A comparison of scavenging and deposition processes in global models: results from the WCRP Cambridge Workshop of 1995

We report on results from a World Climate Research Program workshop on representations of scavenging and deposition processes in global transport models of the atmosphere. 15 models were evaluated by comparing simulations of radon, lead, sulfur dioxide, and sulfate against each other, and against observations of these constituents. This paper provides a survey on the simulation differences between models. It identifies circumstances where models are consistent with observations or with each other, and where they differ from observations or with each other. The comparison shows that most models are able to simulate seasonal species concentrations near the surface over continental sites to within a factor of 2 over many regions of the globe. Models tend to agree more closely over source (continental) regions than for remote (polar and oceanic) regions. Model simulations differ most strongly in the upper troposphere for species undergoing wet scavenging processes. There are not a sufficient number of observations to characterize the climatology (long‐term average) of species undergoing wet scavenging in the upper troposphere. This highlights the need for either a different strategy for model evaluation (e.g., comparisons on an event by event basis) or many more observations of a few carefully chosen constituents.     

淡水双壳类壳体碳同位素研究:以河蚬(corbicula fluminea,Müller 1774)为例

双壳类壳体碳酸盐(文石)稳定同位素组成已被广泛地用于古气候和古环境重建研究中,但是双壳类壳体碳同位素组成所指示的气候和环境意义一直是争议的问题.对双壳类河蚬(corbicula fluminea)进行了室内养殖,并选取两个壳体样品(壳高,A=13 mm,B=9mm),测定其生长部分壳体和生长期间水体碳同位素,研究表明,随着水体碳同位素的升高(δ13CDIC由-5.24‰升至1.41‰),两壳体碳同位素也随之升高,表明水体对壳体碳同位素的影响;δ13CA分布范围为-4.76‰～2.09‰,δ13CB为-8.49‰～2.89,壳体A和B碳同位素均比预测平衡值偏负,表明壳体在形成过程中利用了新陈代谢产生的富集12C的CO2.根据计算壳体A在实验中沉淀部分壳体利用新陈代谢碳的比例(M值)为24%～43%,平均值为33%;壳体B为33%～75%,平均值为58%.M值随生物的生长呈下降变化,这说明在实验中河蚬主要是通过增加对DIC的吸收和利用来满足壳体生长对物质量增加的需求.     

针式微萃取结合GC-IRMS测定水溶液中甲酸、乙酸的稳定碳同位素组成

甲酸和乙酸稳定碳同位素组成（δ^13C）的分析对环境、食品、制药和自然产品等的研究具有重要的应用价值。但目前尚缺乏有效的测定方法。本研究利用最近出现的针式固相微萃取技术（NeedlEX）,以吹扫．捕集方式对水溶液中的有机酸进行了萃取,然后利用气相色谱．同位素比值质谱联用仪（GC—IRMS）对所萃取的有机酸分子进行了占δ^13C的测定。结果显示,质谱计的信号强度与水溶液中有机酸的浓度存在显著的线性相关关系（R^2〉0．99,P〈0．05）,表明Needl EX对水溶液中有机酸具有稳定的萃取能力。在甲酸与乙酸含量分别不低于300μg／mL与200μg／mL的水溶液中,1000mL的吹扫体积可以使两者δ^13C多次分析结果的相对误差分别保持在3％和1％左右,且整个实验流程没有造成可检测的碳同位素分馏作用。低于这两个浓度界线,则分析误差随浓度的降低迅速增加。本研究虽然是针对水溶液中有机酸δ^13C的测定,其萃取方法对其他水溶性挥发和半挥发有机物δ^13C的分析也同样具有应用价值。     

大兴安岭中生代两类流纹岩与玄武岩的成因联系

根据地质产状和地球化学特征大兴安岭中生代流纹岩类可划分为高Ti流纹岩和低Ti流纹岩。高Ti流纹岩类与亚碱性系列玄武岩类紧密伴生 ,两者在地球化学上构成连续变异系列。低Ti流纹岩类则与碱性系列玄武岩类构成地球化学双峰态。岩相学和地球化学研究表明 ,这两类流纹岩与该区同期玄武岩类有着密切的成因联系 :起源于地幔柱亏损成分的亚碱性系列玄武岩浆经过单斜辉石、斜长石、磷灰石、锆石的分离结晶 ,形成亚碱性系列低钾玄武岩→高钾玄武岩→高Ti流纹岩演化系列 ;起源于地幔柱富集成分的碱性系列玄武岩浆侵入下地壳 ,使下地壳岩石发生部分熔融 ,形成碱性系列玄武岩 -低Ti流纹岩双峰态组合     

Structural state of detrital alkali feldspars

The structural state of an alkali feldspar is determined by the nature of the distribution of Al and Si in the tetrahedral sites of the feldspar structure. This state is a function of a number of genetic controls including temperature, cooling rate, deformation, crystal size, and several chemical factors. Together these controls constitute a genetic regime. Identification of the structures of detrital feldspars may enable recognition of genetic regimes and be useful in provenance interpretation and mineral province definition. A 2-peak method of X-ray diffraction (XRD) determination as a variant of an earlier proposed 3-peak method of structural state determination is used in this study. Total analytical time for each determination is about 50–55 min per grain. Results of structural state identification of 126 detrital feldspars from Holocene stream sands derived from volcanic, plutonic and metamorphic rocks are presented in order to illustrate the application and potential of the technique. Detrital feldspars from the metamorphic rocks are all maximum microcline; those from the plutons range from orthoclase to microcline depending on the age of the pluton, whereas those from the volcanic rocks are sanidines.     

