Carbon and oxygen isotopes in the Frasnian–Famennian section of the Kuznetsk basin (southern West Siberia)

The first detailed isotope-geochemical study of carbonate deposits has been performed in the Lower Famennian stratotype section of the northwestern Kuznetsk Basin (Kosoy Utyos), which was localized in the middle latitudes of the Northern Hemisphere in the Late Devonian. The δ¹³C_carb, δ¹³C_org, and δ¹⁸O variation curves were constructed for the section deposits. Geochemical and petrographic studies of carbonates allowed allocation of samples that underwent postsedimentation alteration and exclude them from further interpretation. Compared with coeval sections in the other world's regions, the Kosoy Utyos section is characterized by higher δ¹³C_carb values, up to 5.4‰, whereas the maximum value in subequatorial area sections is 4‰. The isotope shift amplitude of the studied section reaches 4.6‰, which is 1.5‰ higher than those in other regions. The δ¹⁸O values are 3‰ lower than the ones of the world's coeval sections. The results obtained show that δ¹³C and δ¹⁸O variation trends differ from those of coeval subequatorial sections. The high shift amplitude and maximum δ¹³C_carb values in the Kosoy Utyos section are due to the shallow-water carbonate sedimentation environments on the Siberian continental shelf and, probably, the lower temperatures of waters in the middle latitudes as compared with the subequatorial areas.     

Isotopically anomalous neon in meteoritic nanodiamonds: Formation during type II supernova explosions

We hypothesize the formation of neon associated with isotopically anomalous xenon (Xe-HL) in meteoritic nanodiamonds and designated as Ne-X through the mixing of the Ne-HL and Ne-S subcomponents. The Ne-HL subcomponent is neon from the helium (He/C) zone of a type II supernova or a mixture of neon from this zone and its hydrogen zone, while the Ne-S subcomponent is spallation neon formed during a supernova explosion in nuclear spallation reactions induced by high-energy protons. Based on this hypothesis and the presumed abundances of neon isotopes in the zones of a high-mass (25M _⊙) supernova after its explosion, we have calculated the abundances of neon components in nanodiamond separates and its grain-size fractions. Our calculations have shown the following. (1) The main source of Ne-HL is neon from the helium zone of the supernova; as a result, the ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios for Ne-X are 0.26 ± 0.03 and 0.19 ± 0.04, respectively. The isotopic composition of Ne-X is identical to that for Ne-A2 if Ne-HL is produced by the mixing of neon from the helium and hydrogen zones in proportion 1: 1.06. (2) In meteoritic nanodiamonds, the main neon abundance is determined by neon of the P3 component (Ne-P3). Ne-P3 is retained during thermal metamorphism, because it is sited in traps of the crystal lattice of diamond with a high energy of its activation. (3) The Ne-X/Ne-P3 ratio increases with nanodiamond grain size; as a result, there is no need to invoke an additional neon component (Ne-P6) to interpret the data on neon in meteoritic nanodiamonds.     

Radio spectra of objects in the RATAN-600 RZF catalog and a population analysis of faint radio sources

Results of centimeter-wavelength RATAN-600 observations of several hundred NVSS objects with a wide range of flux densities are presented. Changes in spectral-index distributions from strong-to faint-object populations are estimated. In the transition from strong to faint radio sources, the number of steep-and ultrasteep-spectrum objects decreases and the minimum between steep-and flat-spectrum objects, which was first discovered in the 1970s, becomes less distinct. A less certain increase in the fraction of inverted-spectrum objects is also found. Comparison with theoretical models of radio-source evolution suggests that the decrease in the number of steep-and ultrasteep-spectrum objects can be naturally explained by a sharp decrease in the fraction of classical FRII radio galaxies. The decrease in the sharpness of the minimum may be due to the growing contribution from the population with spectral indices 0.7–0.5, which is usually identified with starbust galaxies. The small increase in the fraction of inverted-spectrum radio sources can be attributed to the growing number of objects with active nuclei. Our spectrum-based conclusions are confirmed by the morphology of the FIRST Catalog images. The number of radio sources associated with supermassive black holes in the Early Universe is estimated using data from the SDSS Catalog.     

