Stress-induced variations of remanent magnetism in Late Quaternary varved clay

A study of the remanent magnetism in Swedish varved clay shows that, even in varves that macroscopically appear to be undeformed, the paleomagnetic record may be seriously altered due to stress-induced deformation of the micro-fabric in the sediment.In the studied area disturbed clays were rather the rule than the exception, but undisturbed sediments were found at two sites, Järna II and III. This clay formed 10,200 years B.P. and shows a declination of about 30° east, a value that could be obtained thanks to excellent lateral control of the magnetism.     

The micrometeorite flux to Earth during the earliest Paleogene reconstructed in the Bottaccione section (Umbrian Apennines), Italy

Based on sediment‐dispersed extraterrestrial spinel grains in the Bottaccione limestone section in Italy, we reconstructed the micrometeorite flux to Earth during the early Paleocene. From a total of 843 kg of limestone, 86 extraterrestrial spinel grains (12 grains > 63 μm, and 74 in the 32–63 μm fraction) have been recovered. Our results indicate that the micrometeorite flux was not elevated during the early Paleocene. Ordinary chondrites dominated over achondritic meteorites similar to the recent flux, but H chondrites dominated over L and LL chondrites (69%, 22%, and 9%, respectively). This H‐chondrite dominance is similar to that recorded within an enigmatic ³He anomaly (70, 27, and 3%) in the Turonian, but different from just before this ³He anomaly and in the early Cretaceous, where ratios are similar to the recent flux (~45%, 45%, and 10%). The K‐Ar isotopic ages of recently fallen H chondrites indicate a small impact event on the H‐chondrite parent body ~50 to 100 Ma ago. We tentatively suggest that this event is recorded by the Turonian ³He anomaly, resulting in an H‐chondrite dominance up to the Paleocene. Our sample spanning the 20 cm above the Cretaceous–Paleogene (K–Pg) boundary did not yield any spinel grains related to the K–Pg boundary impactor.     

A 3-D lithospheric model of the Caribbean-South American plate boundary

A 3-D structural model of the Caribbean-South American plate boundary was constructed by gravity modeling. The model was constrained by four wide-angle seismic refraction sections, Moho depth estimations from receiver functions, and additionally seismological hypocenters, surface geology, and geodynamic information. Density values were calculated from empirical velocity-density functions, and mineralogical-chemical composition considering specific P/T conditions. We tested different structural models for Western and Eastern Venezuela. In the final model, the fit of the measured and modeled gravity fields for a long Caribbean slab in Western Venezuela was better than the fit obtained for a short one. This interpretation is consistent with the constraining data. The slab is interpreted to extend further to the south beneath Northern Colombia and culminates in the area of the seismic cluster of the Bucaramanga nest. The modeling estimates a slab dip angle under Maracaibo and Mérida Andes of 15°, which increases to 32° below 100 km depth. The dip direction of approx. N150°E ± 5 increases lightly eastward. In Eastern Venezuela, considering its short wavelength, lineaments analyzed from gravity data (by curvature methods and Euler deconvolution) seem to be related to shallow structures and density contrast in the Serranía del Interior and not from a deep detached slab beneath the continental crust. It is deduced from modeling results that this slab configuration has a very small influence on the gravity field. The slab was modeled according to the subduction-transform propagation model with purely westward subduction and a slab break off along a vertical dip-slip tear through the lithosphere.     

Development of Emission Models and Improvement of Emission Data for Germany

Measurements and model developments with the objective to improve the quality and resolution of estimations of anthropogenic emissions are described. Measurement results on a chassis dynamometer were used to determine VOC profiles for exhaust gas emissions of passenger cars for different vehicle and fuel types and different driving modes. Further measurements resulted in emission factors and VOC profiles for lignite burning in residential stoves. Using remote sensing techniques benzene emission factors of gas stations and the efficiency of gasoline vapour recovery systems were measured.To improve the quality and the spatial and temporal resolution of emission data, emission models were improved or modified. This was done by elaborating and applying new methods for important emission source categories (e.g., solvent use, road traffic, small combustion) as well as including new data sources in the calculation routines (e.g. emission statements, land use data, import/export indices of solvents). Simultaneously considerable progress was made improving temporal and spatial allocation functions and VOC profiles. With these improvements a large number of anthropogenic emission data sets for 14 different grid projections in Germany and Europe have been generated. An emission scenario for Germany for 2010 suggests that considering air quality directives from the EU and Germany which are in force or in pipeline, German emissions of VOC and NO_x will decrease, but still exceed the national emission ceilings of the EU-NEC directive.     

