Rotational cross sections and rate coefficients of $\mathrm{CP}(\mathrm{X}^{2}\varSigma ^{+})$ induced by its collision with He(1S)$\mathrm{He}(^{1}S)$ at low temperature

The potential energy surface (PES) for the \(\mathrm{CP}(\mathrm{X}^{2}\varSigma^{+})\)-\(\mathrm{He}(^{1}S)\) complex has been calculated at the RCCSD(T)-F12/VTZ-F12 level of theory. The analytic fit of the PES was obtained by using global analytical method. The fitted PES was used subsequently in the close-coupling approach for the computation of the state-to-state collisional excitation cross sections of the fine-structure levels of the CP-He complex. Collision energies were taken up to 1500 cm^?1 and they yield after thermal averaging, state-to-state rate coefficients up to 200 K. The propensity rules between the lowest fine-structure levels were studied. These rules show, on one hand, a strong propensity in favour of even \(\Delta N\) transitions, and the other hand, that cross sections and collisional rate coefficients for \(\Delta j =\Delta N\) transitions are larger than those for \(\Delta j\neq \Delta N\) transitions.     

Chemical weathering studies in relation to geomorphological research in southeastern Canada

Although chemical weathering provides fundamental information relevant to geomorphology, the subject has been overlooked during the 20th century in Canada. This paper provides an overview of the current state of Canadian research on chemical weathering in southeastern Canada and takes into account three spatial and temporal contexts: (1) the formation of bedrock morphology by chemical weathering, (2) occurrences, characteristics and age of saprolites and (3) contemporary chemical denudation rates. Long-term geomorphological evolution of southeastern Canadian landscapes shows that chemical weathering has played an important role. An example is taken from the Laurentide region of the Canadian Shield north of Montréal (Québec). The present topography resulted from the stripping of the former weathering mantle and from the probable subsequent modification of the weathering front, first by the action of hillslope processes and rivers and then by glaciers, before and during Plio-Pleistocene times. The present landscape reflects the timing of the formation of erosion surfaces, and of the stripping of the Paleozoic cover rocks and exposure of the Shield. Since the late seventies, several isolated occurrences of saprolite-soil profiles have been discovered in eastern Canada and prompted a renewal of the study of these materials about the Cenozoic evolution of these regions. One of the problems in this field of research is the dating of saprolites and their inclusion in a chronostratigraphic framework, along with the other Cenozoic surficial deposits and landforms. Because of the multiple factors involved in the development of secondary minerals in saprolites during the course of weathering, it is preferable to distinguish the dating of saprolites from the study of their mineralogical and geochemical evolution. Fortunately, several new techniques are becoming available for the absolute dating of surficial deposits and saprolites, including the use of cosmogenic radionuclides. Saprolites provide a strong potential field of research for our understanding of the geological evolution of eastern Canada during the Cenozoic. Contemporary weathering and erosion rates are fields of research that have gained increasing interest recently, since modeling landscape geochemical response can be applied to various environmental stress situations, such as acidification by rain and forest harvesting. Rock-type may be the main factor explaining the large differences between watersheds. In fact, variability of cation removal in the temperate zone is probably most closely related to flow-paths of water. Investigations, at different scales, from entire watersheds to slopes to individual pedons, highlight the problem. In the Catamaran Brook watershed (New Brunswick), water chemistry is explained by a mix of groundwater and soil solution from the horizons at the base of the floodplain soils. Geochemical mass-balances based on net outputs give little information on the weathering reactions of primary minerals, the weathering products or on the nature of the weathering processes that provide the dissolved load of streams. Mineralogic and petrographic analysis of selected soil pedons are necessary to determine weathering reactions and their role as sources or sinks for bases, silica, aluminum and iron in the various compartments through which water percolates before it reaches the stream.     

Planning the use of fish for food security in the Pacific

Fish is a mainstay of food security for Pacific island countries and territories (PICTs). Recent household income and expenditure surveys, and socio-economic surveys, demonstrate that subsistence fishing still provides the great majority of dietary animal protein in the region. Forecasts of the fish required in 2030 to meet recommended per capita fish consumption, or to maintain current consumption, indicate that even well-managed coastal fisheries will only be able to meet the demand in 6 of 22 PICTs. Governments of many PICTs will need to increase local access to tuna, and develop small-pond aquaculture, to provide food security. Diversifying the supply of fish will also make rural households in the Pacific more resilient to natural disasters, social and political instability, and the uncertainty of climate change.     

