A contribution to the migration of gold in the biosphere of the humid mild zone

The content of gold in plants has been used as an indicator in the prospecting for gold. For this purpose non-destructive analytical methods have been developed. In the humid mild zone — where the process of weathering is of a kaolinitic character — there is practically no migration of gold, and consequently its increased content indicates the presence of a gold deposit.     

Die alten Gebirge der Provinz Buenos Aires

Ohne Zusammenfassung     

Eddy-resolving ocean circulation in the Asian-Australian region inferred from an ocean reanalysis effort

The first global ocean reanalysis with focus on the Asian-Australian region was performed for the period October 1992 to June 2006. The 14-year experiment assimilated available observations of altimetric sea-level anomaly, satellite SST and quality-controlled in situ temperature and salinity profiles from a range of sources, including field surveys and the Argo float array. This study focuses on dominant circulation patterns in the South-East Asian/Australian region as simulated by an eddy-resolving and data-assimilating ocean general circulation model. New estimates of the ocean circulation are provided which are largely in agreement with the limited number of observations. Transports of key currents in the region are as follows: The total (top-to-bottom) annual mean Indonesian Throughflow transport and its standard deviation are 9.7 ± 4.4 Sv from the Pacific to the Indian Ocean with a minimum in January (6.6 Sv) and a maximum in April (12.3 Sv). The Leeuwin Current along the west coast of Australia is dominated by eddy structures with a mean southward transport of 4.1 ± 2.0 Sv at 34°S. Along the southern coast of Australia a narrow shelf edge current known as the South Australian Current advects 4.5 ± 2.6 Sv eastward at 130°E. The South Australian Current converges east of Tasmania with the eddy-rich extension of East Australian Current. At 32°S this current transports 36.8 ± 18.5 Sv southward. A dominating feature of the circulation between north-eastern Australia and Papua-New Guinea is the strong and quasi-permanent Coral Sea Gyre. This gyre is associated with the highly variable Hiri Current which runs along the south coast of Papua-New Guinea and advects 8.2 ± 19.1 Sv into the Western Pacific Ocean. All of these transport estimates are subject to strong eddy variability.     

Development of a Neural Network Algorithm for Retrieving Concentrations of Chlorophyll, Suspended Matter and Yellow Substance from Radiance Data of the Ocean Color and Temperature Scanner

An algorithm is presented to retrieve the concentrations of chlorophyll a, suspended pariclulate matter and yellow substance from normalized water-leaving radiances of the Ocean Color and Temperature Sensor (OCTS) of the Advanced Earth Observing Satellite (ADEOS). It is based on a neural network (NN) algorithm, which is used for the rapid inversion of a radiative transfer procedure with the goal of retrieving not only the concentrations of chlorophyll a but also the two other components that determine the water-leaving radiance spectrum. The NN algorithm was tested using the NASA's SeaBAM (SeaWiFS Bio-Optical Mini-Workshop) test data set and applied to ADEOS/OCTS data of the Northwest Pacific in the region off Sanriku, Japan. The root-mean-square error between chlorophyll a concentrations derived from the SeaBAM reflectance data and the chlorophyll a measurements is 0.62. The retrieved chlorophyll a concentrations of the OCTS data were compared with the corresponding distribution obtained by the standard OCTS algorithm. The concentrations and distribution patterns from both algorithms match for open ocean areas. Since there are no standard OCTS products available for yellow substance and suspended matter and no in situ measurements available for validation, the result of the retrieval by the NN for these two variables could only be assessed by a general knowledge of their concentrations and distribution patterns. This revised version was published online in July 2006 with corrections to the Cover Date.     

Atmospheric Measurements of HONO by Tunable Diode Laser Absorption Spectroscopy

Ambient gas phase nitrous acid (HONO) has been measured by Tunable Diode Laser Absorption Spectroscopy with sub-ppbv detection limits. An R-branch line in the 1263.4 cm^–1 ₃ band was found tobe free of interference and suitable for ambient HONO measurements. Nitrous acid was measured during the night and early morning at an urban site in Toronto, Canada, during the summer of 1998. Average mixing ratios, integrated over 30 minutes, ranged from below the minimum detection limit of 300 pptv to 1.9 ppbv, with the highest concentrations observed during the early morning hours. During the night of 19 June 1998, the concentration of HONO increased by as much as 0.5 ppbv/hr. The usual decrease in HONO after sunrise was delayed by a few hours, possibly due to a combination of an increase in the production rate of HONO with rush hour, and attenuation of the early morning light by high NO₂ within the aerosol fog/haze.     

