Calcium Carbonate and Phosphate Reference Materials for Monitoring Bulk and Microanalytical Determination of Sr Isotopes

In situ laser ablation analyses rely on the microanalytical homogeneity of reference materials (RMs) and a similar matrix and mass fraction between unknown samples and RMs to obtain reliable results. Suitable carbonate and phosphate RMs for determination of Sr isotope ratios in such materials are limited. Thus, we determined ⁸⁷Sr/⁸⁶Sr ratios of several carbonate (JCt‐1, JCp‐1, MACS‐1, MACS‐3) and phosphate (MAPS‐4, MAPS‐5, NIST SRM 1400, NIST SRM 1486) international RMs using dissolved samples and two different multi‐collector inductively coupled plasma‐mass spectrometers (MC‐ICP‐MS). Our Sr isotope data are in agreement with published data and have an improved measurement precision for some RMs. For MACS‐1, we present the first ⁸⁷Sr/⁸⁶Sr value. We tested the suitability of these materials for microanalytical analyses by LA‐MC‐ICP‐MS, with two different laser ablation systems: a conventional nanosecond laser and a state‐of‐the‐art femtosecond laser. We investigated the RMs micro‐homogeneity and compared the data with our solution data. Both laser ablation systems yielded identical ⁸⁷Sr/⁸⁶Sr ratios within uncertainty to the solution data for RMs with low interferences of REEs. Therefore, these carbonate and phosphate RMs can be used to achieve accurate and precise results for in situ Sr isotope investigations by LA‐MC‐ICP‐MS of similar materials.     

230Th/U Dating of Travertines Related to Paleoearthquakes in Gorny Altai: First Results

Doklady Earth Sciences - First 230Th/U-dating results have been obtained for six Quaternary travertine deposits from the southeastern Gorny Altai associated with zones of active faults that bound...     

Open clusters and the galactic disk

It is textbook knowledge that open clusters are conspicuous members of the thin disk of our Galaxy, but their role as contributors to the stellar population of the disk was regarded as minor. Starting from a homogenous stellar sky survey, the ASCC‐2.5, we revisited the population of open clusters in the solar neighbourhood from scratch. In the course of this enterprise we detected 130 formerly unknown open clusters, constructed volume‐ and magnitude‐limited samples of clusters, re‐determined distances, motions, sizes, ages, luminosities and masses of 650 open clusters. We derived the present‐day luminosity and mass functions of open clusters (not the stellar mass function in open clusters), the cluster initial mass function CIMF and the formation rate of open clusters. We find that open clusters contributed around 40 percent to the stellar content of the disk during the history of our Galaxy. Hence, open clusters are important building blocks of the Galactic disk (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Impact of climate change on wetland ecosystems: A critical review of experimental wetlands

Climate change is identified as a major threat to wetlands. Altered hydrology and rising temperature can change the biogeochemistry and function of a wetland to the degree that some important services might be turned into disservices. This means that they will, for example, no longer provide a water purification service and adversely they may start to decompose and release nutrients to the surface water. Moreover, a higher rate of decomposition than primary production (photosynthesis) may lead to a shift of their function from being a sink of carbon to a source. This review paper assesses the potential response of natural wetlands (peatlands) and constructed wetlands to climate change in terms of gas emission and nutrients release. In addition, the impact of key climatic factors such as temperature and water availability on wetlands has been reviewed. The authors identified the methodological gaps and weaknesses in the literature and then introduced a new framework for conducting a comprehensive mesocosm experiment to address the existing gaps in literature to support future climate change research on wetland ecosystems. In the future, higher temperatures resulting in drought might shift the role of both constructed wetland and peatland from a sink to a source of carbon. However, higher temperatures accompanied by more precipitation can promote photosynthesis to a degree that might exceed the respiration and maintain the carbon sink role of the wetland. There might be a critical water level at which the wetland can preserve most of its services. In order to find that level, a study of the key factors of climate change and their interactions using an appropriate experimental method is necessary. Some contradictory results of past experiments can be associated with different methodologies, designs, time periods, climates, and natural variability. Hence a long-term simulation of climate change for wetlands according to the proposed framework is recommended. This framework provides relatively more accurate and realistic simulations, valid comparative results, comprehensive understanding and supports coordination between researchers. This can help to find a sustainable management strategy for wetlands to be resilient to climate change.     

Lithium isotope geochemistry of marine pore waters - Insights from cold seep fluids

