Hydrogeochemistry and environmental isotopes of ground water in Jeju volcanic island,Korea: implications for nitrate contamination

Ground water from springs and public supply wells was investigated for hydrochemistry and environmental isotopes of ³H, ¹⁸O and D in Jeju volcanic island, Korea. The wells are completed in a basaltic aquifer and the upper part of hydrovolcanic sedimentary formation. Nitrate contamination is conspicuous in the coastal area where most of the samples have nitrate concentrations well above 1 mg NO₃ N/l. Agricultural land use seems to have a strong influence on the distribution of nitrate in ground water. Comparison of stable isotopic compositions of precipitation and ground water show that ground water mostly originates from rainy season precipitation without significant secondary modification and that local recharge is dominant. ³H concentration of ground water ranged from nearly zero to 5 TU and is poorly correlated with vertical location of well screens. The occurrence of the ³H‐free, old ground water is due to the presence of low permeability layers near the boundary of the basaltic aquifer and the hydrovolcanic sedimentary formation, which significantly limits ground water flow from the upper basaltic aquifer. The old ground water exhibited background‐level nitrate concentrations despite high nitrate loadings, whereas young ground water had considerably higher nitrate concentrations. This correlation of ³H and nitrate concentration may be ascribed to the history of fertilizer use that has increased dramatically since the early 1960s in the island. This suggests that ³H can be used as a qualitative indicator for aquifer vulnerability to nitrate contamination. Copyright © 2005 John Wiley & Sons, Ltd.     

Stress integration approach to evaluate damping ratio in torsional tests

The complexity of determining strain associated with shear modulus and damping ratio in torsional tests has been resolved by means of several approaches. The stress integration approach is adequate when generating the plots of equivalent radius ratio versus strain more effectively over any range of strains in resonant column and torsional shear (RC/TS) tests. The stress integration approach was applied for hyperbolic, modified hyperbolic, and Ramberg–Osgood models in evaluating damping ratio. This study showed that using a single value of equivalent radius ratio in evaluating damping ratio is not appropriate. The combined hysteretic‐nonviscous damping model was developed and employed to consider the increased damping behavior at small strains using the stress integration approach. The results suggest that adding viscous behavior has no significant effect strain calculations in RC/TS testing. Copyright © 2010 John Wiley & Sons, Ltd.     

Space-continuous measurements on ocean current and chemicalproperties with the intelligent towed vehicle “Flying Fish”

A research project to develop observation systems for heat, momentum, and material circulation in the ocean and atmosphere was carried out from 1992 to 1997. A pitch, roll, and depth controllable towed vehicle called “Flying Fish” was developed which houses an acoustic Doppler current profiler, CO₂ analyzer, and sensors for measuring temperature, salinity, dissolved oxygen, pH, turbidity, and chlorophyll. The length of the vehicle is 3.84 m, the breadth is 2.26 m, the height is 1.4 m, the weight in air is 1400 kg, and the weight in water is roughly 0 kg. Flying Fish enables us to obtain space-continuous data of physical and chemical properties efficiently in the upper mixed layer of the ocean, From 1994 to 1997, the vehicle was used for observations in the northern, southern, and central parts of the Japan Sea in a collaborative study by Japan, Korea, and Russia. Examples of data obtained are shown in this paper and the results of current velocities are compared with those taken by other observation systems     

Multivariate statistical analysis of underground gas storage caverns on groundwater chemistry in Korea

An understanding of groundwater flow and chemistry is important to operate underground storage caverns. Groundwater flow is mainly affected by cavern operating conditions. Groundwater chemistry is modified by disinfection activities for removing possible biological clogging and by mixing with cement pore water. It is important to discern these two effects, because wells affected by the disinfection activities may have hydrological connections with water curtains used to inject the disinfectant. However, it is difficult to separate these two effects using graphical methods because of their similar chemical characteristics. Instead, multivariate statistical analysis, such as principal component analysis (PCA) and factor analysis (FA), can be used. Groundwater samples for chemical analysis were obtained from four surveys in 1999–2000. Based on the results from PCA and FA, it appears that there were temporal variations of seepage water into the propane area when the cavern operation fluctuated, but we could not observe such variation in the butane area. These changes may occur mainly at depth, where water flow is slow and water renewal in the cavern surrounding is limited. Copyright © 2008 John Wiley & Sons, Ltd.     