Contraction,fragmentation and expansion dynamics determine nutrient availability in a Mediterranean forest stream

Temporary streams are a dominant surface water type in the Mediterranean region. As a consequence of their hydrologic regime, these ecosystems contract and fragment as they dry, and expand after rewetting. Global change leads to a rapid increase in the extent of temporary streams, and more and more permanent streams are turning temporary. Consequently, there is an urgent need to better understand the effects of flow intermittency on the biogeochemistry and ecology of stream ecosystems. Our aim was to investigate how stream nutrient availability varied in relation to ecosystem contraction, fragmentation and expansion due to hydrologic drying and rewetting. We quantified the temporal and spatial changes in dissolved nitrogen (N) and phosphorus (P) concentrations along a reach of a temporary Mediterranean forest stream during an entire contraction–fragmentation–expansion hydrologic cycle. We observed marked temporal changes in N and P concentrations, in the proportion of organic and inorganic forms as well as in stoichiometric ratios, reflecting shifts in the relative importance of in-stream nutrient processing and external nutrient sources. In addition, the spatial heterogeneity of N and P concentrations and their ratios increased substantially with ecosystem fragmentation, reflecting the high relevance of in-stream processes when advective transport was lost. Overall, changes were more pronounced for N than for P. This study emphasizes the significance of flow intermittency in regulating stream nutrient availability and its implications for temporary stream management. Moreover, our results point to potential biogeochemical responses of these ecosystems in more temperate regions under future water scarcity scenarios.     

A method for the stochastic modeling of karstic systems accounting for geophysical data: an example of application in the region of Tulum, Yucatan Peninsula (Mexico)

The eastern coast of the Yucatan Peninsula, Mexico, contains one of the most developed karst systems in the world. This natural wonder is undergoing increasing pollution threat due to rapid economic development in the region of Tulum, together with a lack of wastewater treatment facilities. A preliminary numerical model has been developed to assess the vulnerability of the resource. Maps of explored caves have been completed using data from two airborne geophysical campaigns. These electromagnetic measurements allow for the mapping of unexplored karstic conduits. The completion of the network map is achieved through a stochastic pseudo-genetic karst simulator, previously developed but adapted as part of this study to account for the geophysical data. Together with the cave mapping by speleologists, the simulated networks are integrated into the finite-element flow-model mesh as pipe networks where turbulent flow is modeled. The calibration of the karstic network parameters (density, radius of the conduits) is conducted through a comparison with measured piezometric levels. Although the proposed model shows great uncertainty, it reproduces realistically the heterogeneous flow of the aquifer. Simulated velocities in conduits are greater than 1 cm?s^?1, suggesting that the reinjection of Tulum wastewater constitutes a pollution risk for the nearby ecosystems.     

The APE-THESEO Tropical Campaign: An Overview

The APE-THESEO campaign was held from 15 February to 15 March 1999 from the Seychelles in the western Indian Ocean. APE-THESEO stands for Airborne Platform for Earth observation — (contribution to) the Third European Stratospheric Experiment on Ozone. The campaign aimed to study processes controlling the low water content of the stratosphere, including the mechanisms of cloud formation in the tropical tropopause region, and transport processes, studied using measurements of long-lived trace gases and ozone.Two aircraft were used: the high-altitude research aircraft, M-55 Geophysica, which can fly up to 21 km, and the Falcon of the Deutsches Zentrum für Luft- und Raumfahrt, a tropospheric aircraft. Seven flights were performed, including the first simultaneous in situ and remote sensing of sub-visible cirrus clouds, the first interception of sub-visible cirrus using in-flight guidance from a path-finding aircraft, and guided descent of a high-altitude research aircraft into the anvil cloud at the top of a tropical cyclone. In this paper we describe the payload used, the objectives for each flight, and the meteorological conditions encountered. First results show that a new type of cloud, which we have dubbed ultra-thin tropical tropopause cloud (UTTC), has been observed frequently, and observed to cover areas of 10⁵ km². The frequent coincidence of the tropopause and hygropause implies that the western Indian Ocean played an important role in the dehydration of the lower tropical stratosphere during the season of the mission. UTTCs, sub-visible cirrus, and visible cirrus, have all been implicated in the observed dehydration. Tracer measurements indicate little mixing of stratospheric air into the upper tropical troposphere.