Evidence for Differential Unroofing in the Adirondack Mountains, New York State, Determined by Apatite Fission-Track Thermochronology

Apatite fission-track ages of 168-83 Ma for 39 samples of Proterozoic crystalline rocks, three samples of Cambrian Potsdam sandstone, and one Cretaceous lamprophyre dike from the Adirondack Mountains in New York State indicate that unroofing in this region occurred from Late Jurassic through Early Cretaceous. Samples from the High Peaks section of the Adirondack massif yielded the oldest apatite fission-track ages (168-135 Ma), indicating that it was exhumed first. Unroofing along the northern, northwestern, and southwestern margins of the Adirondacks began slightly later, as shown by younger apatite fission-track ages (146-114 Ma) determined for these rocks. This delay in exhumation may have resulted from burial of the peripheral regions by sediment shed from the High Peaks. Apatite fission-track ages for samples from the southeastern Adirondacks are distinctly younger (112-83 Ma) than those determined for the rest of the Adirondack region. These younger apatite fission-track ages are from a section of the Adirondacks dissected by shear zones and post-Ordovician north-northeast-trending normal faults. Differential unroofing may have been accommodated by reactivation of the faults in a reverse sense of motion with maximum compressive stress, sigma1, oriented west-northwest. A change in the orientation of the post-Early Cretaceous paleostress field is supported by a change in the trend of Cretaceous lamprophyre dikes from east-west to west-northwest.     

Field trial using bone meal amendments to remediate mine waste derived soil contaminated with zinc, lead and cadmium

Bone meal amendments are being considered as a remediation method for metal-contaminated wastes. In various forms (biogenic, geogenic or synthetic), apatite, the principal mineral constituent of bone, has shown promise as an amendment to remediate metal-contaminated soils via the formation of insoluble phosphates of Pb and possibly other metals. The efficacy of commercially available bovine bone meal in this role was investigated in a field trial at Nenthead, Cumbria with a mine waste derived soil contaminated with Zn, Pb and Cd. Two 5 m² plots were set up; the first as a control and the second, a treatment plot where the soil was thoroughly mixed with bone meal to a depth of 50 cm at a soil to amendment ratio of 25:1 by weight. An array of soil solution samplers (Rhizon SMS^™) were installed in both plots and the soil pore water was collected and analysed for Ca, Cd, Zn and Pb regularly over a period of 2 a. Concurrently with the field trial, a laboratory trial with 800 mm high and 100 mm wide leaching columns was conducted using identical samplers and with soil from the field site.A substantial release of Zn, Pb, Cd and Ca was observed associated with the bone meal treatment. This release was transient in the case of the leaching columns, and showed seasonal variation in the case of the field trial. It is proposed that this effect resulted from metal complexation with organic acids released during breakdown of the bone meal organic fraction and was facilitated by the relatively high soil pH of 7.6–8.0. Even after this transient release effect had subsided or when incinerated bone meal was substituted in order to eliminate the organic fraction, no detectable decrease in dissolved metals was observed and no P was detected in solution, in contrast with an earlier small column laboratory study. It is concluded that due to the relative insolubility of apatite at above-neutral pH, the rate of supply of phosphate to soil solution was insufficient to result in significant precipitation of metal phosphates and that this may limit the effectiveness of the method to more acidic soils.     

Shoreline development,longshore transport and surface wave dynamics,Pleistocene Lake Bonneville,Utah

