Behavior of polycyclic aromatic hydrocarbons at impact shock: Its implication for survival of organic materials delivered to the early Earth

Polycyclic aromatic hydrocarbons (PAHs) with a hydrous or an unhydrous mineral matrix were impacted and analyzed, to study the behavior of PAHs against shock. Results of the shock experiments suggested that volatiles discharged from the hydrous mineral did not influence the behavior of PAHs against shock. The shocked samples contained unreacted starting PAHs, soot-like materials insoluble in dichloromethane, and secondarily formed PAHs with molecular weights ranging from 128 to 404. Approximately 95% of starting PAHs decomposed at ∼30 GPa and the dominant product was the soot-like materials. Formation mechanisms of the shock products were explained by reaction processes under static high pressure-temperature conditions (e.g., carbonization, radical addition reaction, ring cross linking, and methylation).We applied these results to estimate the survival degree of organic matter delivered by carbonaceous asteroids against their impact pressures at the accretion stage of early Earth. If we use a simplified homogeneous accretion model without atmosphere to represent the stage, the radius of Earth causing 30 GPa, the pressure at which PAHs almost decompose, was calculated as 2270 km (4.0 km s⁻¹ of impact velocity) for the impact of carbonaceous asteroids. In the case of impactors striking not land but oceans on the early Earth, the impact velocity for the decomposition of PAHs was estimated to be 6.0 km s⁻¹. These impact velocities should have been commonly realized on the early Earth, due to the airburst and the aerobreak of impactors in the dense atmosphere. The early Earth should have been a favorable environment for obtaining and maintaining a large quantity of prebiotic organic materials leading to life.     

基于全球降水数据估计值的地表径流模拟--以长江上游地区为例

为了评价在相对较短时间内针对长江上游地区地表水径流所建立模型的模拟效果,以及检验以GCM模型和其他卫星数据所估算的降水数据作为输入数据的可行性,选择分布式水文模型HSPF以及1987年和1988年的ISLSCP降水数据作为输入数据。模型模拟结果表明:从整个长江上游地区看,在校正期内,5天平均流量的Nash–Sutcliffe相关系数(R2) 为0.94;在验证期内,Nash-Sutcliffe相关系数(R2) 为0.95。此外,该模型对长江上游主要支流的5天平均流量的模拟效果也很好,R2的值在0.46到0.96之间。例外的情况主要发生在沱江和嘉陵江,模型对2年洪水期的峰值流速的估计值偏低,沱江只有实际值的71%,嘉陵江只有实际值的61%。ISLSCP估计的降水比实际测量的降水频繁且程度要弱,这可能是HSPF不能在所有时间和所有区域都具有较好模拟效果的一个主要原因。     

Disastrous sediment discharge due to typhoon-induced heavy rainfall over fossil periglacial catchments in western Tokachi,Hokkaido, northern Japan

In August 2016, Typhoon 1610 (Lionrock) caused heavy rainfall in Hokkaido, which led to the discharge of a large volume of sediment and water from catchments on the eastern slope of the northern Hidaka Range. The eight catchments examined in this study are characterized by granitic lithology and late Pleistocene periglacial landforms with weakly cohesive, low-resistance periglacial debris thickly covering the weathered bedrocks. This characteristic of the landscape presumably provided a transport-limited condition where some debris flows were initiated by shallow landslides. As they moved, the debris flows grew larger through mobilization and erosion of sediment in channel beds and sidewalls. This sediment mobilization and erosion continued for an extensive distance along the course of the river. Morphological changes induced by channel aggradation and bank erosion were considerable and distinctive from upstream to downstream. Granitic periglacial sediments are amply present on the mountain slopes, river channels, and river banks in the area, likely due to the rarity of intensive rainfall events. These distinctive features of fossil periglacial catchments are important for disaster prevention and catchment-scale sediment management in sub-boreal areas, particularly in the context of climate change, which may generate more frequent and intensive rainfall events.     

Cep A: A possible proto-cluster

We present high resolution CS and CO maps of Cep A region made with the 45m telescope at Nobeyama. The CS map shows that a dense cloud surrounding the proto-star cluster extends in the North-South direction and is probably rotating. The bipolar molecular flow apparent in the CO maps is well-collimated along East-West direction within 0.2 pc from the proto-stars. The dense cloud is gravitationally unstable and appears to be in a contracting phase to form a cluster of massive stars.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.NRO, a branch of the Tokyo Astronomical Observatory, University of Tokyo, is a cosmic radio observing facility open for outside users.     

Theoretical study on the stability of a reservoir created by the intersection of a fluid-filled crack with an oblique joint for the extraction of geothermal heat

On the basis of the two-dimensional theory of elasticity, the theoretical analysis of a vertical, fluid-filled crack intersecting and oblique joint has been made for the extraction of geothermal heat from hot, dry rock masses, where the opening of the joint near a point of intersection and the frictional resistance against slips along the joint are taken into account. The stress intensity factors are evaluated for discussing crack kinking at the upper joint tip, and the sufficient conditions on theinclination of the joint and on the length between the upper joint tip and the point of intersection are obtained for keeping a fluid-filled crack stable just beneath a joint. It is also shown that the volume of the stable reservoir created by using a joint is much larger than that of a fluidfilled crack in a jointless rock mass, even if the joint is oblique and is opened up by the fluid pressure.     

