Nitrogen isotopes in lunar highlands breccias

Some breccias from the lunar highlands have probably trapped solar wind gases at a very early epoch in the history of the moon, as implied by their high contents of parentless fissiogenic xenon and sometimes, of parentless radiogenic¹²⁹Xe. Four samples of this type, on which noble gas data already exist, have been selected for analysis of nitrogen contents and isotopic composition, by using step-wise heating techniques: 14047, 14055, 14307, 60255. Since uncertainties in the evolution of the solar wind¹⁵N/¹⁴N ratio with time are due in part to uncertainties in the measurement of the epoch of exposure, those samples provided the opportunity to measure the isotopic composition of nitrogen which has been trapped in the remote past, avoiding the problems inherent in the use of spallogenic nuclides. Results show that, in the samples studied from the Apollo 14 landing site, nitrogen is not particularly light, and has not been acquired, as a whole, in very ancient times. The conflicting presence of both parentless xenon and nitrogen of relatively “recent” isotopic signature can be explained if the hypothetical light nitrogen is diluted by more abundant, heavier nitrogen. Accordingly, the very ancient soil components which are implied in these objects by the presence of excess fission xenon have been re-exposed at a much later epoch, or mixed with some younger soil components, before the compaction event. The present data do not question the hypothesis of a secular isotopic variation of lunar trapped nitrogen, but cannot prove that very light nitrogen was trapped together with parentless fission xenon in the soil components of the highlands soil breccias. The very unusual release pattern of nitrogen in breccia 60255 can result from nitrogen isotopic homogenization with gas loss.     

Can Sea Fog be Inferred from Operational GEM Forecast Fields?

Three cases of widespread sea fog in Lunenburg Bay, Nova Scotia were used to evaluate the suitability of operational regional GEM forecast fields for inferring advection fog occurrences. Verification scores suggest that the objective analyses contain significant departures from observations that will affect model accuracy, given the sensitivity of fog condensation microphysics. Dew point depression (ES) scores show larger differences compared to temperature, with both influenced by surface characteristics. For objective analyses and GEM forecasts ES < 2 C seems to match fog satellite images better than the physical threshold ES ≤ 0 C. In addition the GEM forecasts show a general tendency towards drier conditions near the surface, therefore reconfiguring GEM to better represent condensation in the boundary layer is proposed.     

Dynamics of greenhouse gases in the river–groundwater interface in a gaining river stretch (Triffoy catchment,Belgium)

This study investigates the occurrence of greenhouse gases (GHGs) and the role of groundwater as an indirect pathway of GHG emissions into surface waters in a gaining stretch of the Triffoy River agricultural catchment (Belgium). To this end, nitrous oxide (N₂O), methane (CH₄) and carbon dioxide (CO₂) concentrations, the stable isotopes of nitrate, and major ions were monitored in river and groundwater over 8 months. Results indicated that groundwater was strongly oversaturated in N₂O and CO₂ with respect to atmospheric equilibrium (50.1 vs. 0.55 μg L^?1 for N₂O and 14,569 vs. 400 ppm for CO₂), but only marginally for CH₄ (0.45 vs. 0.056 μg L^?1), suggesting that groundwater can be a source of these GHGs to the atmosphere. Nitrification seemed to be the main process for the accumulation of N₂O in groundwater. Oxic conditions prevailing in the aquifer were not prone for the accumulation of CH₄. In fact, the emissions of CH₄ from the river were one to two orders of magnitude higher than the inputs from groundwater, meaning that CH₄ emissions from the river were due to CH₄ in-situ production in riverbed or riparian zone sediments. For CO₂ and N₂O, average emissions from groundwater were 1.5?×?10⁵ kg CO₂ ha^?1 year^?1 and 207 kg N₂O ha^?1 year^?1, respectively. Groundwater is probably an important source of N₂O and CO₂ in gaining streams but when the measures are scaled at catchment scale, these fluxes are probably relatively modest. Nevertheless, their quantification would better constrain nitrogen and carbon budgets in natural systems.     