Lithium concentration and isotope data (δ⁷Li) are reported for pore fluids from 18 cold seep locations together with reference fluids from shallow marine environments, a sediment-hosted hydrothermal system and two Mediterranean brine basins. The new reference data and literature data of hydrothermal fluids and pore fluids from the Ocean Drilling Program follow an empirical relationship between Li concentration and δ⁷Li (δ⁷Li = −6.0(±0.3) · ln[Li] + 51(±1.2)) reflecting Li release from sediment or rocks and/or uptake of Li during mineral authigenesis. Cold seep fluids display δ⁷Li values between +7.5‰ and +45.7‰, mostly in agreement with this general relationship. Ubiquitous diagenetic signals of clay dehydration in all cold seep fluids indicate that authigenic smectite-illite is the major sink for light pore water Li in deeply buried continental margin sediments. Deviations from the general relationship are attributed to the varying provenance and composition of sediments or to transport-related fractionation trends. Pore fluids on passive margins receive disproportionally high amounts of Li from intensely weathered and transported terrigenous matter. By contrast, on convergent margins and in other settings with strong volcanogenic input, Li concentrations in pore water are lower because of intense Li uptake by alteration minerals and, most notably, adsorption of Li onto smectite. The latter process is not accompanied by isotope fractionation, as revealed from a separate study on shallow sediments. A numerical transport-reaction model was applied to simulate Li isotope fractionation during upwelling of pore fluids. It is demonstrated that slow pore water advection (order of mm a⁻¹) suffices to convey much of the deep-seated diagenetic Li signal into shallow sediments. If carefully applied, Li isotope systematics may, thus, provide a valuable record of fluid/mineral interaction that has been inherited several hundreds or thousands of meters below the actual seafloor fluid escape structure.     

Golden perch Macquaria ambigua are flexible spawners in the Darling River,Australia

The role of flow and floodplains for the recruitment of fishes in the Murray‐Darling Basin, Australia, remains a contentious issue. In this context, the reproductive ecology of golden perch Macquaria ambigua, a widespread, high‐profile angling species with a propensity to produce large numbers of semi‐pelagic eggs remains to be resolved. Back‐calculation of spawning dates from otoliths of juvenile golden perch (Macquaria ambigua) collected in August and November 1997 from the Menindee Lakes on the floodplain of the Darling River, in western New South Wales, Australia, advances understanding of spawning of this species in three ways: (1) golden perch spawned at lower temperatures (≤18.8°C) than has previously been reported from the Murray‐Darling Basin; (2) golden perch in the Menindee Lakes can be derived from spawning in all seasons of the year in contrast to what is apparent in more southerly locations of the Murray‐Darling Basin; and (3) spawning can occur in the absence of floods.     

Isotopic evidence (Sr/Sr, δLi) for alteration of the oceanic crust at deep-rooted mud volcanoes in the Gulf of Cadiz, NE Atlantic Ocean

The chemical and isotopic composition of pore fluids is presented for five deep-rooted mud volcanoes aligned on a transect across the Gulf of Cadiz continental margin at water depths between 350 and 3860 m. Generally decreasing interstitial Li concentrations and ⁸⁷Sr/⁸⁶Sr ratios with increasing distance from shore are attributed to systematically changing fluid sources across the continental margin. Although highest Li concentrations at the near-shore mud volcanoes coincide with high salinities derived from dissolution of halite and late-stage evaporites, clayey, terrigenous sediments are identified as the ultimate Li source to all pore fluids investigated. Light δ⁷Li values, partly close to those of hydrothermal vent fluids (δ⁷Li: +11.9‰), indicate that Li has been mobilized during high-temperature fluid/sediment or fluid/rock interactions in the deep sub-surface. Intense leaching of terrigenous clay has led to radiogenic ⁸⁷Sr/⁸⁶Sr ratios (∼0.7106) in pore fluids of the near-shore mud volcanoes. In contrast, non-radiogenic ⁸⁷Sr/⁸⁶Sr ratios (∼0.7075) at the distal locations are attributed to admixing of a basement-derived fluid component, carrying an isotopic signature from interaction with the basaltic crust. This inference is substantiated by temperature constraints from Li isotope equilibrium calculations suggesting exchange processes at particularly high temperatures (>200 °C) for the least radiogenic pore fluids of the most distal location.Advective pore fluids in the off-shore reaches of the Gulf of Cadiz are influenced by successive exchange processes with both oceanic crust and terrigenous, fine-grained sediments, resulting in a chemical and isotopic signature similar to that of fluids in near-shore ridge flank hydrothermal systems. This suggests that deep-rooted mud volcanoes in the Gulf of Cadiz represent a fluid pathway intermediate between mid-ocean ridge hydrothermal vent and shallow, marginal cold seep. Due to the thicker sediment coverage and slower fluid advection rates, the overall geochemical signature is shifted towards the sediment-diagenetic signal compared to ridge flank hydrothermal environments.     

Fast Object Detection for Use Onboard Satellites

We propose an object detection algorithm which is efficient and fast enough to be used in (almost) real time with the limited computer capacities onboard satellites. For stars below the saturation limit of the CCD detectors it is based on a four neighbourhood local maximum criterion in order to find the centre of a stellar image. For saturated stars it is based on the assumption that the image is increasing monotonically towards the centre in the unsaturated part of the image. The algorithm also calculates approximate stellar magnitudes and efficiently rejects most of the cosmics which would otherwise lead to a large number of false detections. The quality of the algorithm was evaluated with the help of a large set of simulated data for the DIVA satellite mission; different assumptions were made for the noise level, and the presence of cosmics or for a variable sky background.We could show that our algorithm fulfills the requirements for DIVA; only in the case of simulated images which included the bright galaxy M31 some fainter stars could not be detected in the galaxy's vicinity. Since stellar images contain large areas without any stars, we propose an additional block-skipping algorithm which can be coded on special-purpose hardware. This revised version was published online in July 2006 with corrections to the Cover Date.