Dating multistage paleofluid percolations: A K-Ar and O/O study of fracture illites from altered Hercynian plutonites at the basement/cover interface (Poitou High, France)

Isotopic age determination of fluid events in basement fractures is of prime importance for the reconstruction of paleo-hydraulic regimes. However, material from fracture or wall-rock is not generally easily dated. In the case of fractures filled by minerals such as phyllosilicates, it can be expected that subsequent fluid circulation may cause partial alteration or recrystallization of the previous phyllosilicates, disturbing the isotope signature. Using a specific methodology, including the extraction process without contamination of the finest (<0.2 μm) authigenic fractions, identification of clay fractions by X-ray diffraction (XRD), scanning electron microscopy, and electron microprobe, analysis of stable isotope composition (D/H, δ¹⁸O) and K-Ar dating, fluid event ages can be estimated. This methodology was applied to the northwestern margin of the French Massif Central, where basinal brines have interacted with the sedimentary cover (infra-Toarcian formations) and the fractured Hercynian crystalline basement. During periods of unknown age, precipitates from brines sealed most basement fractures as carbonates, and a recrystallization of early Hercynian phengite (+chlorite) into illite and illite/smectite minerals occurred in the earlier fractures.XRD patterns show that the clay fraction is dominated by illite and ordered mixed-layer minerals having a relatively high amount of illite (I-S R3). In the shallowest samples beneath the paleo-surface, a late assemblage is identified as a mixture of I-S minerals, a part of them being characterized by significant amounts of swelling layers (I-S R0).The δD values of the clay fractions are fairly constant around −50 ± 10‰, but δ¹⁸O values of the same clay fractions display a wide range from 8‰ to 18‰ (SMOW). The study of the size fractions between 2 and 0.2 μm reveals a correlation between K-Ar ages and δ¹⁸O values, which cannot be related to a change in the relative amounts of clay minerals. Deep fractures (at depths of 570 and 923 m) are characterized by δ¹⁸O values around 10.3 ± 0.4‰ SMOW and old ages ranging from 253 to 272 Ma. The finest fractions (<0.2 μm) of clays located at shallow level (<300 m) beneath the paleo-surface yield the highest δ¹⁸O values (15.7-18.2‰) and the youngest K-Ar dates (188 to 198 Ma). These dates are likely to record the extensional episode and thermal anomaly related to the rifting of central Atlantic Ocean (c. 190 Ma). The other important thermal/extensional episode which affected the Aquitaine Basin, namely the opening of the Gascogne gulf at c. 120 Ma, is not detected by the K-Ar method on the clay fractions. We believe that resetting of clay-type K-Ar ages linked to recrystallization was favoured in the upper part of the basement where the ancient (Hercynian) clay minerals were destabilized by subaerial low-temperature alteration during Permo-Triassic times.From a methodologic point of view, the analytical characterization of several size fractions of clays from reactivated fractures, using both stable isotope geochemistry and K-Ar isotope geochemistry, can be considered as a powerful tool for dating fluid events when no suitable material for conventional methods is available.     

The missing Myopus: plugging the gaps in Late Pleistocene small mammal identification in western Europe with geometric morphometrics

Lemmus and Myopus are two lemming species with distinct habitat requirements but which show very similar dental morphologies. They are thus extremely difficult to distinguish from one another in the fossil record on the basis of their dental remains, leading to poor understanding of the palaeobiogeographical evolution of Myopus as well as inaccurate palaeoenvrionmental reconstructions. Currently, the presence of Myopus in the fossil register from the Pleistocene is still debated and no firm occurrence of this lemming in western Europe has yet been confirmed for the Late Pleistocene. In this paper, we used geometric morphometrics on modern material to establish morphological differences between Lemmus and Myopus teeth (first lower and third upper molars). Morphological data were then used to build a robust linear discriminant model able to confidently classify isolated teeth of these two genera, and finally, linear discriminant models were used on fossil remains of Lemmus/Myopus from two Late Pleistocene archaeological/palaeontological sites (Grotte des Gorges and Gully Cave). This study demonstrates, for the first time, the presence of Myopus schisticolor in west European Late Pleistocene sites between the end of Marine Isotope Stage 3 and the beginning of the Holocene, during climatic events that favoured the development of taiga forest of birch and pine in these regions.     

