Chemical denudation rates in Kärkevagge, Swedish Lapland

This study examines the spatial and temporal variability of chemical denudation rates in Kärkevagge, northern Sweden. The chemical flux rates within the valley are strongly influenced by the local geology. Chemical denudation rates determined for the study period are more than double those previously reported in the literature for this valley. Rates of greater than 46t km⁻² a⁻¹ were measured at the valley mouth over the course of the melt season. This difference is likely due to differences in measurement technique compared to that used by past researchers. This rate is also much higher than for other arctic and alpine watersheds. Chemical denudation in Kärkevagge is comparable to larger temperate rivers. The rapid chemical denudation in Kärkevagge is likely due to sulfide weathering creating acid solutions.     

An expanded surface-water palaeotemperature inference model for use with fossil midges from eastern Canada

Using an expanded surface sample data set, representing lakes distributed across a transect from southernmost Canada to the Canadian High Arctic, a revised midge-palaeotemperature inference model was developed for eastern Canada. Modelling trials with weighted averaging (with classical and inverse deshrinking; with and without tolerance downweighting) and weighted averaging partial least squares (WA-PLS) regression, with and without square-root transformation of the species data, were used to identify the best model. Comparison of measured and predicted temperatures revealed that a 2 component WA-PLS model for square-root transformed percentage species data provided the model with the highest explained variance (r =0.88) and the lowest error estimate (RMSEP _jack =2.26 °C). Comparison of temperature inferences based on the new and old models indicates that the original model may have seriously under-estimated the magnitude of late-glacial temperature oscillations in Atlantic Canada. The new inferences suggest that summer surface water temperatures in Splan Pond, New Brunswick were approximately 10 to 12 °C immediately following deglaciation and during the Younger Dryas. During the Allerod and early Holocene, surface water temperatures of 20 to 24 °C were attained. The new model thus provides the basis for more accurate palaeotemperature reconstructions throughout easternmost Canada.     

Anomalous luminescence of subglacial sediment at Haut Glacier d'Arolla,Switzerland – a consequence of resetting at the glacier bed?

Swift, D. A., Sanderson, D. C. W., Nienow, P. W., Bingham, R. G. & Cochrane, I. C. 2010: Anomalous luminescence of subglacial sediment at Haut Glacier d'Arolla, Switzerland – a consequence of resetting at the glacier bed? Boreas, Vol. 40, pp. 446–458. 10.1111/j.1502‐3885.2010.00196.x. ISSN 0300‐9483. Luminescence has the potential to elucidate glacial geomorphic processes because primary glacial sediment sources and transport pathways are associated with contrasting degrees of exposure to light. Most notably, sediment entrained from extraglacial sources should be at least partially reset, whereas sediment produced by glacial erosion of subglacial bedrock should retain substantial luminescence commensurate with a geological irradiation history. We set out to test the validity of this assumption at Haut Glacier d'Arolla, Switzerland using sediment sampled extraglacially and from the glacier bed. Contrary to our expectations, the subglacial samples exhibited natural signals that were substantially lower than those of other sample groups, and further (albeit limited) analyses have indicated no obvious differences in sample‐group luminescence characteristics or behaviour that could account for this observation. For glaciological reasons, we can eliminate the possibilities that the subglacial sediment has been extraglacially reset or exposed in situ to heat or light. We therefore advocate investigation of possible resetting processes related to subglacial crushing and grinding, and speculate that such processes, if more generally present, may enable the dating of subglacially deposited tills using luminescence‐based techniques.     

Performance of seismically loaded shearwalls on nonlinear shallow foundations

If utilized, the energy dissipative capability of seismically loaded shallow foundations due to inelastic behavior can result in more economic design, provided the consequences, such as excessive deformations are accounted for. In this article, a Beam‐on‐Nonlinear‐Winkler‐Foundation (BNWF) model is used to assess the performance of shearwall‐foundation systems with different attributes, when subjected to ground motions of varied hazard levels. The numerical study indicates that the force and drift demands to the shearwall reduce significantly, when nonlinear foundation behavior is realized, while permanent settlement is well below the permissible limit. These results support the concept of shallow foundation capacity mobilization in future design. Copyright © 2010 John Wiley & Sons, Ltd.     

Space-time interaction amongst clusters of mining induced seismicity

Elementary cluster analysis of induced seismicity in a South African gold mine has shown that there is a clear interaction amongst the clusters; and that the level of the interaction is a function of the distance. The clusering algorithm used is an adaptation of the single-link cluster analysis which considers both three-dimensional space and time. A high level of interaction between the clusters is demonstrated from the cross-correlation analysis of seismic activity rates and radiated energy. A distinct decrease in the value of correlation coefficients was detectable as distance increased. This was somewhat surprising, considering the simplicity of the technique used. Since no attempt is made to study the physical mechanisms of interaction, these results are very preliminary, but interesting from an observational point of view.     

The use of acidimetric titration as a novel approach to study particulate trace metal speciation and mobility: Application to sediments of the Scheldt estuary

The study of trace metal speciation has benefited from a great deal of interest leading to the development and the diversification of sequential extraction schemes (SES), which triggered the need for harmonization by the standard, measurements and testing programme (SM & T). However, some uncertainties still persist in the application of the harmonized 3-step protocol, because of the difficulty in conceptualizing a technique that can be applied to environmental samples irrespective of their nature. The alternative method proposed in this study is based on the solubility of the sample components progressively dissolved during the course of an acidimetric titration by 1 mol L⁻¹ HCl. The major HCl-reactive mineralogical components are identified using mass balance calculation of H⁺ consumed by their dissolution together with the amount of major elements released into solution. The speciation of minor and trace elements is investigated by comparing their titrations to those of the major elements. This approach is much simpler than SES because it uses simple non-selective H⁺ at room temperature instead of a complex experimental design of so-called specific reagents. The different mineral components of the solid are no longer operationally defined and the problem of selectivity is irrelevant to the titration approach. The method was applied to several sediment samples from the Scheldt estuary and the particulate phase was further examined by Scanning Electron Microprobe and X-ray Diffraction techniques. The nearly complete consumption of H⁺ in the suspension is balanced by the total dissolution of carbonates and Fe-oxyhydroxides. In contrast to the speciation inferred from the Tessier SES, the acidimetric titration has demonstrated that the carbonate phase does not significantly contain trace metals with the exceptions of 40% of the Mn and 30% of the Co. In contrast, the Fe-oxyhydroxides seem to play a major role and account for 70% of Pb and 20% of Cr, in addition to 60% of P and additional amounts of 20% Co and 40% Mn. 70% of the Cu also occur in the oxyhydroxide phase, more likely coprecipitated with gibbsite. 90% of the Cd and 85% of Zn can be attributed to the Acid Volatile Sulfide (AVS) phase as evidenced from S titration. The acidimetric titration method not only provides information on the speciation of trace metals but also allows the quantification of their reactivity and mobility, if one considers that the titration roughly mimics pH changes that may occur as a result of chemical disequilibrium in the environment. The results demonstrate the potential of the acidimetric titration as an alternative to SES protocols in geochemical and environmental regulation studies. This method is applicable to a wide variety of environmental materials with little or minor adjustments.