Isotopic and molecular composition of coal-bed gas in the Amasra region (Zonguldak basin—western Black Sea)

Previous studies on the coal-bed methane potential of the Zonguldak basin have indicated that the gases are thermogenic and sourced by the coal-bearing Carboniferous units. In this earlier work, the origin of coal-bed gas was only defined according to the molecular composition of gases and to organic geochemical properties of the respective source rocks, since data on isotopic composition of gases were not available. Furthermore, in the western Black Sea region there also exist other source rocks, which may have contributed to the coal-bed gas accumulations. The aim of this study is to determine the origin of coal-bed gas and to try a gas-source rock correlation. For this purpose, the molecular and isotopic compositions of 13 headspace gases from coals and adjacent sediments of two wells in the Amasra region have been analyzed. Total organic carbon (TOC) measurements and Rock-Eval pyrolysis were performed in order to characterize the respective source rocks. Coals and sediments are bearing humic type organic matter, which have hydrogen indices (HI) of up to 300 mgHC/gTOC, indicating a certain content of liptinitic material. The stable carbon isotope ratios (δ¹³C) of the kerogen vary from −23.1 to −27.7‰. Air-free calculated gases contain hydrocarbons up to C₅, carbon dioxide (<1%) and a considerable amount of nitrogen (up to 38%). The gaseous hydrocarbons are dominated by methane (>98%). The stable carbon isotope ratios of methane, ethane and propane are defined as δ¹³C₁: −51.1 to −48.3‰, δ¹³C₂: −37.9 to −25.3‰, δ¹³C₃: −26.0 to −19.2 ‰, respectively. The δD₁ values of methane range from −190 to −178‰. According to its isotopic composition, methane is a mixture, partly generated bacterially, partly thermogenic. Molecular and isotopic composition of the gases and organic geochemical properties of possible source rocks indicate that the thermogenic gas generation took place in coals and organic rich shales of the Westphalian-A Kozlu formation. The bacterial input can be related to a primary bacterial methane generation during Carboniferous and/or to a recent secondary bacterial methane generation. However, some peculiarities of respective isotope values of headspace gases can also be related to the desorption process, which took place by sampling.     

An Analysis of Regional and Intra-annual Precipitation Variability over Iran using Multivariate Statistical Methods

Summary The temporal and spatial precipitation regime of Iran was analysed using multivariate analyses of monthly mean precipitation records for 71 stations. A Principal Component Analysis was applied to the correlation matrix in order to describe the intra-annual variations of precipitation. The Principal Component scores were mapped to visualize the spatial structure of the three derived precipitation regimes. By applying an agglomerative clustering (WARD) of the three Principal Component scores, five homogeneous spatial clusters, representing five precipitation regions, were developed. The intra-annual types of precipitation distribution, shown by the five clusters, are described and discussed. Received November 24, 1997 Revised July 17, 1998     

Cosmo-SkyMed X-band SAR data for classification of ice-free areas and glacier facies on Potter Peninsula,King George Island Antarctica

The climate change phenomena have been influencing terrestrial and glacial ecosystems around the planet. Maritime Antarctica is especially sensitive to these climate variations and over the last 50 years increasing global air temperatures have caused extensive glacial retreat. The objective of this study is to evaluate the potential use of the SAR technology in monitoring the surface dynamics of the Potter Peninsula, King George Island, maritime Antarctica. An image generated by the SAR satellite COSMO-SkyMed, obtained on 2 February 2011, was used to extract the backscattering values of targets on the surface for further processing and classification, using a supervised statistic classifier of maximum likelihood for the determination of the surface classes. The average backscattering of water bodies presented high similarity, which made its separation unattainable. On the other hand, the surface classes’ bare ice and wet snow over the glacier presented distinct average backscattering values, which allowed an efficient and precise classification using only this parameter. The classification process showed satisfactory results for periglacial environments, presenting high fidelity to the field data.     

Remote sensing of thunderstorm activity by means of VLF sferics

The results of a three-month observational period (June–August 1981) during sunlit hours (9:00–15:00 GMT) with VLF sferics at the two stations Tel Aviv, Israel, and Pretoria, South Africa, are presented and compared with rainfall data for the European-African area, with two lability indices of thunderstorm prediction, and with synoptic thunderstorm reports for the same time interval. The locations of thunderstorm centers on the continents determined from the sferics stations compare reasonably well with the distribution of rainfall, indicating that the VLF sferics method is a useful measure of rainfall, particularly in remote regions with inadequate coverage of observing stations. The lability index of Showalter (1953) appears to be rather qualitative for the prediction of thunderstorm occurrence, and any fine structure in the distribution of thunderstorm centers as seen in the sferics data is lost. The same is true of the synoptic reports of thunderstorm days. A new lability index has been developed. This index leads to a more detailed structure of thunderstorm prediction, which is consistent with the sferics data.     

