclimate. Micromorphological features of Andosol to Luvisol transition confirm that these soils form an evolutionary sequence. Being for the most part consistent with lacustrine records, the palaeosol properties do not reflect the episodes of ‘drier climate’ during the Last Glacial Maximum, however, as shown by diatom and palynological data from lake sediments. Mesoclimate variations and/or incompleteness of ‘soil memory’, reflecting mostly periods of humid pedogenesis, probably provide the reason for this disagreement. Copyright © 2001 John Wiley & Sons, Ltd.     

Geochemical Baselines of Nickel and Chromium in Various Surficial Materials in the Barents Region, NW Russia and Finland

The geochemical baselines of nickel and chromium were studied from the data produced by the Barents Ecogeochemistry project, a large international regional geochemical mapping exercise. The project surveyed major and trace element distributions in stream water, organic and mineralogically-modified soil horizons, and terrestrial moss in the northwestern part of Russia and in Finland. Other materials were collected during the pilot phase and later from thirty special sites. The results on respective materials by XRF, ICP-MS and ICP-AES showed that both geological and anthropogenic factors have an influence on the geochemical baseline concentrations of Ni and Cr in organic soil and stream water. The main explanation of the observed distribution patterns in terrestrial moss is human activity, but geological factors can also affect the baselines. The variation of geochemical baselines in the mineral-rich soil horizon depends only on variations in bedrock. The mineralogy of samples mainly controls the leachability properties of soil samples.     

Holocene environmental changes and development of Figurnoye Lake in the southern Bunger Hills, East Antarctica

The lithology, radiocarbon chronology, granulometry, geochemistry and distribution of diatoms were investigated in three sediment cores from fresh-water Figurnoye Lake in the southern Bunger Hills, East Antarctica. Our paleolimnological data provide a record of Holocene environmental changes for this region. In the early Holocene (prior to 9.0 ± 0.5 kyr BP), warm climate conditions caused intensive melting of either the floating glacier ice mass or glaciers in the immediate lake surroundings, leading to the accumulation of terrigenous clastic sediments and limiting biogenic production in the lake. From ca. 9.0 ± 0.5 to 5.5 ± 0.5 kyr BP, highly biogenic sediments dominated by benthic mosses formed, indicating more distal glaciers or snowfields. A relatively cold and dry climate during this period caused weaker lake-water circulation and, likely, occurrence of lake ice conditions were more severe than present. The distribution of marine diatoms in the cores shows that, sometime between 8 and 5 kyr BP, limited amounts of marine water episodically penetrated to the lake, requiring a relative sea-level rise exceeding 10–11 m. During the last ca. 5.5 ± 0.5 kyr BP, sedimentation of mainly biogenic matter with a dominance of laminated microbial mats occurred in the lake under warm climatic conditions, interrupted by relative coolings: the first one around 2 kyr BP and then shortly before recent time. Between ca. 5.5 and 4 kyr BP, the drainage of numerous ice-dammed lakes took place in the southern Bunger Hills and, as a result, drier landscapes have existed here from about 4 kyr BP.