A Database for Volatile Organic Compounds

The database for volatile organic compounds (VOC data base) was created with the aim of providing an overview of tropospheric hydrocarbon measurements. The data base contains 202 substances, for which atmospheric and useful kinetic data such as rate coefficients, photolysis frequencies, mixing ratios, emission data and ozone formation potentials are compiled from available literature. The database file can be downloaded without charge from http://www.physchem.uni-wuppertal.de/voc-database. Registered users will be informed about the appearance of updates.     

Preservation of extraterrestrial 3He in 480-Ma-old marine limestones.

We have measured the helium abundance and isotopic composition of a suite of Lower Ordovician marine limestones and associated fossil meteorites from Kinnekulle, Sweden. Limestone 3He/4He ratios as high as 11.5 times the atmospheric value in fused samples and up to 23 times atmospheric in a single step-heat fraction indicate the presence of extraterrestrial helium, and demonstrate that at least a fraction of the extraterrestrial 3He carried by interplanetary dust particles must be retained against diffusive and diagenetic losses for up to 480 Ma. The carrier phase has not been identified but is not magnetic. Extrapolation of high-temperature 3He diffusivities in these sediments is consistent with strong retention of extraterrestrial 3He under ambient Earth-surface conditions. Combination of the observed helium concentrations with sedimentation rates estimated from conodont biostratigraphy suggest that the flux of extraterrestrial 3He in the Early Ordovician was about 0.5 x 10(-12) cm3 STP cm-2 ka-1, ignoring potential post-deposition helium loss. This value is indistinguishable from the average 3He flux estimated for the Cenozoic Era. In contrast, previous studies of fossil meteorites, Ir abundances, and Os isotopic ratios in the limestone suggest that the total accretion rate of extraterrestrial material during the studied interval was at least an order of magnitude higher than the Cenozoic average. This disparity may reflect significant post-depositional loss of 3He from IDPs within these old limestones; if so, the match between the Ordovician flux and the Cenozoic average would be fortuitous. Alternatively, the size distribution of infalling objects during the Early Ordovician may have been enriched only in extraterrestrial material too large to retain 3He during atmospheric entry heating (> approximately 30 micrometers). The fossil meteorites themselves also preserve extraterrestrial helium. Meteorite 3He concentrations of 2 to 9 x 10(-12) cm3 STP g-1 are several orders of magnitude lower than found in most modern meteorites, suggesting very substantial helium loss (probably >99.9%) from these chemically altered objects. The Meteorites carry 3He concentrations only a factor of a few higher than the host limestones. The meteorites themselves cannot be the source of the extraterrestrial 3He observed in the limestones.     

X-ray diffraction studies of millerite NiS under non-ambient conditions

The high-pressure behaviour of millerite NiS up to 34.7 GPa was studied using single-crystal X-ray diffraction techniques. Under ambient pressure, 8.3, 19.2 and 26.8 GPa crystal-structure determinations were performed. No phase transition was observed and the fit of the Birch-Murnaghan equation of state gave a bulk modulus K=111(1) GPa and a pressure derivative K=5.0(1) at high pressure and room temperature. The high-temperature modification of NiS belongs to the NiAs type and has the smaller volume per formula unit. High-pressure–high-temperature X-ray diffraction studies on NiS powder indicate that the transition temperature is strongly dependent on pressure. Owing to the higher compressibility of millerite compared with that of the high-temperature phase, it is assumed that the NiAs-type is not the stable phase at high pressures.