Point of the Mountain spit and Fingerpoint spit are two of the largest geomorphic features of Pleistocene Lake Bonneville of the western Great Basin, USA. The spits and their associated shorelines show distinctly different geomorphic expression and genesis; this is a function of their positions within the lake and the dynamics of the waves and storms that formed them. Mapping of geomorphic features, geometry of erosional features, and detailed lithologic analysis of shoreline deposits are used to determine dominant modes of sediment erosion and deposition. The Point of the Mountain spit, located in the eastern portion of the basin, was formed as a result of highly fractured bedrock in a salient of the Wasatch Front being exposed to wave trains that approached from the north‐northwest causing north‐to‐south longshore sediment transport. Shoreline development and sediment transport on the southern portion of the spit were minimal. The Fingerpoint spit, located on an island in the northwest portion of the basin, was formed by bidirectional longshore sediment transport as the result of waves that approached from both the north‐northeast and the south‐southwest. Spit development is a function of surface wave energy and direction which in turn is the integrated result of wind direction, wind intensity, and fetch. Wave transport direction determined from ?eld measurements at Point of the Mountain spit corresponds very well to the direction of maximum fetch (c. 200 km). For the Fingerpoint spit, the hypothesized wave transport direction from the south corresponds with the direction of maximum fetch (c. 350 km). However, wave energy transport from the north had limited fetch (c. 100 km), implying that wind intensity from the north was relatively large. The geometry of the two large Bonneville spits suggests the predominant wind direction from storms during the Pleistocene was from the north and points the way for future studies that can aid in further understanding the nature of Pleistocene wind ?elds in the Great Basin. Copyright © 2004 John Wiley & Sons, Ltd.     

Type 1 aqueous alteration in CM carbonaceous chondrites: Implications for the evolution of water‐rich asteroids

The CM carbonaceous chondrite meteorites experienced aqueous alteration in the early solar system. They range from mildly altered type 2 to almost completely hydrated type 1 chondrites, and offer a record of geochemical conditions on water‐rich asteroids. We show that CM1 chondrites contain abundant (84–91 vol%) phyllosilicate, plus olivine (4–8 vol%), magnetite (2–3 vol%), Fe‐sulfide (<5 vol%), and calcite (<2 vol%). The CM1/2 chondrites contain phyllosilicate (71–88 vol%), olivine (4–20 vol%), enstatite (2–6 vol%), magnetite (2–3 vol%), Fe‐sulfides (1–2 vol%), and calcite (~1 vol%). As aqueous alteration progressed, the abundance of Mg‐serpentine and magnetite in the CM chondrites increased. In contrast, calcite abundances in the CM1/2 and CM1 chondrites are often depleted relative to the CM2s. The modal data support the model, whereby metal and Fe‐rich matrix were the first components to be altered on the CM parent body(ies), before further hydration attacked the coarser Mg‐rich silicates found in chondrules and fragments. Based on the absence of tochilinite, we suggest that CM1 chondrites experienced increased alteration due to elevated temperatures (>120 °C), although higher water/rock ratios may also have played a role. The modal data provide constraints for interpreting the composition of asteroids and the mineralogy of samples returned from these bodies. We predict that “CM1‐like” asteroids, as has been proposed for Bennu—target for the OSIRIS‐REx mission—will have a high abundance of Mg‐rich phyllosilicates and Fe‐oxides, but be depleted in calcite.     

The alteration history of the Jbilet Winselwan CM carbonaceous chondrite: An analog for C‐type asteroid sample return

Jbilet Winselwan is one of the largest CM carbonaceous chondrites available for study. Its light, major, and trace elemental compositions are within the range of other CM chondrites. Chondrules are surrounded by dusty rims and set within a matrix of phyllosilicates, oxides, and sulfides. Calcium‐ and aluminum‐rich inclusions (CAIs) are present at ≤1 vol% and at least one contains melilite. Jbilet Winselwan is a breccia containing diverse lithologies that experienced varying degrees of aqueous alteration. In most lithologies, the chondrules and CAIs are partially altered and the metal abundance is low (<1 vol%), consistent with petrologic subtypes 2.7–2.4 on the Rubin et al. ( 2007 ) scale. However, chondrules and CAIs in some lithologies are completely altered suggesting more extensive hydration to petrologic subtypes ≤2.3. Following hydration, some lithologies suffered thermal metamorphism at 400–500 °C. Bulk X‐ray diffraction shows that Jbilet Winselwan consists of a highly disordered and/or very fine‐grained phase (73 vol%), which we infer was originally phyllosilicates prior to dehydration during a thermal metamorphic event(s). Some aliquots of Jbilet Winselwan also show significant depletions in volatile elements such as He and Cd. The heating was probably short‐lived and caused by impacts. Jbilet Winselwan samples a mixture of hydrated and dehydrated materials from a primitive water‐rich asteroid. It may therefore be a good analog for the types of materials that will be encountered by the Hayabusa‐2 and OSIRIS‐REx asteroid sample‐return missions.     