Measuring saturated hydraulic conductivity and anisotropy of peat by a modified split-container method

Long-term changes in the physical and hydraulic properties of peat result from the decomposition and consolidation processes. The saturated hydraulic conductivity (K _s) of peat is depth-dependent and could increase or decrease with depth; therefore, K _s determination on a large number of samples is required to more accurately assess field variability. The cube method is a popular laboratory procedure to determine K _s because it allows use of smaller sample dimensions, while minimizing edge effects. This article describes the design and use of an alternate split container to enclose undisturbed peat cubes during measurement of K _s and the application of this method to a field site in Northwest Territories, Canada. The method allows for simpler and more controlled K _s measurements while also permitting anisotropy measurements. Matched tests on identical samples (K _s range 21–314 m/d), using the split-container and wax methods, showed a good agreement for intermediate K _s values; however, significant deviations occurred for low and high K _s values. Hydraulic-conductivity measurements taken on field samples showed a decrease with depth and exhibited anisotropic hydraulic conductivity as expected based on previous studies.     

Spectral similarity between scalars at very low frequencies in the unstable atmospheric surface layer over the Tibetan plateau

Similarity between temperature and water vapour was investigated in the Fourier domain by using their coherency spectra, defined as the correlation coefficient between their Fourier modes, and the relative efficiency of their vertical transport. The class-averaged values of these indices were computed from the turbulence measurements over sparse grasslands on the Tibetan plateau during the intensive observations of GEWEX (Global Energy and Water Experiment) Asian Monsoon Experiment (GAME). It was found that the energy-containing eddies at scales up to 100z (z being height) are characterised by well-maintained similarity between these scalars. The scalars are highly correlated with each other, and their transport efficiencies are almost equal within this scale range. In contrast, similarity was not always maintained at scales larger than 1000z. Detailed analyses showed that this breakdown of similarity occurs occasionally or sporadically, suggesting that it is caused by events whose average return period is not much smaller than the current averaging time, i.e. 30 min. We speculate that entrainment of drier and warmer air at the top of the atmospheric boundary layer caused the scalar dissimilarity at this scale range.     

Stability of the Courses of the Warm Coastal Currents along the Kyushu Island Suggested by the Population Structure of the Japanese Turban Shell, Turbo (Batillus) Cornutus

The genetic structure of a population of the Japanese turban shell, Turbo (Batillus) cornutus at Sata-Misaki Point, on the southern coast of Kyushu Island, was determined on the basis of nucleotide sequences of mitochondrial DNA and compared with that of a population of the western coast of Kyushu Island. The significant genetic differentiation between these two populations suggests that the courses of the warm currents along the coast of the Kyushu Island have been relatively stable after the divergence between the two genetically distant groups of the Japanese turban shell, which was estimated to have occurred during some period in Pleistocene.     

Genetic Aspects of the Manto-type Copper Deposits Based on Geochemical Studies of North Chilean Deposits

Recent studies on mineralogy, geochronology, fluid inclusion and stable isotope (Pb, Os, S, C, O, Sr) characteristics were reviewed to determine constraints for genetic models of the Chilean manto‐type copper deposits. The Chilean manto‐type deposits are divided into the two geologic categories of the northern areas (Arica–Iquique, Tocopilla–Taltal) and the central areas (Copiapó, La Serena, Santiago). The former is distributed in the coastal range composed of Jurassic andesite‐dominated volcano‐sedimentary piles and younger plutonic intrusions, and yields chalcocite (‐digenite) and bornite as the principal hypogene copper sulfides. The latter is hosted mostly in Lower Cretaceous volcano‐sedimentary sequences, and has chalcopyrite‐rich mineral associations. The fluid inclusion data indicate that the primary copper mineralization was commonly generated in the temperature range 150–360°C under low‐pressure conditions near the boiling curve, mediated with relatively saline brines. Generally, homogeneous Pb and S isotope compositions for primary copper minerals imply direct magma source or leaching of igneous rocks. Pb and Os isotope data published for some deposits, however, suggest that ore‐forming metals were derived mainly from the volcano‐sedimentary host rocks. The noticeably negative isotope ratios of primary sulfide sulfur and hydrothermal calcite carbon of some central area deposits indicate influx of sedimentary rock components, and the high ⁸⁷Sr/⁸⁶Sr initial ratios of hydrothermal calcite from the Tocopilla–Taltal area deposits imply contribution of the contemporaneous seawater or marine carbonates. These isotopic constraints imply a formation mechanism in which the Chilean manto‐type copper deposits formed epigenetically in the process of hydrothermal interaction of non‐magmatic surface‐derived brine with the volcano‐sedimentary host rocks, which is inferred to have been induced by a deep‐seated plutonic complex as the possible heat source.     

Non-intrusive measurements of crater growth

An experimental technique to measure crater growth is presented whereby a high speed video captures profiles of a crater forming after impact obtained using a vertical laser sheet centered on the impact point. Unlike previous so called “quarter-space experiments,” where projectiles were launched along a transparent Plexiglas sheet so that growth of half a crater could be viewed, the use of the laser sheet permits viewing changes in crater shape without any physical interference to the cratering process. This technique indicates that for low velocity impacts (<300 m/s) into 220 μm glass beads that are without cohesion and where the projectile is not disrupted, craters initially grow somewhat proportionally, but that later their depths remain essentially constant while their diameters continue to expand. In addition, these experiments indicate that as the impact velocity increases, the rate of growth and the transient depth to diameter ratio at the end of ejecta excavation decreases. These last two observations are probably due to the large time of penetration of the projectile, which becomes a significant fraction of the time of crater formation. This is contrary to the expectations for the scaling rules, which assumes a point source. Very high curtain angles (>45°) are also seen, and could be due to the low friction angle of the target. Significant crater modification, which is rarely seen in “quarter-space experiments,” is also observed and appears to be controlled by the dynamic angle of repose of the target. These latter observations indicate that differences in target friction angles may need to be considered when determining near rim ejecta-mass distributions and large-scale crater modification processes on the planets.