Constitutive modelling of state-dependent behaviour of unsaturated soils: an overview

An unsaturated soil is a three-phase material that is ubiquitous on the earth’s surface. The fully saturated and completely dry states are just two limiting conditions of an unsaturated soil. The state and properties of unsaturated soils can change significantly with external loads, weather conditions and groundwater level. Proper modelling of the state-dependent behaviour of unsaturated soils is crucial for analysing the performance of almost all civil engineering structures. So far, there are many unsaturated soil models and several relevant review papers in the literature. None of the existing review papers, however, focused on the state dependency of unsaturated soil behaviour. Moreover, some aspects of soil behaviour have not been reviewed, including small strain stiffness, dilatancy and stress-dependence of water retention curve. In the current review paper, the state dependency of unsaturated soil behaviour is reviewed, with a particular attention to the three missing parts. The review is carried out in a unified and relatively simple constitutive framework, which adopts a three-by-three compliance matrix to link incremental volumetric strain, deviator strain and degree of saturation to incremental mean net stress, deviator stress and suction. All of the nine variables in the proposed three-by-three compliance matrix have clear physical meanings and can be measured through compression, shearing and water retention tests. Theoretical models based on other constitutive stress variables can be also converted to this framework by matrix transformation.

     

Mineralogy and radioactivity of pegmatites from South Wadi Khuda area,Eastern Desert,Egypt

Stohl F.V.and Smith (1981) The Crystal Chemistry of the Uranyl Silicate Minerals[M].Department of Geosciences,the Pennsylvania State University,University Park.Pennsylvania.

Stuckless J.S.,Nkomo I.T.,Wenmer D.B.,and Van Trump G.(1984) Geochemistry and uranium favourability of the postorogenic granites of the north-eastern Arabian Shield,Kingdom of Saudi Arabia[J].Bull Fac.Earth Sci.King Abdel Aziz Univ.6,195-209.

William S.B.,Hanson S.L.,and Falster A.U.(2006) Samarskite-Yb:A new species of the samarskite group from the Little Patsy pegmatites,Jefferson County,Colorado[J].Canadian Mineralogist.44,1119-1125.

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Modeling in situ benzene bioremediation in the contaminated Liwa aquifer (UAE) using the slow-release oxygen source technique

Dissolved benzene was detected in the shallow unconfined Liwa aquifer, UAE, which represents the main freshwater source for the nearby residence Bu Hasa camp area. The main source of this contamination is believed to be the rejected water released from Bu Hasa liquid recovery plant. In this paper, a finite element model (METABIOTRANS) is used to simulate the fate and transport of the dissolved benzene plume in Liwa aquifer. Different remediation scenarios were simulated in which the slow-release oxygen source (SOS) technique is utilized to minimize benzene concentrations at the nearest camp supply wells downstream of the contamination zone. Results of the remediation scenarios show that the highest biodegradation rates occur when the oxygen source is placed near the plume center; where higher benzene concentrations exist. The nearest oxygen release source to the contamination zone caused higher stimulation to bacterial growth than further down-gradient oxygen sources. It also exhibited longer resident time of oxygen in the aquifer; and therefore, yielded higher reductions in benzene concentrations. However, using one central SOS proved to be insufficient as contaminant escaped laterally. Additional four transverse oxygen sources were necessary to capture benzene that laterally spread away from the contamination zone. These lateral SOSs were essential to reduce benzene concentrations at the supply wells that are located at the plume fringes. Finally, it was found that increasing oxygen release from one source did not always improve remediation; and that using several SOSs with lower release rates could be a more practical approach to enhance benzene biodegradation in the aquifer.     

Even-numbered <Emphasis Type="Italic">n</Emphasis>-alkanes/<Emphasis Type="Italic">n</Emphasis>-alkenes predominance in surface sediments of Gabes Gulf in Tunisia

We investigated the mineral composition and trace element contents of dustfall with different deposited phases at the Minqin Oasis, in China’s Hexi Corridor. The contents of elements such as Pb, Cd, Cu, As, Sb, Se, Rb, Cs, and Ba (believed to be of anthropogenic origin) indicated that the significance of human impacts on dust emissions increased from 1970s to the early 2000s. However, variations in the content of elements including Sc, Mn, Na, Cr, V, Eu, Ce, Nb, Zr, La, and Ce (believed to originate from natural processes such as physical and chemical weathering) show no obvious changes in the major potential dust source areas (PSAs) in this region. In addition, analysis of the assemblage of trace elements in dustfall indicated that the elements assumed to originate from anthropogenic and natural processes appear to be intertwined, leading to difficulties and uncertainties in identifying the PSAs and evaluating the significance of human impacts on dust emissions. Comparisons of the element contents of dustfall collected in Beijing and Minqin with similar data for Beijing show that under different conditions some differences in ranges are permitted; the contents of most trace elements were similar even though the dustfall in the two areas came from different sources. These results suggest that before attempting to identify major PSAs, researchers should perform an integrated analysis that includes the mineral, elemental, geomorphological, vegetation cover, climatic conditions, and other characteristics of the regions being studied.     