Stability of Titanium Dioxide Nanoparticle Agglomerates in Transitional Waters and Their Effects Towards Plankton from Lagoon of Venice (Italy)

The present study explores the effect of salinity and dissolved organic carbon (DOC) gradients on the stability and reactivity of titanium dioxide nanoparticle (TiO₂-NP) agglomerates in ambient water from the Lagoon of Venice and their possible effect on nauplii sampled at the same locations. In all ambient water samples, TiO₂-NPs formed rapidly micrometre-sized agglomerates. The increase in the salinity and concomitant decrease in DOC content induced the formation of larger agglomerates, with z-average hydrodynamic diameter increasing with TiO₂-NP concentration and exposure duration. Under the studied conditions, ζ-potential exhibited negative values. In line with agglomeration results, enhancement of the salinity and lower DOC resulted in less negative ζ-potential with close to 0 values in the dispersions of 100 mg L^?1 TiO₂-NPs in sea water. Two-hour exposure to micrometre-sized agglomerates of TiO₂-NPs resulted in an increase in the fluorescence of propidium iodide (PI) stained nauplii in comparison with unexposed controls, but had no effect at 24-h exposure. The increase in nauplii-associated PI fluorescence was more noticeable in dispersions containing 100 mg L^?1 than those containing 10 mg L^?1 TiO₂-NPs, suggesting membrane permeability alteration in a concentration-dependent manner. However, the PI staining results have to be interpreted with caution because of the possible dye binding to the nauplii surface without penetration of cellular membrane. The effect of TiO₂-NPs on nauplii was more pronounced at higher salinity and decreased with increasing DOC concentrations at 2 h, while no trends were found at 24-h exposure, as well as exposure to 100 mg L^?1 TiO₂-NPs.     

Abundance of fin whales (Balaenoptera physalus) in the north-western Mediterranean Sea,using photo-identification and microsatellite genotyping

The Mediterranean fin whale population, Balaenoptera physalus, is resident, with almost no exchanges with the Atlantic population. The entire population was estimated at 1300 or 13,300 individuals by a recent project depending on the platform used. This disparity shows the importance of long-term monitoring with a unique protocol of survey. Capture-recapture approaches using dorsal photographs and genetic identity collections over a 10 years period were used to estimate the abundance of the north-western Mediterranean fin whale. We identified 332 individuals using photographs and 470 using genotypes, with a total of 546 individuals identified between 2008 and 2019, when some whales were double-marked. The inter-annual percentage of recapture varied between 15% and 17% respectively for genotypes and photographs methods. Using Cormack-Jolly-Seber models, the abundance of fin whales in the north-western Mediterranean is estimated at 1295 individuals (95% CI: 1116–1474) with a survival probability of 0.945 (95% CI: 0.690–0.993) from genotypes. Abundance estimates from combined collections (photographs and genotypes) and corrected photograph estimates were similar to the genetic ones. Future studies might prioritize the genetic approach which is the least biased and with a narrower confidence interval. The genetic abundance estimates show relative stability over time, when compared to 1990 estimates, and should be included in future conservation actions.     

Rotational cross sections and rate coefficients of $\mathrm{CP}(\mathrm{X}^{2}\varSigma ^{+})$ induced by its collision with He(1S)$\mathrm{He}(^{1}S)$ at low temperature

The potential energy surface (PES) for the \(\mathrm{CP}(\mathrm{X}^{2}\varSigma^{+})\)-\(\mathrm{He}(^{1}S)\) complex has been calculated at the RCCSD(T)-F12/VTZ-F12 level of theory. The analytic fit of the PES was obtained by using global analytical method. The fitted PES was used subsequently in the close-coupling approach for the computation of the state-to-state collisional excitation cross sections of the fine-structure levels of the CP-He complex. Collision energies were taken up to 1500 cm^?1 and they yield after thermal averaging, state-to-state rate coefficients up to 200 K. The propensity rules between the lowest fine-structure levels were studied. These rules show, on one hand, a strong propensity in favour of even \(\Delta N\) transitions, and the other hand, that cross sections and collisional rate coefficients for \(\Delta j =\Delta N\) transitions are larger than those for \(\Delta j\neq \Delta N\) transitions.     

