Changes in diatom, pollen, and chironomid assemblages in response to a recent volcanic event in Lake Galletué (Chilean Andes)

Several lakes in Chile are near important volcanic areas where eruption impacts can limit the quality of lacustrine sediments for reconstructing past environmental changes. In this study, we report changes in diatoms, pollen, and chironomids assemblages after a tephra deposition in Lake Galletué (Chilean Andes). A sediment core obtained from Lake Galletué (40 m water depth) was sliced in 1 cm intervals and subsamples were taken to analyze each proxy. ²¹⁰Pb and ¹³⁷Cs activities were measured to obtain the geochronology and mineralogical analyses were performed to determine the mineral composition of the tephra. Diatom species composition and productivity were modified when the lake received the tephra; Aulacoseira granulata decreased and was later replaced by Cyclotella af. glomerata. After the tephra input, Aulacoseira granulata abundance increased to pre-disturbance levels and Cyclotella af. glomerata decreased. These changes seem to suggest a momentary increase in lake nutrient levels after the tephra deposition. Chironomid assemblages also decreased in head capsules just after the tephra deposition, but the most important change was the replacement of Ablabesmyia by Parakiefferiella, probably due to the sedimentological changes produced by the input of coarse tephra grains. Furthermore, unlike other studies, chironomid assemblages in Lake Galletué did not show a decrease drastically in diversity within the tephra layer. The pollen analysis indicated that, prior to the volcanic event, the vegetal community was dominated by Nothofagus sp., Araucaria araucana, and Blechnum sp.-type. After the tephra deposition, the same taxa are dominant, indicating that the volcanic event seems not produce changes in the vegetation. Nevertheless, within the tephra layer it is possible to see an increase in Poaceae, which represent – due to the percolation process – the effect of eruption on the vegetation. According to our results, diatoms were the most sensitive proxy for describing the changes produced by tephra deposition into the aquatic ecosystem and, despite the noticeable changes in its sedimentological properties; the lake seems to have a high resilience capacity, allowing it to return to pre-tephra input conditions.     

Evolutionary unification in composite active galactic nuclei

In this paper, we present an evolutionary unification scenario, involving supermassive black holes (SMBHs) and starbursts (SBs) with outflow (OF), that seems capable of explaining most of the observational properties (of at least part) of active galactic nuclei (AGN).
The scenario includes a nuclear/circumnuclear SB closely associated with the AGN where the narrow-line region (NLR), broad-line region (BLR) and broad absorption line (BAL) region are produced in part by the OF process with shells and in compact supernova remnants (cSNRs).
The OF process in BAL quasi-stellar objects (QSOs) with extreme infrared (IR) and Fe  ii emission is studied. In addition, the Fe  ii problem regarding the BLR of AGN is analysed. The correlations between the BAL, IR emission, Fe  ii intensity and the intrinsic properties of the AGN are not clearly understood. We suggest here that the behaviour of the BAL, IR and Fe  ii emission in AGN can be understood within an evolutionary and composite model for AGN.
In our model, strong BAL systems and Fe  ii emission are present (and intense) in young IR objects. Parameters like the BALs, IR emission, Fe  ii /Hβ intensity ratio, Fe  ii equivalent width (EW), broad-line width, [O  iii ]λ5007-Å intensity and width, NLR size, X-ray spectral slope in radio quiet (RQ) AGN plus lobe separation, and lobe to core intensity ratio in radio loud (RL) AGN are proposed to be fundamentally time-dependent variables inside time-scales of the order of 10⁸ yr. Orientation/obscuration effects take the role of a second parameter providing the segregation between Seyfert 1/Seyfert 2 galaxies (Sy1/Sy2) and broad-/narrow-line radio galaxies (BLRG/NLRG).     

Water structure at hematite-water interfaces

The atomic-level structure of water at mineral surfaces is an important controlling factor in interfacial reactions such as foreign ion incorporation, crystal growth and dissolution, and redox reactions. Molecular dynamics simulations with four different models based on interatomic potentials have been carried out to determine the atomic-level structure of three hematite-water interfaces. In addition, for each of the three surfaces, different terminations or protonation schemes were considered. The availability of surface X-ray scattering data for the surfaces considered here allowed for an extensive comparison with experimental data. Qualitatively, with the exception of one termination with one model, all models predict the correct arrangement of water molecules at the interface. Quantitatively, the agreement with experimental positions, distances, and layer occupancies is good to excellent, especially given the range of values reported in published experimental studies. Therefore, this study provides further evidence that interatomic potential models can be used to reliably predict the structure of mineral-water interfaces. In addition, molecular simulations are a valuable source of information to complement surface X-ray scattering experiments owing to their ability to directly determine the position of hydrogen atoms and to yield three-dimensional predicted structures at no added cost, as demonstrated in this work. Indeed, the molecular dynamics trajectories were analyzed to determine the surface structural controls on the interfacial water structure. Each of the three surface functional groups present at the surfaces considered in this work, namely, triply-coordinated oxo, doubly-coordinated hydroxo, and singly-coordinated aquo groups, was found to form similar hydrogen bond configurations with adsorbed water molecules at all surfaces. Oxo groups accept long-lasting and linear hydrogen bonds from adsorbed water molecules; hydroxo groups can form hydrogen bonds with other surface functional groups as well as with adsorbed water molecules; and aquo groups normally only donate hydrogen bonds to other surface groups or adsorbed water molecules. Additionally, the majority of adsorbed water molecules were found to adopt multiple configurations and orientations. This information was used to evaluate three-dimensional structural models of the interfaces, which were previously derived experimentally from one-dimensional electron density profiles and steric considerations.     

A fast GIS-based risk assessment for tephra fallout: the example of Cotopaxi volcano, Ecuador-Part II: vulnerability and risk assessment

In order to develop efficient strategies for risk mitigation and emergency management, planners require the assessment of both the expected hazard (frequency and magnitude) and the vulnerability of exposed elements. This paper presents a GIS-based methodology to produce qualitative to semi-qualitative thematic risk assessments for tephra fallout around explosive volcanoes, designed to operate with datasets of variable precision and resolution depending on data availability. Due to the constant increase in population density around volcanoes and to the wide dispersal of tephra from volcanic plumes, a large range of threats, such as roof collapses, damage to crops, blockage of vital lifelines and health problems, concern even remote communities. To address these issues, we have assessed the vulnerability and the risk levels for five themes relevant to tephra fallout: (1) social, (2) economic, (3) environmental, (4) physical and (5) territorial. Risk and vulnerability indices for each theme are averaged to the fourth level of administrative unit (parroquia, parish). In a companion paper, Biass and Bonadonna (this volume) present a probabilistic hazard assessment for tephra fallout at Cotopaxi volcano (Ecuador) using the advection-diffusion model TEPHRA2, which is based on field investigations and a global eruption database (Global Volcanism Program, GVP). The scope of this paper is to present a new approach to risk assessment specifically designed for tephra fallout, based on a comprehensive hazard assessment of Cotopaxi volcano. Our results show that an eruption of moderate magnitude (i.e. VEI 4) would result in the possible collapse of ??9,000 houses in the two parishes located close to the volcano. Our study also reveals a high risk on agriculture, closely linked to the economic sector, and a possible accessibility problem in case of an eruption of any size, as tephra is likely to affect the only major road running from Quito to Latacunga (Panamerican Highway). As a result, this method fits into the ongoing effort to better characterize and evaluate volcanic risk, and more specifically the risk associated with tephra fallout. Although this methodology relies on some assumptions, it can serve as a rapid and efficient starting point for further investigations of the risk level around explosive volcanoes.