Thermodynamics of the xanthoconite-proustite and pyrostilpnite-pyrargyrite phase transition as determined by abrasive stripping voltammetry

The electrochemical reduction of xanthoconite, proustite, pyrostilpnite, and pyrargyrite was studied by abrasive stripping voltammetry, a technique which is based upon a preliminary mechanical transfer of trace amounts of the mineral onto the surface of a paraffin impregnated graphite electrode. Because the electrochemical reduction proceeds near to reversibility and is very similar for each pair of minerals, the peak potentials in differential pulse voltammetry can be used to calculate the standard enthalpy of phase transformation of xanthoconite to proustite and of pyrostilpnite to pyrargyrite: _T H _{(xanth proust)} ^O = 35.46 ± 14.15 kJ/mol and _T H _{(pyrostilp pyrarg)} ^O = 38.85 ± 6.60 kJ/mol. These values are not accessible otherwise until now.     

Modelling stalagmite growth and δC as a function of drip interval and temperature

Growth and stable isotope composition of stalagmites are affected by climate changes. To understand the underlying mechanisms, we developed a time dependent multi-box model that describes stalagmite growth and stable isotope fractionation of carbon under disequilibrium conditions. The model takes variations of the drip interval, temperature and the amount of mixing between the impinging drops and the solution on top of the stalagmite into account, which allows to quantify the influence of these parameters. To calculate the variations of δ¹³C, the multi-box model was calibrated by comparison with an existing growth model. The results show that drip interval, temperature and the mixing coefficient do have a significant influence on δ¹³C. However, considering the higher natural variability of the drip interval, this parameter might have the largest influence.     

The POETICs of industrial carbon dioxide emissions in Japan: an urban and institutional extension of the IPAT identity

Background  

This study applies the POETICs framework (population, organization, environment, technology, institutions and culture) to an analysis of industrial carbon dioxide emissions in Japanese cities. The inclusion of institutional variables in the form of International Council for Local Environmental Initiatives membership, ISO 14001 implementation, and non-profit sector activity addresses the ecological limitations of the often used IPAT (impact = population × affluence × technology) approach.     

Estimating the uncertainty of coral isochron U–Th ages

Recently, alternative models to estimate the age of diagenetically altered fossil reef corals have been presented based on either redistribution of U or its immediate daughters ²³⁴Th and ²³⁰Th. Here, we present three methods to estimate the uncertainty of ages derived using an amended version of our coral isochron method [Scholz et al., 2004. U-series dating of diagenetically altered fossil reef corals. Earth and Planetary Science Letters 218, 163–178], which is based on addition/loss of U. The obtained uncertainties are substantially larger than those previously published and should, in general, be more reliable. The isochron method yields larger uncertainties than alternative models based on Th redistribution due to -recoil processes. However, comparison of model open-system ages based on such redistribution of U-series daughters for different sub-samples from an individual coral specimen shows that the smaller errors derived with these models cannot account for the observed variability. We recognise that none of the available models is applicable to all corals, probably reflecting different diagenetic processes even in different sub-samples from one coral specimen. To better understand the diagenetic processes and precisely constrain the uncertainties of the ages derived from diagenetically altered corals, the application of all available models is recommended.     

The formation of biogeochemical laminations in Lake Bosumtwi, Ghana, and their usefulness as indicators of past environmental changes

The sediments from Lake Bosumtwi, Ghana contain a unique record of fine-scale (mm to sub-mm) laminations, which will provide a valuable annual chronometer for reconstructing paleoenvironmental changes in West Africa covering much of the last 1 Ma. Comparisons of laminae counts to independent ²¹⁰Pb dates and the rise in anthropogenic “bomb” radiocarbon support the interpretation of the laminations in the uppermost sediments as registering annual events. Radiocarbon dates on in-situ fish-bone collagen are in agreement with varve counts, further supporting the annual nature of our varve chronology. Over the instrumental period (1925–1999), dark-varve thickness measurements are correlated with local rainfall (r = 0.54) and appear able to resolve decadal-scale changes in precipitation. The relationship between varve thickness and rainfall provides support for our interpretation that dark-colored varve thickness records catchment runoff during the rainy season rather than dust flux during the dry season. Dark laminae alternate with organic and carbonate-rich light laminae formed during the fall period of enhanced productivity. Downcore, varves undergo significant microstratigraphic and geochemical variations, but retain the same pattern of alternating clastic and organic-rich laminae, providing support that the laminae may represent annual time markers for reconstructions of the deeper part of the record.     

Demographic and environmental conditions are uncoupled in the social–ecological system of the Pribilof Islands

Since the end of the commercial fur seal hunt in 1984, the economy of the Pribilof Islands, Alaska, has lacked a stable, lasting basis. As a contribution to the effort to understand and promote the effective management of the Pribilof Islands as a social–ecological system, we examined current and recent conditions on the islands to assess local perceptions of, and prospects for, economic, social and environmental well-being. We found few correlations between environmental conditions and socio-economic indicators. The lack of apparent connection between population levels and economic or environmental stimuli is likely attributable to one or more of several factors: (a) modest economic dependence on the environment; (b) predominance of other economic inputs to the economies of the islands; (c) islanders basing residence choices largely on non-economic factors; and (d) the islanders' tolerance for economic fluctuations and uncertainty. These results suggest economic analysis alone is insufficient to explain the dynamics of this social–ecological system, contrary to many other case studies and an expectation of tight coupling and clear connections between society and ecology in the Pribilofs.     