玩具业中重金属的等离子体发射光谱分析

为了支持玩具业,许多实验室需要分析各种复杂基体中的金属含量。人们关心的主要元素是铅,但很多其他有毒元素也具有潜在的威胁,尤其对于儿童。这些重金属元素包括锑、砷、钡、镉、铬、硒、汞和铅,累积在人体中将产生不利的影响。一些塑料和木制玩具,特别是表面色彩鲜艳的玩具被证实含有更高水平的铅和其他元素,儿童因接触易摄入,相关法规对产品表面含有这些元素的材料作了一些限制。为了保证玩具和其他物品的生产、流通和销售,有必要检测其中的重金属含量。不同的管理机构对各类样品中的元素提供了限量要求。在玩具安全性的欧洲标准EN71第3部分(已纳入ISO8124-3),其中在“特定元素的迁移”一节给出了玩具材料中元素迁移的     

西江干流河水主要离子及锶同位素地球化学组成特征

水环境中锶（Sr）含量及其同位素组成特征的研究有助于认识区域水文地球化学特征及流域盆地岩石风化速率等地球化学行为,因此河流环境中Sr的地球化学行为是地球化学研究的重要课题之一。对中国南方西江干流及其支流河水主要阴阳离子及sr同位素组成进行了分析,发现其水化学组成主要以Ca^2＋、Mg^2＋、HCO3^-和SO4^2-离子为主,分别占阴阳离子组成的80％以上。郁江河水具有较高的Sr同位素比值（^87St／^86Sr=0．71049）和较低的Sr含量（0．0263mg／L）,而西江河水具有较低的Sr同位素比值以及较高的Sr含量,其Sr含量变化范围在0．0667．0．187mg／L之间,平均含量为0．136mg／L;Sr同位素比值变化范围在0．70856．0．70936之间,平均比值为0．70894。与世界主要河流水体中Sr含量平均值（0．078mg／L）及Sr同位素比值（^87Sr／^86Sr=0．7119）相比,西江干流水体具有较高的Sr含量及较低的Sr同位素比值。两条河流河水中主要离子及Sr的来源存在显著差异,西江干流河水中的主要溶解离子及Sr同位素主要源于碳酸盐岩（石灰岩和白云岩）的风化作用,主要受黔江及其上游红水河等化学组成所控制,而郁江则主要受碎屑岩风化作用的影响;同时,中上游地区的酸沉降及人类活动的输入可能导致西江干流水体受到一定程度的污染,而郁江受污染程度则相对较小。     

Contrast in Fluid M etallogeny between the Tianmashan Au-S Deposit and the Datuanshan Cu Deposit in Tongling, Anhui Province

A comprehensive contrast of ore-forming geological background and ore-forming fluid features, especially fluid ore-forming processes, has been performed between the Tianmashan and the Datuanshan ore deposits in Tongling, Anhui Province. The major reasons for the formation of the stratabound skarn Au-S ore deposit in Tianmashan and the stratabound skarn Cu ore deposit in Datuanshan are analyzed in accordance with this contrast. The magmatic pluton in Tianmashan is rich in Au and poor in Cu, but that in Datuanshan is rich in Cu and Au. The wallrock strata in Tianmashan contain Au-bearing pyrite layers with some organic substance but those in Datuanshan contain no such layers. Moreover, the ore-forming fluids in Tianmashan are dominantly magmatic ones at the oxide and sulfide stages, but those with high content of Cu in Datuanshan are mainly groundwater fluids. In addition, differences in compositional evolution and physicochemical condition variation of the ore-forming fluids result in gradual dispersion     

闽西南晚中生代四方岩体同位素年代学、地球化学及其构造意义

闽西南地区四方岩体主要由花岗闪长岩和花岗闪长斑岩组成 ,花岗闪长岩单颗粒锆石 U-Pb年龄为 10 7.8±1.2 Ma,角闪石 Ar-Ar年龄为 10 4.8± 0 .8Ma,形成于早白垩世。岩体是在伸展拉张构造环境下以快速冷却 (50～ 60℃ / Ma)侵位的 ,岩石相对富 Na2 O,A / CNK<1,具壳 -幔混合源 I型花岗岩特征。岩石富 K、Rb、Th、U、L REE,贫 Ti、Nb、Ta、Sr,具火山弧/活动大陆边缘钙碱性岩系的特征。 (87Sr/ 86Sr) i为 0 .70 63 5～ 0 .70 898,εNd(t)为 -5.2 4～ -3 .69,TDM为 1.3 3～ 1.2 1Ga。岩石主要由幔源岩浆与中下地壳物质部分熔融形成的花岗质岩浆的混合形成的。与闽东沿海地区相比 ,晚中生代时闽西南地区总体处于与华南软流圈地幔上涌有关的伸展拉张构造环境 ,但由玄武岩浆底侵作用引发的壳幔作用并不强烈。该时期中酸性岩浆作用与成矿关系十分密切