The last British Ice Sheet: growth, maximum extent and deglaciation

The growth, maximum lateral extent and deglaciation of the last British Ice Sheet (BIS) has been reconstructed using sediment, faunal and stable isotope methods from a sedimentary record recovered from the Barra Fan, north-west Scotland. During a phase of ice sheet expansion postdating the early "warmth" of Marine Isotope Stage 3 (MIS 3), ice rafting events, operating with a cyclicity of approximately 1500 years, are interspersed between warm, carbonate-rich interstadials operating with a strong Dansgaard-Oeschger (D-O) cyclicity. The data suggest that the BIS expanded westwards to the outer continental shelf break shortly after 30 Ky BP (before present) and remained there until about 15 Ky BP. Within MIS 2, as the ice sheet grew to its maximum extent, the pronounced periodicities which characterize MIS 3 are lost from the record. The exact timing of the Last Glacial Maximum is difficult to define in this record; but maxima in Neogloboquadrina pachyderma (sinistral) ع⁸O are observed between 21-17 Ky BP. A massive discharge of ice-rafted detritus, coincident with Heinrich event 1, is observed at about 16 Ky BP. Deglaciation of the margin is complete by about 15 Ky BP and surface waters warm rapidly after this date.     

Electronic environments in carrollite, CuCo2S4, determined by soft X-ray photoelectron and absorption spectroscopy

Fracture surfaces of a natural carrollite specimen have been characterised by synchrotron and conventional X-ray photoelectron spectroscopy and near-edge X-ray absorption spectroscopy. For the synchrotron X-ray measurements, the mineral surfaces were prepared under clean ultra high vacuum and were unoxidised. The characterisation was undertaken primarily to establish unequivocally the oxidation state of the Cu in the mineral, but also to obtain information on the electronic environments of the Co and S, and on the surface species. Experimental and simulated Cu L_2,3-edge absorption spectra confirmed an oxidation state of Cu^I, while Co 2p photoelectron and Co L_2,3 absorption spectra were largely consistent with the Co^III established previously by nuclear magnetic resonance spectroscopy. S 2p photoelectron spectra provided no evidence for S to be present in the bulk in more than one state, and were consistent with an oxidation state slightly less negative than S^-II. Therefore it was concluded that carrollite can be best represented by Cu^ICo^III₂(S₄)^-VII. The Cu^I oxidation state is in agreement with that expected for Cu tetrahedrally coordinated by S, but is in disagreement with the Cu^II deduced previously from some magnetic, magnetic resonance and Cu L-edge X-ray absorption spectroscopic measurements. A significant concentration of S species with core electron binding energies both lower and higher than the bulk value were formed at fracture surfaces, and these entities were assigned to monomeric and oligomeric surface S species. The density of Cu d states calculated for carrollite differed from that previously reported but was consistent with the observed Cu L₃ X-ray absorption spectrum. The initial oxidation of carrollite in air under ambient conditions was confirmed to be congruent, unlike the incongruent reaction undergone by a number of non-thiospinel sulfide minerals.     

Sediment deposition from flow at low gradients into a buffer strip—a critical test of re-entrainment theory

The spatial and size distribution of sediment deposited from short periods of overland flow due to the effect of a simulated grass buffer strip was measured for low slopes of 1.6, 3.4 and 5.1%. These data were analysed so as to critically evaluate two alternative models of the process of re-entrainment of recently deposited sediment. A model of re-entrainment, previously thought to be appropriate only for a steady-state or equilibrium situation, was found to give better agreement with experiments than did a model previously used in the literature on this subject.     

On the interannual variability of arctic sea‐level pressure and sea ice

Abstract

Monthly mean sea‐level pressure (SLP) data from the Northern Hemisphere for the period January 1952‐December 1987 are analysed. Fluctuations in this field over the Arctic on interannual time‐scales and their statistical association with fluctuations farther south are determined. The standard deviation of the interannual variability is largest compared with that of the annual cycle along the seaboards of the major land masses. The SLP anomalies are generally in phase over the entire Arctic Basin and extend south over the northern Russia and Canada, but tend to be out of phase with fluctuations at mid‐latitudes. The anomalies are most closely associated with fluctuations over the North Atlantic and Europe except near the Chukchi Sea to the north of Bering Strait. The associations with the North Pacific fluctuations become increasingly more prominent at most Arctic sites (e.g. the Canadian Arctic Archipelago) as the time‐scale increases.

Associations between the SLP fluctuations and atmospheric indices that represent processes affecting sea‐ice drift (wind stress and wind stress curl) are determined. In every case local associations dominate, but some remote ones are also evident. For example, changes in the magnitude of the wind stress curl over the Beaufort Sea are increased if the atmospheric circulation over the North Pacific is intensified; wind stress over the region where sea ice is exchanged between the Beaufort Gyre and the Transpolar Drift Stream is modulated by both the Southern and North Atlantic Oscillations.

Severe sea‐ice conditions in the Greenland Sea (as measured by the Koch Ice Index) coincide with a weakened atmospheric circulation over the North Atlantic.     

