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111.
Constant shear drained tests (CSD) are probably the most suitable to simulate the strength and deformation behaviour of soils
in slopes under water infiltration conditions or lateral stress relief. This is significant because soil behaviour following
a CSD stress path could differ from that of traditional compression triaxial tests. In this paper, CSD tests on sand following
an alternative procedure are presented and discussed. The modified CSD tests were conducted by increasing the pore water pressure
at a constant rate from one end of the specimen with water free to drain from the opposite end. Among the results from specimens
consolidated at variable initial void ratios and principal stress ratios it was revealed that specimens showed a tendency
to dilate even for loose sands; failure was reached at low axial strains; and a pre-failure type of instability could be identified.
The modified procedure has the potential to provide new insights into the failure mechanisms of slopes under a water infiltration
condition. 相似文献
112.
François Farges 《Physics and Chemistry of Minerals》2009,36(8):463-481
Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO4 2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses. 相似文献
113.
Ghislain Dubois Benjamin Sovacool Carlo Aall Maria Nilsson Carine Barbier Alina Herrmann Sébastien Bruyère Camilla Andersson Bore Skold Franck Nadaud Florian Dorner Karen Richardsen Moberg Jean Paul Ceron Helen Fischer Dorothee Amelung Marta Baltruszewicz Jeremy Fischer Françoise Benevise Valérie R. Louis Rainer Sauerborn 《Chemie der Erde / Geochemistry》2012
Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy. 相似文献
114.
Yu Zhou Yanxin Wang Yilian Li François Zwahlen Julie Boillat 《Environmental Earth Sciences》2013,68(3):765-778
The central Jianghan Plain is the semi-closed basin in the middle reaches of Yangtze River. A total of 78 water samples targeting groundwater were collected from 75 sites in this study site, the area between Yangtze River and Han River, including rivers and lakes for temperature, pH, electrical conductivity (EC), total dissolved solids (TDS) and ion composition measurements. Correlation matrix was used to assess the geochemical and anthropogenic processes. The most confined groundwater was grouped into HCO3–Ca–Mg, while phreatic groundwater and surface water had a more diversified hydrochemistry. The spatial variation in overall water quality as well as comparison with WHO (World Health Organization) standards for drinking water is illustrated. Mn, As and NO3 ? concentrations were found to exceed the allowable limits for drinking water of WHO guidelines, and they also show remarkable spatial variations. Abnormally high nitrate concentration, up to 150–190 mg/l, was found only in phreatic groundwater, which suggested that the nitrate pollution might be caused by agricultural activities. The present study may be helpful in further studies concerning water quality issues in this area where groundwater is a vital source for drinking and other activities. 相似文献
115.
Bi-weekly water quality data from seven monitoring stations located within Tahtali Watershed, ?zmir, Turkey and digital land use/land cover data of the same watershed are analyzed in this study. To examine the changes in land use associated with urbanization, the satellite images of the main pool of the Tahtali reservoir prior to filling and subsequent to filling, respectively, are analyzed. Aerial photos of the basin taken in 1995 (October) are compared with images taken in 2005 (November) from the IKONOS satellite through use of several GIS techniques. New residential buildings, greenhouses, and industrial buildings are presented in separate layers, and changes in basin activities are quantified. The effects of urbanization on the water quality are investigated through statistical analysis. The seasonal Kendall test is applied to the water quality parameters monitored bi-weekly at seven stations within the basin for the duration 1997–2005. There was no trend in phosphorus, but there was a negative trend in boron and nitrate and a positive trend in the parameters of biological oxygen demand (BOD) and chemical oxygen demand (COD). The improvement in nitrate concentrations is attributed to the new regulations on the use of fertilizers in greenhouses. However, increase of BOD and COD concentrations is related to the growing settlement areas and industrial zones, which point to the insufficient wastewater treatment within the basin. Soil erosion within the basin is also quantified by the universal soil loss equation using available maps. Estimated total soil loss rate increased about 2.5 times that of 1995 when the changed land use composition in 2005 is considered in the calculations. 相似文献
116.
R.?H.?SievwrightEmail authorView authors OrcID profile J.?J.?Wilkinson H.?St.?C.?O’Neill A.?J.?Berry 《Contributions to Mineralogy and Petrology》2017,172(8):62
Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO2) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg2+, Mn2+, Co2+, Ni2+, Zn2+) and Cu2+/Cu+ with increasing fO2 between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO2 implies a reciprocal relationship between a(Fe2+O) and a(Fe3+O1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO2 in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO2 in silicic, but less so in mafic bulk systems. 相似文献
117.
118.
