The Mg-carbonate-Fe interaction:Implication for the fate of subducted carbonates and formation of diamond in the lower mantle

The fate of subducted carbonates in the lower mantle and at the core-mantle boundary was modelled via experiments in the MgCO3-Fe^0 system at 70-150 GPa and 800-2600 Kin a laser-heated diamond anvil cell.Using in situ synchrotro n X-ray diffraction and ex situ transmission electron microscopy we show that the reduction of Mg-carbonate can be exemplified by:6 MgCO3+19 Fe=8 FeO+10(Mg0.6Fe^0.4)O+Fe7 C3+3 C.The presented results suggest that the interaction of carbonates with Fe^0 or Fe^0-bearing rocks can produce Fe-carbide and diamond,which can accumulate in the D"region,depending on its carbon to Fe ratio.Due to the sluggish kinetics of the transformation,diamond can remain metastable at the core-mantle boundary(CMB)unless it is in a direct contact with Fe-metal.In addition,it can be remobilized by redox melting accompanying the generation of mantle plumes.     

The Arctic Coastal Dynamics Database: A New Classification Scheme and Statistics on Arctic Permafrost Coastlines

Arctic permafrost coasts are sensitive to changing climate. The lengthening open water season and the increasing open water area are likely to induce greater erosion and threaten community and industry infrastructure as well as dramatically change nutrient pathways in the near-shore zone. The shallow, mediterranean Arctic Ocean is likely to be strongly affected by changes in currently poorly observed arctic coastal dynamics. We present a geomorphological classification scheme for the arctic coast, with 101,447?km of coastline in 1,315 segments. The average rate of erosion for the arctic coast is 0.5?m? year^?1 with high local and regional variability. Highest rates are observed in the Laptev, East Siberian, and Beaufort Seas. Strong spatial variability in associated database bluff height, ground carbon and ice content, and coastline movement highlights the need to estimate the relative importance of shifting coastal fluxes to the Arctic Ocean at multiple spatial scales.     

Improved statistical prediction of surface currents based on historic HF-radar observations

Accurate short-term prediction of surface currents can improve the efficiency of search-and-rescue operations, oil-spill response, and marine operations. We developed a linear statistical model for predicting surface currents (up to 48?h in the future) based on a short time history of past HF-radar observations (past 48?h) and an optional forecast of surface winds. Our model used empirical orthogonal functions (EOFs) to capture spatial correlations in the HF-radar data and used a linear autoregression model to predict the temporal dynamics of the EOF coefficients. We tested the developed statistical model using historical observations of surface currents in Monterey Bay, California. The predicted particle trajectories separated from particles advected with HF-radar data at a rate of 4.4?km/day. The developed model was more accurate than an existing statistical model (drifter separation of 5.5?km/day) and a circulation model (drifter separation of 8.9?km/day). When the wind forecast was not available, the accuracy of our model degraded slightly (drifter separation of 4.9?km/day), but was still better than existing models. We found that the minimal length of the HF-radar data required to train an accurate statistical model was between 1 and 2?years, depending on the accuracy desired. Our evaluation showed that the developed model is accurate, is easier to implement and maintain than existing statistical and circulation models, and can be relocated to other coastal systems of similar complexity that have a sufficient history of HF-radar observations.     

Mesoscale and Nutrient Conditions Associated with the Massive 2008 Cochlodinium polykrikoides Bloom in the Sea of Oman/Arabian Gulf

Cochlodinium polykrikoides formed large blooms in the coastal waters of Oman from October 2008 through mid-January 2009, and satellite images from Aqua-MODIS and region-wide reports suggest that this bloom was found throughout the Arabian Gulf and Sea of Oman for more than 10 months. The unusual occurrence of this species appears to have supplanted the more regularly occurring bloom species, Noctiluca scintillans, in 2008–2009. For the first 2 weeks of the coastal Omani bloom, C. polykrikoides abundance was near monospecific proportions, with cell densities ranging from 4.6?×?10³ to 9?×?10⁶ cells L^?1 and very high levels of chlorophyll a (78.0 μg L^?1) were also recorded. The regional progression of the bloom likely began with stronger than normal upwelling along the Iranian and northern Omani coasts during the southwest monsoon in late summer, followed by discharge of unusually warm coastal plume water along the coast of Oman with the reversal of monsoonal winds in late October. The occurrence and persistence of high densities of C. polykrikoides in Oman coastal water were also significantly influenced by an elevated nutrient load and warmer than normal temperatures. Concentrations of nutrients, especially NH₄ ⁺, urea, PO₄ ^3?, and organic nitrogen and phosphorus, were manyfold higher than observed in the year prior or since. These findings suggest that mesoscale features were important in bloom dynamics more regionally, but locally the bloom was sustained by nutrient enrichment supplemented by its mixotrophic capabilities.     