Late Paleozoic Age of Intrusive Rocks from the “Trondhjemite” Massif of the Tyrnyauz W–Mo Deposit (North Caucasus,Russia): The First Results of U–Pb Isotope Dating of Zircon (LA–ICP–MS Method)

Doklady Earth Sciences - The first data of U–Pb isotopic study (LA–ICP–MS method) of zircon from tonalite–granodiorite forming a dominant part of the...     

Formation of Dibenzodioxins and Dibenzofurans in the Photochemical Transformation of Polychlorinated Phenols

It is shown that in the direct photolysis of polychlorinated phenols (2,4,5-TCP, PCP) in aqueous solution, under the action of solar light or UV-radiation from artificial sources, polychlorinated dibenzodioxins (PCDD) and dibenzofurans (PCDF) are found among the products of transformation. A mechanism is suggested of formation of these toxic compounds via the intermediate formation of free radicals. In the oxidation of chlorophenols by singlet oxygen, free radicals are not formed. Addition of fulvic acids prevents formation of PCDD and PCDF in solar light, possibly as a result of trapping of intermediate radicals.     

A detailed study of the rupture zone of the MW 5.8 March 16, 2010 Earthquake at Northwestern Sakhalin Island

An earthquake of magnitude M_W = 5.8 occurred in the upper reaches of the Uanga and Pogibi rivers in northwestern Sakhalin at 9 h 44 min WT on March 16, 2010. The event is the largest for the northwestern part of the island during the entire history of instrumental seismological observations that have been conducted on Sakhalin since 1905. A macroseismic study showed that the earthquake was felt in much of northern Sakhalin and the Amur River area. This paper presents the results from a detailed study of the seismicity in the rupture zone, the space-time distribution of aftershocks, and their relationships to the active fault zones that exist in northern Sakhalin. Some new results were obtained that concern the interrelationships between the focal mechanism and the present-day geodynamic setting.     

The requirements toward the methods of “Clearing” the atmosphere in ground-based radio-astronomical observations of background emissions of the atmosphere

The results of a reduction of the dataset obtained with the RATAN-600 within the framework of the “Cosmological Gene” project are reported. The project was performed in order to estimate the contribution of atmospheric noise in observations of Galactic background radiation. Atmospheric noise prevails on time scales exceeded 10–100 seconds. The efficiency of preselecting the data with low atmospheric noise on the time scales of interest is demonstrated. The potential of the “Cosmological Gene” project for different accumulation times in the sky area studied are assessed with the effect of real atmospheric noise taken into account.     

The “X component” of the radio background

The recent publication of evidence for a new mechanism producing background radio emission of the Galaxy at centimeter wavelengths (in addition to synchrotron radiation, free—free transitions in ionized gas, and the weak radio emission of standard dust) gave rise to a strong reaction among observers, and requires independent experimental verification. This signal is of special concern in connection with studies of the polarization of the cosmic microwave background (CMB) using new-generation experiments. We have derived independent estimates of the validity of the “spinning-dust” hypothesis (dipole emission of macromolecules) using multi-frequency RATAN-600 observations. Test studies in the Perseus molecular cloud show evidence for anomalous extended emission in the absence of strong radio sources (compact HII regions) that could imitate an anomalous radio spectrum in this region. A statistical analysis at centimeter wavelengths over the Ratan Zenith Field shows that the upper limit for the polarized noise from this new component in the spinning-dust hypothesis is unlikely to exceed 1 µK at wavelengths of 1 cm or shorter on the main scales of the EE mode of Sakharov oscillations. Thus, this emission should not hinder studies of this mode, at least to within several percent of the predicted level of polarization of the CMB emission.     

Features and Factors of Hydrological and Morphological Changes in the Agrakhan Bay at the Mouth of the Terek River in the 20th–Early 21st Centuries

Water Resources - The Agrakhan Bay of the Caspian Sea is a unique hydrographic and environmentally valuable object at the mouth of the Terek River. At the beginning of the 20th century, it was a...