Emmanuel Discamps Jacques Jaubert François Bachellerie 《Quaternary Science Reviews》2011,30(19-20):2755-2775
The evolution in the selection of prey made by past humans, especially the Neandertals and the first anatomically modern humans, has been widely debated. Between Marine Isotope Stages (MIS) 5 and 3, the accuracy of absolute dating is still insufficient to precisely correlate paleoclimatic and archaeological data. It is often difficult, therefore, to estimate to what extent changes in species procurement are correlated with either climate fluctuations or deliberate cultural choices in terms of subsistence behavior. Here, the full development of archeostratigraphy and Bayesian statistical analysis of absolute dates allows the archeological and paleoclimatic chronologies to be compared. The variability in hunted fauna is investigated using multivariate statistical analysis of quantitative faunal lists of 148 assemblages from 39 archeological sequences from MIS 5 through MIS 3. Despite significant intra-technocomplex variability, it is possible to identify major shifts in the human diet during these stages. The integration of archeological data, paleoclimatic proxies and the ecological characteristics of the different species of prey shows that the shifts in large game hunting can be explained by an adaptation of the human groups to climatic fluctuations. However, even if Middle and Early Upper Paleolithic men adapted to changes in their environment and to contrasting landscapes, they ultimately belonged to the ecosystems of the past and were limited by environmental constraints. 相似文献
119.
Fleurice Parat François Holtz Miloš René Renat Almeev 《Contributions to Mineralogy and Petrology》2010,159(3):331-347
The equilibrium phase relations of a mafic durbachite (53 wt.% SiO2) from the Třebíč pluton, representative of the Variscan ultrapotassic magmatism of the Bohemian Massif (338–335 Ma), have
been determined as a function of temperature (900–1,100°C), pressure (100–200 MPa), and H2O activity (1.1–6.1 wt.% H2O in the melt). Two oxygen fugacity ranges were investigated: close to the Ni–NiO (NNO) buffer and 2.6 log unit above NNO
buffer (∆NNO + 2.6). At 1,100°C, olivine is the liquidus phase and co-crystallized with phlogopite and augite at 1,000°C for
the whole range of investigated pressure and water content in the melt. At 900°C, the mineral assemblage consists of augite
and phlogopite, whereas olivine is not stable. The stability field of both alkali feldspar and plagioclase is restricted to
low pressure (100 MPa) at nearly water-saturated conditions (<3–4 wt.% H2O) and T < 900°C. A comparison between experimental products and natural minerals indicates that mafic durbachites have a near-liquidus
assemblage of olivine, augite, Ti-rich phlogopite, apatite and zircon, followed by alkali feldspar and plagioclase, similar
to the mineral assemblage of minette magma. Natural amphibole, diopside and orthopyroxene were not reproduced experimentally
and probably result from sub-solidus reactions, whereas biotite re-equilibrated at low temperature. The crystallization sequence
olivine followed by phlogopite and augite reproduces the sequence inferred in many mica-lamprophyre rocks. The similar fractionation
trends observed for durbachites and minettes indicate that mafic durbachites are probably the plutonic equivalents of minettes
and that K- and Mg-rich magmas in the Bohemian Massif may have been generated from partial melting of a phlogopite–clinopyroxene-bearing
metasomatized peridotite. Experimental melt compositions also suggest that felsic durbachites can be generated by simple fractionation
of a more mafic parent and mixing with mantle-derived components at mid crustal pressures. 相似文献
120.
François Holtz Donald B. Dingwell Harald Behrens 《Contributions to Mineralogy and Petrology》1993,113(4):492-501
The effects of F, B2O3 and P2O5 on the H2O solubility in a haplogranite liquid (36 wt. % SiO2, 39 wt. % NaAlSi3O8, 25 wt. % KAlSi3O8) have been determined at 0.5, 1, 2, and 3 kb and 800, 850, and 900°C. The H2O solubility increases with increasing F and B content of the melt. The H2O solubility increase in more important at high pressure (2 and 3 kb) than at low pressure (0.5 kb). At 2 kb and 800°C, the H2O solubility increases from 5.94 to 8.22 wt. % H2O with increasing F content in the melt from 0 to 4.55 wt. %, corresponding to a linear H2O solubility increase of 0.53 mol H2O/mol F. With addition of 4.35 wt. % B2O3, the H2O solubility increases up to 6.86 wt. % H2O at 2 kb and 800°C, corresponding to a linear increase of 1.05 mol H2O/mol B2O3. The results allow to define the individual effects of fluorine and boron on H2O solubility in haplogranitic melts with compositions close to that of H2O-saturated thermal minima (at 0.5–3 kb). Although P has a dramatic effect on the phase relations in the haplogranite system, its effect on the H2O solubility was found to be negligible in natural melt compositions. The concominant increase in H2O solubility and F can not be interpreted on the basis of the available spectroscopic data (existence of hydrated aluminofluoride complexes or not). In contrast, hydrated borates or more probably boroxol complexes have been demonstrated in B-bearing hydrous melts. 相似文献