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31.
On the practice of estimating fractal dimension 总被引:11,自引:0,他引:11
Coastlines epitomize deterministic fractals and fractal (Hausdorff-Besicovitch) dimensions; a divider [compass] method can be used to calculate fractal dimensions for these features. Noise models are used to develop another notion of fractals, a stochastic one. Spectral and variogram methods are used to estimate fractal dimensions for stochastic fractals. When estimating fractal dimension, the objective of the analysis must be consistent with the method chosen for fractal dimension calculation. Spectal and variogram methods yield fractal dimensions which indicate the similarity of the feature under study to noise (e.g., Brownian noise). A divider measurement method yields a fractal dimension which is a measure of complexity of shape. 相似文献
32.
R. Scott Anderson Renata B. Jass Jaime L. Toney Craig D. Allen Marcey Hess Julianna Fessenden 《Quaternary Research》2008,69(2):263-275
Chihuahueños Bog (2925 m) in the Jemez Mountains of northern New Mexico contains one of the few records of late-glacial and postglacial development of the mixed conifer forest in southwestern North America. The Chihuahueños Bog record extends to over 15,000 cal yr BP. An Artemisia steppe, then an open Picea woodland grew around a small pond until ca. 11,700 cal yr BP when Pinus ponderosa became established. C/N ratios, δ13C and δ15N values indicate both terrestrial and aquatic organic matter was incorporated into the sediment. Higher percentages of aquatic algae and elevated C/N ratios indicate higher lake levels at the opening of the Holocene, but a wetland developed subsequently as climate warmed. From ca. 8500 to 6400 cal yr BP the pond desiccated in what must have been the driest period of the Holocene there. C/N ratios declined to their lowest Holocene levels, indicating intense decomposition in the sediment. Wetter conditions returned after 6400 cal yr BP, with conversion of the site to a sedge bog as groundwater levels rose. Higher charcoal influx rates after 6400 cal yr BP probably result from greater biomass production rates. Only minor shifts in the overstory species occurred during the Holocene, suggesting that mixed conifer forest dominated throughout the record. 相似文献
33.
SHRIMP zircon dating and Sm/Nd isotopic investigations of Neoproterozoic granitoids, Eastern Desert, Egypt 总被引:2,自引:0,他引:2
Ewais M.M. Moussa Robert J. Stern William I. Manton Kamal A. Ali 《Precambrian Research》2008,160(3-4):341-356
There is an increasing evidence for the involvement of pre-Neoproterozoic zircons in the Arabian–Nubian Shield, a Neoproterozoic crustal tract that is generally regarded to be juvenile. The source and significance of these xenocrystic zircons are not clear. In an effort to better understand this problem, older and younger granitoids from the Egyptian basement complex were analyzed for chemical composition, SHRIMP U–Pb zircon ages, and Sm–Nd isotopic compositions. Geochemically, the older granitoids are metaluminous and exhibit characteristics of I-type granites and most likely formed in a convergent margin (arc) tectonic environment. On the other hand, the younger granites are peraluminous and exhibit the characteristics of A-type granites; these are post-collisional granites. The U–Pb SHRIMP dating of zircons revealed the ages of magmatic crystallization as well as the presence of slightly older, presumably inherited zircon grains. The age determined for the older granodiorite is 652.5 ± 2.6 Ma, whereas the younger granitoids are 595–605 Ma. Xenocrystic zircons are found in most of the younger granitoid samples; the xenocrystic grains are all Neoproterozoic, but fall into three age ranges that correspond to the ages of other Eastern Desert igneous rocks, viz. 710–690, 675–650 and 635–610 Ma. The analyzed granitoids have (+3.8 to +6.5) and crystallization ages, which confirm previous indications that the Arabian–Nubian Shield is juvenile Neoproterozoic crust. These results nevertheless indicate that older Neoproterozoic crust contributed to the formation of especially the younger granite magmas. 相似文献
34.
Quick-look assessments to identify optimal CO2 EOR storage sites 总被引:1,自引:0,他引:1
Vanessa Núñez-López Mark H. Holtz Derek J. Wood William A. Ambrose Susan D. Hovorka 《Environmental Geology》2008,54(8):1695-1706
A newly developed, multistage quick-look methodology allows for the efficient screening of an unmanageably large number of
reservoirs to generate a workable set of sites that closely match the requirements for optimal CO2 enhanced oil recovery (EOR) storage. The objective of the study is to quickly identify miscible CO2 EOR candidates in areas that contain thousands of reservoirs and to estimate additional oil recovery and sequestration capacities
of selected top options through dimensionless modeling and reservoir characterization. Quick-look assessments indicate that
the CO2 EOR resource potential along the US Gulf Coast is 4.7 billion barrels, and CO2 sequestration capacity is 2.6 billion metric tons. In the first stage, oil reservoirs are screened and ranked in terms of
technical and practical feasibility for miscible CO2 EOR. The second stage provides quick estimates of CO2 EOR potential and sequestration capacities. In the third stage, a dimensionless group model is applied to a selected set
of sites to improve the estimates of oil recovery and storage potential using appropriate inputs for rock and fluid properties,
disregarding reservoir architecture and sweep design. The fourth stage validates and refines the results by simulating flow
in a model that describes the internal architecture and fluid distribution in the reservoir. The stated approach both saves
time and allows more resources to be applied to the best candidate sites. 相似文献
35.