Thermodynamic properties of solutions in metastable systems under negative or positive pressures

Metastable systems are created when the interface between the atmosphere (in which P_atm = 1 bar) and water forms a spherical meniscus either concave toward the air (water filling capillaries, wherein P_water < P_atm) or convex toward the air (fog water droplet, wherein P_water > P_atm). Soil water, undergoing negative pressure (“capillary potential”) remains bound to the solid matrix (instead of flowing downward) by the capillary meniscus, concave toward the undersaturated dry atmosphere. The positive counterpart of tensile water in soils is the pressurized water contained in fine droplets suspended in oversaturated humid air, as in clouds. All these systems are anisobaric domains the phases of which have different pressures. Geochemical consequences of such characteristics are assessed here by calculating the consequences of the positive or negative water potential on the equilibrium constants of reactions taking place in stretched or pressurized aqueous solutions. Thermodynamic properties of aqueous species are obtained by using the TH model, used explicitly for positive pressures but extrapolated to negative ones for soil solutions. It appears that soil water dissolves gases, offering an alternative explanation of the observed enrichment of atmospheric noble gases in groundwater and of carbonic gas in the unsaturated zone below the root zone. Water droplets obviously show the opposite behavior, that is, a decreasing dissolutive capability with decreasing droplet size (water pressure increases), inducing some climatic consequences. An application of this approach to the solid-solution equilibria is performed by comparing experimental solubility of amorphous silica in unsaturated media on the one hand, to theoretical calculations taking account of the negative water pressure on the other hand. This comparison outlines the potential complexity of anisobaric situations in nature and the necessity to develop a suitable approach for solid pressure.     

Cristallisation fractionnée et contamination crustale dans la série magmatique jurassique transitionnelle du Haut Atlas central (Maroc)Fractional crystallisation and crustal contamination in the transitional Jurassic magmatic series of Central High Atlas (Morocco)

The Middle Jurassic plutonism of the Central High Atlas (Morocco) was emplaced in N45° trending anticlinal ridges. It is characterised by various petrographic facies including mafic rocks (troctolites), intermediate rocks (diorites, monzodiorites), and evolved rocks (syenites), together with heterogeneous facies resulting from mixing between acidic and the intermediate magmas. Mineralogical and chemical data show (i) the transitional character of the Jurassic magmatic series of the Central High Atlas and (ii) the implication of continental crust as a contaminant during fractional crystallization. To cite this article: R. Zayane et al., C. R. Geoscience 334 (2002) 97–104.     

Environmental assessment of heavy metal contamination in bottom sediments of Al-Kharrar lagoon,Rabigh, Red Sea,Saudi Arabia

In order to assess the pollution levels of selected heavy metals, 45 bottom sediment samples were collected from Al-Kharrar lagoon in central western Saudi Arabia. The concentrations of the heavy metals were recorded using inductively coupled plasma-mass spectrometer (ICP-MS). The results showed that the concentrations of Pb and Cd exceeded the environmental background values. However, the heavy metal contents were less than the threshold effect level (TEL) limit. The concentrations of heavy metals in lagoon bottom sediments varied spatially, but their variations showed similar trends. Elevated levels of metals were observed in the northern and southern parts of the lagoon. Evaluation of contamination levels by the sediment quality guidelines (SQG) of the US-EPA revealed that sediments were non-polluted-moderately to heavily polluted with Pb; non-polluted to moderately polluted with Cu; and non-polluted with Mn, Zn, Cd, and Cr. The geoaccumulation index showed that lagoon sediments were unpolluted with Cd, Mn, Fe, Hg, Mo, and Se; unpolluted to moderately polluted with Zn and Co; and moderately polluted with Pb, Cr, Cu, and As. The high enrichment factor values for Pb, As, Cu, Cr, Co, and Zn (>2) indicate their anthropogenic sources, whereas the remaining elements were of natural origins consistent with their low enrichment levels. The values of CF indicate that the bottom sediments of Al-Kharrar lagoon are moderately contaminated with Mn and Pb.     

Source mechanism and parameters of the 19 October 2012 earthquake,northern Egyptian continental margin

The 19 October 2012 earthquake (M _L = 5.1) occurred in the northern continental margin of Egypt within the Nile Cone at latitude 32.35° N and longitude 31.27° E. The quake was felt over a wide area in north Egypt and East Mediterranean countries, but no casualties have been reported. This area had experienced the large earthquake (Ms = 6.7) of 12 September 1955. The fault plane solution of the 19 October 2012 earthquake is here presented based on the digital seismograms recorded by the Egyptian National Seismological Network (ENSN) and other regional seismic stations. The analysis is carried out using the well-known techniques of first motion polarities of P-wave and the amplitude ratios of P-, SH-, and SV-waves with lower hemisphere projection. The fault plane solution based on the first P-wave onset demonstrates a left lateral strike-slip faulting mechanism, while the solution based on both P-wave polarities and amplitude ratios of P-, SH-, and SV-waves reveals a reverse fault with strike-slip component trending NW–SE to NE–SW, in conformity with the N–S compression along the Hellenic Arc convergence zone. Following the Brune’s model, the source dynamic parameters for the 19 October 2012 earthquake are estimated as corner frequency = 1.47 Hz, fault radius = 0.7 km, stress drop = 22.1 MPa, seismic moment = 2.80E + 16 Nm, and moment magnitude M _w = 4.9. These parameters may provide important quantitative information for the seismic hazard assessment studies.     

Group velocity dispersion analysis in northern Peninsular Malaysia

The crustal structure beneath three seismic stations over Malaysia has been investigated with the application of the group velocity dispersion analysis of the northern Sumatra earthquake data which occurred on 06 April 2010. Eighteen crustal layer models are constructed to assess the structure. Group velocity dispersions have been computed for the recorded earthquake data using a graphical method and modified Haskell matrix method for the models. Both dispersions have been presented for the interpretation of crustal layers. Findings have shown four major crustal layers having thicknesses of 2.5–4.0, 2.0–5.5, 5.0–8.0, and 8.5–9.0 km, while in Terengganu, it has shown three layers. Density, shear, and compressional wave velocities used in models have suggested that the crustal structure of the northern part of Peninsular Malaysia is crystalline. Major crustal minerals are of quartz, plagioclase, and mica. Most layers seem to have upward directions toward Perak from Kedah and Terengganu.