Computer Expert System for Epithermal Gold-Silver Deposit Prognostication (Okhotsk–Chuckchee Volcanic Belt,Northeast Russia)

The Okhotsk–Chuckchee volcanic belt (OCVB) represents a world class gold–silver province, being a well-studied part of the Circum-Pacific Rim. Extensive research, preceding the system compilation, included collection of various data on major gold–silver, silver–lead–zinc, and tin–silver ore fields (with some data on minor gold–quartz, gold–sulfide, and gold–rare-metal sites). The database consists of 129 ore fields of the OCVB and comprises 433 geological, mineralogical, geochemical, and geophysical indicators. Using the original pattern recognition programs (accounting the frequencies and correlation of the indicators), the most informative indicators were selected, their weights (both positive and negative) were identified, and an expert system (solution tree) was compiled. The computer system is intended to be an assistance to an expert in the ore field potential evaluation. The system includes several blocks of questions with a goal of classifying the geochemical type and size of the analyzed ore field. The questions have an indirect character, so they could be answered by an expert at early stages of exploration (before drilling). The level of recognition of sizes of the ore sites in the control populations is 95% or higher. The aim of the expert system is to reestimate a large number of known ore sites in a relatively brief period of time with the aid of the personal computer. The revealed patterns could be used in other less studied parts of the Circum-Pacific belt.     

Safety of small and medium dams in permafrost regions

Safe operation and performance of dams is one of the key issues in permafrost regions. At present, the existing dams are 40–45 years old and they are reaching their design life limit. Intensive geocryological processes（thermokarst, thermal erosion, frost heaving, suffosion, concentrated seepage along the voids left by melt ice and others） begin to develop at the early stages of construction. These processes are even more intensive under severe climatic conditions of the permafrost zone due to the large thermal and moisture gradients and the resulting complex thermal stress-strain state in the structures. Determining safety criteria is a critical and difficult task in dam safety management. The existing procedures need to be continuously refined and improved depending on dam importance class. Some researchers recommend introducing process development criteria（stability, destabilization, and extremality） for more objective assessment of dam safety, in addition to the existing two condition criteria. In other words, they call for a multi-factor dam – environment interaction system. A case study of safety declaration for an existing dam is presented.     

Time-series analysis of subsidence associated with rapid urbanization in Shanghai,China measured with SBAS InSAR method

River delta plains (deltas) are susceptible to subsidence producing undesirable environmental impact and affecting dense population. The City of Shanghai, located in the easternmost of Yangtze Delta in China, is one of the most developed regions in China that experiences the greatest land subsidence. Excessive groundwater withdrawal is thought to be the primary cause of the land subsidence, but rapid urbanization and economic development, mass construction of skyscrapers, metro lines and highways are also contributing factors. In this paper, a spatial–temporal analysis of the land subsidence in Shanghai was performed with the help of the Small Baseline Subset Interferometric Synthetic Aperture Radar. Twenty l-band ALOS PALSAR images acquired during 2007–2010 were used to produce a linear deformation rate map and to derive time series of ground deformation. The results show homogeneous subsidence within the research area, but exceptionally rapid subsidence around skyscrapers, along metro lines, elevated roads and highways was also observed. Because groundwater exploitation and rapid urbanization responsible for much of the subsidence in the Shanghai region are expected to continue, future subsidence monitoring is warranted.     

北极圈数据库及为何需要

Many factors, such the great changes of temperature, which will be expected at the high latitudes, increased pressure from humans to extract the natural resources in cold regions, seriously affect the cold environment. Many meetings have been held about the classification of cold soils, ideas and concepts of cold soils. These facilitate the need for developing a database of soils of the circumpolar region. The database can help offering information for potential problems in cold regions and for selecting the best areas for placement of new road and towns.     

Nanoporous nanocrystalline impact diamonds

Mineralogy and Petrology - Complementary nano- and atomic-scale data from SEM, FIB, HRTEM, and EELS observations of after-coal impact diamonds from the giant Kara astrobleme are described,...     

Mineral-fluid equilibria in the system CaO–MgO–SiO<Subscript>2</Subscript>–H<Subscript>2</Subscript>O–CO<Subscript>2</Subscript>–NaCl and the record of reactive fluid flow in contact metamorphic aureoles

Phase equilibria in the system CaO–MgO–SiO₂–CO₂–H₂O–NaCl are calculated to illustrate phase relations in metacarbonates over a wide-range of P–T–X[H₂O–CO₂–NaCl] conditions. Calculations are performed using the equation of state of Duan et al. (Geochim Cosmochim Acta 59:2869–2882, 1995) for H₂O–CO₂–NaCl fluids and the internally consistent data set of Gottschalk (Eur J Mineral 9:175–223, 1997) for thermodynamic properties of solids. Results are presented in isothermal-isobarical plots showing stable mineral assemblages as a function of fluid composition. It is shown that in contact-metamorphic P–T regimes the presence of very small concentrations of NaCl in the fluid causes almost all decarbonation reactions to proceed within the two fluid solvus of the H₂O–CO₂–NaCl system. Substantial flow of magma-derived fluids into marbles has been documented for many contact aureoles by shifts in stable isotope geochemistry of the host rocks and by the progress of volatile-producing mineral reactions controlled by fluid compositions. Time-integrated fluid fluxes have been estimated by combining fluid advection/dispersion models with the spatial arrangement of mineral reactions and isotopic resetting. All existing models assume that minerals react in the presence of a single phase H₂O–CO₂ fluid and do not allow for the effect that fluid immiscibility has on the flow patterns. It is shown that fluids emanating from calc-alkaline melts that crystallize at shallow depths are brines. Their salinity may vary depending mainly on pressure and fraction of crystallized melt. Infiltration-driven decarbonation reactions in the host rocks inevitably proceed at the boundaries of the two fluid solvus where the produced CO₂ is immiscible and may separate from the brine as a low salinity, low density H₂O–CO₂ fluid. Most parameters of fluid–rock interaction in contact aureoles that are derived from progress of mineral reactions and stable isotope resetting are probably incorrect because fluid phase separation is disregarded.