Chemical weathering studies in relation to geomorphological research in southeastern Canada

Although chemical weathering provides fundamental information relevant to geomorphology, the subject has been overlooked during the 20th century in Canada. This paper provides an overview of the current state of Canadian research on chemical weathering in southeastern Canada and takes into account three spatial and temporal contexts: (1) the formation of bedrock morphology by chemical weathering, (2) occurrences, characteristics and age of saprolites and (3) contemporary chemical denudation rates. Long-term geomorphological evolution of southeastern Canadian landscapes shows that chemical weathering has played an important role. An example is taken from the Laurentide region of the Canadian Shield north of Montréal (Québec). The present topography resulted from the stripping of the former weathering mantle and from the probable subsequent modification of the weathering front, first by the action of hillslope processes and rivers and then by glaciers, before and during Plio-Pleistocene times. The present landscape reflects the timing of the formation of erosion surfaces, and of the stripping of the Paleozoic cover rocks and exposure of the Shield. Since the late seventies, several isolated occurrences of saprolite-soil profiles have been discovered in eastern Canada and prompted a renewal of the study of these materials about the Cenozoic evolution of these regions. One of the problems in this field of research is the dating of saprolites and their inclusion in a chronostratigraphic framework, along with the other Cenozoic surficial deposits and landforms. Because of the multiple factors involved in the development of secondary minerals in saprolites during the course of weathering, it is preferable to distinguish the dating of saprolites from the study of their mineralogical and geochemical evolution. Fortunately, several new techniques are becoming available for the absolute dating of surficial deposits and saprolites, including the use of cosmogenic radionuclides. Saprolites provide a strong potential field of research for our understanding of the geological evolution of eastern Canada during the Cenozoic. Contemporary weathering and erosion rates are fields of research that have gained increasing interest recently, since modeling landscape geochemical response can be applied to various environmental stress situations, such as acidification by rain and forest harvesting. Rock-type may be the main factor explaining the large differences between watersheds. In fact, variability of cation removal in the temperate zone is probably most closely related to flow-paths of water. Investigations, at different scales, from entire watersheds to slopes to individual pedons, highlight the problem. In the Catamaran Brook watershed (New Brunswick), water chemistry is explained by a mix of groundwater and soil solution from the horizons at the base of the floodplain soils. Geochemical mass-balances based on net outputs give little information on the weathering reactions of primary minerals, the weathering products or on the nature of the weathering processes that provide the dissolved load of streams. Mineralogic and petrographic analysis of selected soil pedons are necessary to determine weathering reactions and their role as sources or sinks for bases, silica, aluminum and iron in the various compartments through which water percolates before it reaches the stream.     

Planning the use of fish for food security in the Pacific

Fish is a mainstay of food security for Pacific island countries and territories (PICTs). Recent household income and expenditure surveys, and socio-economic surveys, demonstrate that subsistence fishing still provides the great majority of dietary animal protein in the region. Forecasts of the fish required in 2030 to meet recommended per capita fish consumption, or to maintain current consumption, indicate that even well-managed coastal fisheries will only be able to meet the demand in 6 of 22 PICTs. Governments of many PICTs will need to increase local access to tuna, and develop small-pond aquaculture, to provide food security. Diversifying the supply of fish will also make rural households in the Pacific more resilient to natural disasters, social and political instability, and the uncertainty of climate change.     

Geology and biostratigraphy of the Jurassic and lower cretaceous series to the north of the Lhasa Block (Tibet,China)

Abstract

— The Lhasa Block (s.l.) is bounded to the South by the Tertiary Yarlung Zangbo suture zone and to the North by the terminal Jurassic/earliest Cretaceous Bangong Nu Jiang suture zone. Several tectonostratigraphic units have been recognized in the central-northern part of the Lhasa Block. These are from bottom to top : 1) a thick turbiditic series with a few lenses of allodapic limestones which have yielded an Aalenian — Bajocian foraminiferal assemblage. This series is tectonieally overlain by the Donqiao ophiolite; 2) the continental to shallow marine late Malm to lowermost Cretaceous Zigetang Formation which disconformably overlies the Donqiao ophiolite and 3) continental red detrital rocks or marine Early/Late Aptian boundary to Early Albian foraminifera-rich bedded limestones in which some volcanic rocks are locally interbedded.

We discuss the palaeogeographical distribution and biostratigraphical meaning of some foraminifera (Gutnicella cayeuxi (LUCAS), Palorbitolina fen<ícu/o?(Bl .LMKNBACIl), Praeorbitolina cormyi SCHROEDER and Palor-bilolmoides hedini CHREREHI and ScilKOKDK.lt) and their bearing on the radiometric age of the Aptian-Albian boundary.