Stratigraphic and structural evolution of the Selenga Delta Accommodation Zone, Lake Baikal Rift, Siberia

Seismic reflection profiles from the Lake Baikal Rift reveal extensive details about the sediment thickness, structural geometry and history of extensional deformation and syn-rift sedimentation in this classic continental rift. The Selenga River is the largest single source of terrigenous input into Lake Baikal, and its large delta sits astride the major accommodation zone between the Central and South basins of the lake. Incorporating one of the world's largest lacustrine deltas, this depositional system is a classic example of the influence of rift basin structural segmentation on a major continental drainage. More than 3700 km of deep basin-scale multi-channel seismic reflection (MCS) data were acquired during the 1989 Russian and the 1992 Russian–American field programs. The seismic data image most of the sedimentary section, including pre-rift basement in several localities. The MCS data reveal that the broad bathymetric saddle between these two major half-graben basins is underlain by a complex of severely deformed basement blocks, and is not simply a consequence of long-term deltaic deposition. Maximum sediment thickness is estimated to be more than 9 km in some areas around the Selenga Delta. Detailed stratigraphic analyses of the Selenga area MCS data suggest that modes of deposition have shifted markedly during the history of the delta. The present mode of gravity- and mass-flow sedimentation that dominates the northern and southern parts of the modern delta, as well as the pronounced bathymetric relief in the area, are relatively recent developments in the history of the Lake Baikal Rift. Several episodes of major delta progradation, each extending far across the modern rift, can be documented in the MCS data. The stratigraphic framework defined by these prograding deltaic sequences can be used to constrain the structural as well as depositional evolution of this part of the Baikal Rift. An age model has been established for this stratigraphy, by tying the delta sequences to the site of the Baikal Drilling Project 1993 Drill Hole. Although the drill hole is only 100 m deep, and the base of the cores is only ∼670 ka in age, ages were extrapolated to deeper stratigraphic intervals using the Reflection-Seismic-Radiocarbon method of Cohen et al. (1993). The deep prograding delta sequences now observed in the MCS data probably formed in response to major fluctuations in sediment supply, rather than in response to shifts in lake level. This stratigraphic framework and age model suggest that the deep delta packages developed at intervals of approximately 400 ka and may have formed as a consequence of climate changes affiliated with the northern hemisphere glaciations. The stratigraphic analysis also suggests that the Selenga Basin and Syncline developed as a distinct depocentre only during the past ∼2–3 Ma. Received: 1 December 1999 / Accepted: 26 January 2000     

Some observations on diamondiferous bedrock gully trapsites on Late Cainozoic, marine-cut platforms of the Sperrgebiet, Namibia

Namibia's southwestern coast, the Sperrgebiet, hosts one of the world's largest gem diamond placer deposits consisting of fluvial, marine and desert deflation/aeolian placer types. To date, the richest onshore placer discovered in the Sperrgebiet comprises several, Plio-Pleistocene to Holocene, littoral marine packages distributed northwards from the Orange River mouth for some 120 km to Chameis Bay. In this zone, known as Mining Area No. 1 (MA1), these Quaternary marine deposits are floored predominantly by siliciclastic rocks of the Late Proterozoic Gariep Belt that have been bevelled into a number of marine-cut platforms during the different Quaternary high sea level stands (notably, at + 30 m, + 8 m, + 4 m and + 2 m). In many places, these bedrock platforms are extensively gullied and potholed, forming abundant fixed trapsites that promote diamond concentration in the Late Cainozoic littoral sediments. Some observations on the distribution, orientation and incision of bedrock gullies in MA1 are presented here.Three principal bedrock gully types, all of which constitute good diamond trapsites, have been identified in the bedrock footwall between the Orange River mouth northwards to Chameis Bay, a distance of some 120 km: (i) swash-parallel gullies in the southern, proximal sector where the bedrock s₂ dips 45°W and the abrasive gravels are most abundant, thus overriding lithological and structural controls in the footwall; (ii) strike-parallel gullies in the central reach where the bedrock s₂ dips between 80° and 85°W and the abrasive bedload is reduced, resistant lithological units promote the formation of such features along the orientation of the metsediments; and (iii) joint gullies in the northern, distal portion where the bedrock s₂ dips 45–60° to the E and coarse abrasive bedload is virtually absent, the structural pattern in the bedrock is exploited by marine erosion.In these Late Cainozoic placers, diamond concentration is further linked to the depth of the gullies incised into the marine-cut platforms. Maximum incision is noted on the seaward margins of the marine-cut platforms where high-energy littoral processes, acting in a micro-tidal range of ca. 1.8 m under strong prevailing southerly wind and South Atlantic derived southwesterly swell regimes, promote marine erosion and deep gully formation.Therefore, the most favourable diamondiferous trapsites in the Late Cainozoic marine packages of the southwestern Sperrgebiet are those developed in deep bedrock gullies of either swash-parallel, strike-parallel or joint pattern origin on the seaward margins of marine-cut platforms that represent discrete high sea level stands during the Quaternary.     

The bridgman ring paradox revisited

The Bridgman ring experiment, in which a hard rubber ring slipped over a steel rod was observed to split when subjected to a hydrostatic confining pressure, was repeated with Pyrex glass rings. Three cases were studied, in which (a) both ring and rod were unjacketed, (b) the inner wall of the ring was sealed from the pressure medium and (c) both rod and ring were completely jacketed. In the first two cases the ring was observed to split abruptly, with a single axial crack when confining pressure reached a critical level. In the third case no abrupt failure occurred, but a number of axial cracks were found to have formed, grown stably, but not penetrated the outer wall of the ring. The first two cases are explained by hydraulic fracturing of the ring. Observations and analysis indicate that in the third case the cracks started at flaws on the inner surface of the ring and propagated outwards in a stable manner. This case, in which a tensile crack propagates in an all-around compressive stress field, provides some insight into axial cracking of rock in triaxial compression and tensile failure of rock under radial shock loading.