Regional climate modelling of the 2006 West African monsoon: sensitivity to convection and planetary boundary layer parameterisation using WRF

Regional climate model (RCM) is a valuable scientific tool to address the mechanisms of regional atmospheric systems such as the West African monsoon (WAM). This study aims to improve our understanding of the impact of some physical schemes of RCM on the WAM representation. The weather research and forecasting model has been used by performing six simulations of the 2006 summer WAM season. These simulations use all combinations of three convective parameterization schemes (CPSs) and two planetary boundary layer schemes (PBLSs). By comparing the simulations to a large set of observations and analysis products, we have evaluated the ability of these RCM parameterizations to reproduce different aspects of the regional atmospheric circulation of the WAM. This study focuses in particular on the WAM onset and the rainfall variability simulated over this domain. According to the different parameterizations tested, the PBLSs seem to have the strongest effect on temperature, humidity vertical distribution and rainfall amount. On the other hand, dynamics and precipitation variability are strongly influenced by CPSs. In particular, the Mellor?CYamada?CJanjic PBLS attributes more realistic values of humidity and temperature. Combined with the Kain?CFritsch CPS, the WAM onset is well represented. The different schemes combination tested also reveal the role of different regional climate features on WAM dynamics, namely the low level circulation, the land?Catmosphere interactions and the meridional temperature gradient between the Guinean coast and the Sahel.     

Application of regularised optimal fingerprinting to attribution. Part I: method, properties and idealised analysis

Optimal fingerprinting has been the most widely used method for climate change detection and attribution over the last decade. The implementation of optimal fingerprinting often involves projecting onto k leading empirical orthogonal functions in order to decrease the dimension of the data and improve the estimate of internal climate variability. However, results may be sensitive to k, and the choice of k remains at least partly arbitrary. One alternative, known as regularised optimal fingerprinting (ROF), has been recently proposed for detection. This is an extension of the optimal fingerprinting detection method, which avoids the projection step. Here, we first extend ROF to the attribution problem. This is done using both ordinary and total least square approaches. Internal variability is estimated from long control simulations. The residual consistency test is also adapted to this new method. We then show, via Monte Carlo simulations, that ROF is more accurate than the standard method, in a mean squared error sense. This result holds for both ordinary and total least square statistical models, whatever the chosen truncation k. Finally, ROF is applied to global near-surface temperatures in a perfect model framework. Improvements provided by this new method are illustrated by a detailed comparison with the results from the standard method. Our results support the conclusion that ROF provides a much more objective and somewhat more accurate implementation of optimal fingerprinting in detection and attribution studies.     

Oxygen isotope variability in calcite shells of the ostracod Cyprideis torosa in Akyatan Lagoon,Turkey

The euryhaline ostracod Cyprideis torosa lives in Akyatan Lagoon, Turkey, which is exposed to large spatial and seasonal variations in water salinity, δ¹⁸O, and temperature. Hydrogen and oxygen isotope measurements of waters reveal that the large range of salinity (15–80 g L^?1) in the lagoon results from a combination of evaporation and mixing between Mediterranean seawater and Seyhan River input. Round sieve-pore relative abundance in C. torosa provides a robust proxy for water salinity (S) from 15 to 80 g L^?1, according to the equation: S = 161.41 (±4.52) * log₁₀(% rounded pores) ? 94.04 (±3.44) (R² = 0.937; p = 10^?31). Seasonal sampling and isotope analysis of C. torosa in waters of known δ¹⁸O values (?4.7 to +6.9 ‰ V-PDB) and temperatures (15–35 °C) yielded a weak positive correlation (r = 0.71) between 1000 lnα_{(calcite–water)} ‰ V-SMOW) and 10³ * T^?1. Specimens of C. torosa collected during the mild and warm seasons have oxygen isotope compositions close to those of inorganic calcite precipitated in equilibrium with ambient water. The large oxygen-isotope variability observed during any season of the year most likely results from shell calcification in water bodies of highly variable salinity, alkalinity, Mg/Ca and water saturation relative to calcite. Indeed, distinct water bodies in the Akyatan Lagoon are generated by mixing of fresh and marine waters, which are exposed to different evaporation rates at the seasonal scale.     

Towards a dedicated impact portal to bridge the gap between the impact and climate communities : Lessons from use cases

Future climate evolution is of primary importance for the societal, economical, political orientations and decision-making. It explains the increasing use of climate projections as input for quantitative impact studies, assessing vulnerability and defining adaptation strategies in different sectors. Here we analyse 17 national and representative use cases so as to identify the diversity of the demand for climate information depending on user profiles as well as the best practices, methods and tools that are needed to answer the different requests. A particular emphasis is put on the workflow that allows to translate climate data into suitable impact data, the way to deal with the different sources of uncertainty and to provide a suited product to users. We identified three complementary tools to close the gap between climate scientists and user needs: an efficient interface between users and providers; an optimized methodology to handle user requests and a portal to facilitate access to data and elaborated products. We detail in the paper how these three tools can limit the intervention of experts, educate users, and lead to the production of useful information. This work provides the basis on which the ENES (European Network for Earth System Modelling) Portal Interface for the Climate Impact Communities is built.