Li-Sr-Nd isotope signatures of the plume and cratonic lithospheric mantle beneath the margin of the rifted Tanzanian craton (Labait) 总被引:3,自引:2,他引:1
Sonja Aulbach Roberta L. Rudnick William F. McDonough 《Contributions to Mineralogy and Petrology》2008,155(1):79-92
Lithium concentrations and isotopic compositions of olivine and 87Sr/86Sr and 143Nd/144Nd of coexisting clinopyroxene from peridotite xenoliths from the Quaternary Labait volcano, Tanzania, document the influence
of rift-related metasomatism on the ancient cratonic mantle. Olivines show negative correlations between Fo content and both
δ7Li and Li concentrations. Olivines in iron-rich peridotites (Fo85–87) have high Li concentrations (3.2–4.8 ppm) and heavy δ7Li (+5.2 to +6.6). In contrast, olivines in ancient, refractory peridotites have lower Li concentrations (∼2 ppm) and relatively
light δ7Li (+2.6 to +3.5). This reflects mixing between ancient, refractory cratonic lithosphere and asthenosphere-derived rift magmas.
A uniquely fertile, deformed, high-temperature garnet lherzolite, interpreted to be from the base of the lithosphere, has
a 87Sr/86Sr of 0.7029 and 143Nd/144Nd of 0.51286, similar to HIMU oceanic basalts. It provides the best estimate of the Sr–Nd isotope composition of the upwelling
mantle (i.e., plume, sensu lato) underlying this portion of the East African Rift, and is slightly less radiogenic compared
to previous estimates of the plume that were based on rift basalts. Although elevated δ7Li are not exclusive to HIMU source regions, the data collectively indicate that the plume beneath Labait has HIMU characteristics
in Sr, Nd and Li isotope composition.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
36.
Imad A.M. Ahmed Neil M.J. Crout Scott D. Young 《Geochimica et cosmochimica acta》2008,72(6):1498-1512
Time-dependent sorption and desorption of Cd on calcite was studied over 210 days utilizing 109Cd as a tracer to distinguish between ‘labile’ and ‘non-labile’ forms of sorbed Cd. Stabilizing the calcite suspensions for 12 months under atmospheric PCO2 and controlled temperature was necessary to reliably follow Cd dynamics following initial sorption. Results revealed time-dependant Cd sorption and marked desorption hysteresis by calcite under environmentally relevant conditions. Data obtained were fitted to a first-order kinetic model and a concentric shell diffusion model. Both models described the progressive transfer of Cd2+ to a less reactive form within calcite and subsequent desorption of Cd subject to different initial contact times. The kinetic model provided a better fit to the combined sorption and desorption data (R2 = 0.992). It differentiates between two ‘pools’ of sorbed Cd2+ on calcite, ‘labile’ and ‘non-labile’, in which labile sorbed Cd is in immediate equilibrium with the free Cd2+ ion activity in solution whereas non-labile Cd is kinetically restricted. For the diffusion model (R2 = 0.959), the rate constants describing Cd dynamics in calcite produced a half-life for Cd desorption of ∼175 d, for release to a ‘zero-sink’ solution. Results from this study allow comment on the likely mechanisms occurring at the calcite surface following long-term Cd sorption. 相似文献
37.
The current study provides an investigation of abiotic reduction of an oversaturated uranyl solution driven by iron nanoparticle oxidation. The reactivity of nano-scale zero-valent iron (ZVI) under mildly oxic conditions (1.2% O2 and 0.0017% CO2) was studied in 1000 ppm uranyl solution in the pH range 3-7, at reaction times from 10 min to 4 h. Reductive precipitation of UO2 was observed as the main process responsible for the removal of uranium from solution with the kinetics of reaction becoming increasingly favourable at higher pH. Despite working with an oversaturated uranium solution, the precipitation of UO2 occurred in preference to precipitation of UO3·2H2O (metaschoepite) at reaction times between 1 and 4 h and for uranyl solutions initially set up at pH ?5. Characterisation of both solid and solution phases was performed using X-ray photoelectron spectroscopy (XPS), focused ion beam (FIB) imaging, X-ray diffraction (XRD) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). 相似文献
38.
Exurbia from the bottom-up: Confronting empirical challenges to characterizing a complex system 总被引:2,自引:0,他引:2
Daniel G. Brown Derek T. Robinson Li An Moira Zellner William Rand Rick Riolo Bobbi Low 《Geoforum》2008,39(2):805-818
We describe empirical results from a multi-disciplinary project that support modeling complex processes of land-use and land-cover change in exurban parts of Southeastern Michigan. Based on two different conceptual models, one describing the evolution of urban form as a consequence of residential preferences and the other describing land-cover changes in an exurban township as a consequence of residential preferences, local policies, and a diversity of development types, we describe a variety of empirical data collected to support the mechanisms that we encoded in computational agent-based models. We used multiple methods, including social surveys, remote sensing, and statistical analysis of spatial data, to collect data that could be used to validate the structure of our models, calibrate their specific parameters, and evaluate their output. The data were used to investigate this system in the context of several themes from complexity science, including have (a) macro-level patterns; (b) autonomous decision making entities (i.e., agents); (c) heterogeneity among those entities; (d) social and spatial interactions that operate across multiple scales and (e) nonlinear feedback mechanisms. The results point to the importance of collecting data on agents and their interactions when producing agent-based models, the general validity of our conceptual models, and some changes that we needed to make to these models following data analysis. The calibrated models have been and are being used to evaluate landscape dynamics and the effects of various policy interventions on urban land-cover patterns. 相似文献
39.
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