Elusive security: The military and political geography of South Lebanon

Israel's quest for security on its northern border with Lebanon has a history dating back to the foundation of the Palestine mandate. In the early period from the First World War to the end of the 1960s the quest was dominated with attaining economic and environmental security by seeking to acquire rights to the waters of South Lebanon. Recent decades in contrast have witnessed the rise in importance of border security and strategic security requirements in the face of military threats to northern Israel. Israel's interventionist policy in South Lebanon has been formalised to include a permanent presence on Lebanese territory in the form of the security zone. It is argued that despite the positive events that have occurred in the region in the early 1990s, it remains unlikely that Israel will easily relinquish its security shield in South Lebanon thus ultimately undermining the possibility of moving away from elusive to permanent security.     

Norse–Inuit interaction and landscape change in southern Greenland? A geochronological,Pedological, and Palynological investigation

Ruins representing both medieval Norse and Inuit (Thule culture) settlements can be found together on the coast at Sandhavn (59°59′ N, 44°46′ W), Greenland. The site presents a rare opportunity to investigate the character of past contact and interaction between these two peoples. Soils‐based, radiocarbon, and palynological analyses demonstrate the creation of hortic anthrosols within Norse home‐fields used between the mid‐11th and late 14th centuries A.D. Irrigation channels have been identified within the home‐fields, while rising grass pollen influx reveals intensification in hay production over the period ca. A.D. 1260–1350 despite climatic deterioration setting in around this time. Floor deposits and wall packing from an Inuit winter house returned dates of cal. A.D. 1220–1290 (2σ), yet no direct landscape‐based evidence for Inuit activity could be determined. Although the exact nature of the relationship between Norse and Thule at Sandhavn remains unclear, the role of this site as a harbor and possible trading area may have attracted Inuit settlers keen to participate in European trade networks. © 2011 Wiley Periodicals, Inc.     

Mineralogical characterization of the Nkamouna Co–Mn laterite ore, southeast Cameroon

The Nkamouna property is an oxide laterite deposit developed on serpentinized peridotite in southeast Cameroon. It is enriched in Co and Mn, has sub-economic Ni grades and will be mined primarily for Co. The ore zone is ca. 10 m thick and comprises the lower breccia (～3 m thick) and ferralite (7–8 m thick) units sandwiched between an 8-m-thick ferricrete overburden and a barren hydrated Mg–silicate saprolite. The ore mineral assemblage includes Mn oxyhydroxides, magnetite, maghemite, ferritchromite, goethite, hematite, kaolinite and gibbsite. Lithiophorite is the most common Mn mineral and is the main host of Co, Mn and a significant proportion of Ni. It occurs as coatings in pores and on other mineral grains and as concretions and impregnations in the matrix. It is invariably associated with gibbsite in the lower breccia and with magnetite and ferritchromite in the ferralite. Although ore in the lower breccia is volumetrically less important than the ferralite, it has the highest grade and Co/Ni ratio. The lithiophorite in the ore zone is authigenic, and its formation was enhanced by influx of Al³⁺ from the overlying ferricrete. Magnetite and ferritchromite in the ferralite are relicts and contributed to mineralization by enhancing the permeability of the ferralite and providing substrates for the precipitation of the Mn oxyhydroxides. The structure and mode of occurrence of the lithiophorite makes Nkamouna ore amenable to physical beneficiation, producing a concentrate with Co grades 2.3–4.5 times higher than the run-of-mine ore.