Passive seismic control of cable-stayed bridges with damped resonant appendages

A study is conducted to investigate the effectiveness of attaching to cable-stayed bridges resonant appendages with a relatively small mass and a high damping ratio as a means to reduce their response to earthquake excitations. The study is based on a previously developed formulation that shows that the use of these appendages may increase the inherent damping of building structures and, as a result, may reduce their response to seismic disturbances. It includes numerical and experimental tests that are conducted to assess the validity of such a formulation for the case of cable-stayed bridges and the extent to which such appendages can reduce their seismic response. In the numerical study, an actual cable-stayed bridge is modelled with finite elements and analysed with and without the proposed appendages under different earthquake ground motions. Appendages with damping ratios of 10, 15, 20 and 30 per cent and masses that, respectively, represent 0.67, 1.5, 2.7 and 6.0 per cent of the total mass of the bridge are considered. In the experimental test, a 3.7 m long cable-stayed bridge and an appendage consisting of a small mass, a small spring and a small viscous damper are built and the bridge tested, without and with the appendage, on a pair of shaking tables which are set to reproduce ground acceleration records from past earthquakes. The damping ratio of the appendage in this test is 32 per cent and its mass represents about 8 per cent of the total mass of the bridge model. In the numerical test, it is found that the appendages reduce the longitudinal response of the bridge deck up to 88 per cent. Similarly, in the experimental test it is found that the appendage reduces the longitudinal bridge deck response by about 41 per cent. From these studies, it is concluded that the suggested appendages may indeed be effective in reducing the seismic response of cable-stayed bridges as they are for building structures.     

The Influence of Storms on Water Quality and Phytoplankton Dynamics in the Tidal James River

Due to the unpredictable nature of intense storms and logistical constraints of sampling during storms, little is known about their immediate and long-term impacts on water quality in adjacent aquatic ecosystems. By combining targeted experiments with routine monitoring, we evaluated immediate impacts of two successive storm events on water quality and phytoplankton community response in the tidal James River and compared these findings to a non-storm year. The James River is a subestuary of the Chesapeake Bay and sampling was conducted before, during, and after Hurricane Irene and Tropical Storm (TS) Lee in 2011 and during the same time period (late summer/early fall) in 2012 when there were no storms. We collected and compiled data on nutrient and chlorophyll a concentrations, phytoplankton abundance, nitrogen uptake, primary productivity rates, and surface salinity, temperature, and turbidity in the meso- and polyhaline segments of the James River. Hurricane Irene introduced significant amounts of freshwater over the entire James River and Chesapeake Bay watersheds, while rainfall from TS Lee fell primarily on the tidal fresh region of the James River and headwaters of the Chesapeake Bay. Dinoflagellates dominated the algal community in the meso- and polyhaline segments prior to the storms in 2011, and a mixed diatom community emerged after the storms. In the mesohaline river segment, cyanobacteria abundance increased after TS Lee when salinities were depressed, likely due to washout from the oligohaline and tidal fresh regions of the river. In 2012, dinoflagellates dominated the community in both segments of the river during late summer but diatoms were also abundant and their biomass fluctuated throughout the summer and fall. Cyanobacteria were not present in either segment. Overall, we observed that the high-intensity rainfall from Hurricane Irene combined with high flushing in the headwaters as a result of TS Lee likely reduced primary productivity and altered community composition in the mesohaline segment but not the more estuarine-influenced polyhaline segment. Understanding the influence of high freshwater flow with a short residence time associated with storms is key to the planning and management of estuarine restoration as such disturbances are projected to increase as a result of climate change.     

Initial results and progress of the Mississippi delta sediment pore water pressure experiment

Abstract

This report describes the instrumentation, initial results, and progress of an experiment designed to measure and monitor submarine sediment pore water and hydrostatic pressures in a selected area of the Mississippi Delta. The experiment also is intended to monitor significant pressure perturbations during active storm periods. Initial analysis of the data revealed excess pore water pressures in the silty clay sediment at selected depths below the mudline. Continuous monitoring of the pore water and hydrostatic pressures was expected to reveal important information regarding sediment pore water pressure variations as a function of the geological processes active in the Mississippi Delta.     

Exurbia from the bottom-up: Confronting empirical challenges to characterizing a complex system

We describe empirical results from a multi-disciplinary project that support modeling complex processes of land-use and land-cover change in exurban parts of Southeastern Michigan. Based on two different conceptual models, one describing the evolution of urban form as a consequence of residential preferences and the other describing land-cover changes in an exurban township as a consequence of residential preferences, local policies, and a diversity of development types, we describe a variety of empirical data collected to support the mechanisms that we encoded in computational agent-based models. We used multiple methods, including social surveys, remote sensing, and statistical analysis of spatial data, to collect data that could be used to validate the structure of our models, calibrate their specific parameters, and evaluate their output. The data were used to investigate this system in the context of several themes from complexity science, including have (a) macro-level patterns; (b) autonomous decision making entities (i.e., agents); (c) heterogeneity among those entities; (d) social and spatial interactions that operate across multiple scales and (e) nonlinear feedback mechanisms. The results point to the importance of collecting data on agents and their interactions when producing agent-based models, the general validity of our conceptual models, and some changes that we needed to make to these models following data analysis. The calibrated models have been and are being used to evaluate landscape dynamics and the effects of various policy interventions on urban land-cover patterns.