Pilot-scale field model tests for detecting landfill leachate intrusion into the subsurface using a grid-net electrical conductivity measurement system

The grid-net electrical conductivity measurement system for detecting exact locations of landfill leachate intrusion in the subsurface was developed in this study. Laboratory and pilot-scale field model tests were performed to evaluate the direct application of a grid-net electrical conductivity measurement system for the detection of landfill leachate. A significant increase in electrical conductivity of soil was observed by adding landfill leachate. This can be explained as an increase in electrical conductivity of pore fluid due to an increase in leachate constituents as charge carriers. In pilot-scale field model tests, leachate intrusion locations were accurately identified at the initial stage of landfill leachate release by the grid-net electrical conductivity measurement system. The electrical conductivity of the subsurface before leachate injection lay within a small range of 24.8–43.0 S/cm. The electrical conductivity values in detected points were approximately ten times more than the conductivity values of the subsurface without landfill leachate intrusion. The results in this study indicate that the grid-net electrical conductivity measurement method has a possible application for detecting locations of landfill leachate intrusion into the subsurface at the initial stage, and thus has great potential in monitoring leachate leakage at waste landfills.     

Active sensing using impedance‐based ARX models and extreme value statistics for damage detection

In this paper, the applicability of an auto‐regressive model with exogenous inputs (ARX) in the frequency domain to structural health monitoring (SHM) is established. Damage sensitive features that explicitly consider non‐linear system input/output relationships are extracted from the ARX model. Furthermore, because of the non‐Gaussian nature of the extracted features, Extreme Value Statistics (EVS) is employed to develop a robust damage classifier. EVS provides superior performance to standard statistical methods because the data of interest are in the tails (extremes) of the damage sensitive feature distribution. The suitability of the ARX model, combined with EVS, to non‐linear damage detection is demonstrated using vibration data obtained from a laboratory experiment of a three‐story building model. It is found that the vibration‐based method, while able to discern when damage is present in the structure, is unable to localize the damage to a particular joint. An impedance‐based active sensing method using piezoelectric (PZT) material as both an actuator and a sensor is then investigated as an alternative solution to the problem of damage localization. Copyright © 2005 John Wiley & Sons, Ltd.     

Evaluation of multiphase flotation models in grid turbulence via Particle Image Velocimetry

Industrial processes involving multi-phase flows such as flotation require understanding of the relationships between bubbles, solid particles and the flow. Modern experimental tools are employed in this effort to measure with great accuracy the basic features of the motion of all three phases in turbulent flow. We employed a unique Digital Particle Image Velocimeter (DPIV) that can record with great accuracy and kHz temporal resolution, velocity vectors of all three phases, namely the fluid, the solid particles and the air bubbles. The interaction of these three phases was studied in homogeneous isotropic turbulence generated by cylindrical grids. Particles and bubbles were released into the turbulence and the motions of the three phases were monitored. The experimental results obtained in the present work were compared with the predictions of the models published in the literature.     

Distribution of Cs and Pu in the surface waters of the East Sea (Sea of Japan)

Surface and subsurface water samples for ¹³⁷Cs and ^239,240Pu analysis were collected in the East Sea (Sea of Japan) during August 1993. The ¹³⁷Cs levels of the surface waters are quite homogeneous in the East Sea (average = 3.1±0.2 mBq kg⁻¹). The ^239,240Pu levels vary from 6 to 10 μBq kg⁻¹ in the surface. ^239,240Pu to ¹³⁷Cs ratios in the surface water are within 0.002 to 0.003. The East Sea may be regarded as a part of the North Pacific Ocean in terms of ¹³⁷Cs dispersal in the surface, where the ¹³⁷Cs contents of the surface seawater seem to be controlled primarily by the atmospheric input. However, since our sampling was made just two months prior to the widely publicized Russian dumping incident on the 17th October 1993, our measurements may provide background data to assess the immediate impact of the Russian dumping on the levels of ¹³⁷Cs and ^239,240Pu in the East Sea.