Jet streams,thunderstorms, and Project Skyfire

Summary More than 70% of forest fires in the northwestern United States are caused by lightening. The Project Skyfire is an attempt to learn more about the atmospheric conditions leading to thunderstorms in this area and to investigate the possibilities of an artificial influence on their development by cloud seeding. The experiences gained with the training of amateur observers as well as the first scientific results of the project are briefly discussed. During the first year of observations, for instance, there was found to exist an intimate relationship between a certain type of fast moving thunderstorms and the intensity and position of the jet stream. Finally, the great economical value of researches in the field of applied meteorology is stressed.

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Zusammenfassung Über 70% der Waldbrände im Nordwesten der Vereinigten Staaten werden durch Blitze entzündet. Das Project Skyfire hat es sich zum Ziel gesetzt, die atmosphärischen Bedingungen, welche zur Bildung von Gewittern in diesem Gebiet führen, zu untersuchen und die Möglichkeiten einer künstlichen Beeinflussung durch seeding zu erforschen. Die gesammelten Erfahrungen mit der Schulung von Amateur-Beobachtern, sowie die bisherigen wissenschaftlichen Ergebnisse werden kurz diskutiert. Schon im ersten Jahr der Beobachtungen ergaben sich interessante Zusammenhänge zwischen einer bestimmten Art von rasch ziehenden Gewittern und dem Jet-Stream. Schließlich wird auf den weitreichenden wirtschaftlichen Nutzen großzügiger Forschungen auf dem Gebiet der angewandten Meteorologie hingewiesen.

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Résumé Plus de 70% des incendies de forêts dans le Nord-Ouest des Etats-Unis sont dûs à la foudre. Le «Project Skyfire» a pour but d'étudier les conditions atmosphériques conduisant dans ces régions à la formation d'orages ainsi que les possibilités d'agir sur cette formation au moyen d'inséminations artificielles. On discute brièvement les expériences faites en instruisant des observateurs amateurs ainsi que les résultats scientifiques. Dès la première année de recherches, on a constaté d'intéressantes relations entre un certain type d'orages rapides et le jet stream. Enfin on attire l'attention sur le grand intérêt économique d'études étendues dans le domaine de la métérologie appliquée.

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With 7 Figures.

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The Munitalp Foundation, Inc.     

Statistical Insights Regarding Fully Softened Shear Strength

The fully softened shear strength (FSS) concept is a practical approximation of the mobilized drained shear strength of first-time slides in stiff-fissured clays. There has been a recent increase in interest in measurement and estimation of FSS secant friction angle (FSS-ϕ′sec) to develop correlations for preliminary design and cost approximation. However, such correlations do not help in understanding the cause and effect relationship between soil properties and FSS-ϕ′sec. In this study, a laboratory database containing FSS-ϕ′sec values (output) and soil properties (inputs) of several overconsolidated clays is used to develop a predictive model for FSS-ϕ′sec (output or response). The goal is to detect which inputs from the whole parameter space dominate the response while creating an accurate prediction tool to provide statistical insights regarding the FSS-ϕ′sec. The proposed methodology is used to assess and quantify the relationships among variables, estimate testing device effects on FSS-ϕ′sec, and analyze the danger of extrapolation due to model constraints. The applicability of the predicted FSS-ϕ′sec is also evaluated and compared. Recommendations regarding the studied prediction tools for slope stability design in stiff-fissured clays are provided.

     

Intertidal boulder transport: A proposed methodology adopting Radio Frequency Identification (RFID) technology to quantify storm induced boulder mobility

Boulder transport is an area of growing interest to coastal scientists as a means of improving our understanding of the complex interactions between extreme wave activity and the evolution of rocky coasts. However, our knowledge of the response of intertidal boulder deposits to contemporary storm events remains limited due to a lack of quantifiable field-based evidence. We address this by presenting a methodology incorporating Radio Frequency Identification (RFID) tagging and Differential Global Positioning Navigation Satellite System (DGNSS) technology to monitor and accurately quantify the displacement of RFID tagged boulders resulting from storm wave activity. Based on preliminary findings we highlight the suitability of the technology and methodology to better understand the spatial and temporal response of intertidal boulders to contemporary storm events. We inserted RFID tags in 104 limestone boulders (intermediate axes from 0.27 to 2.85 m) across a range of morphogenic settings at two sites on the intertidal shore platforms at Bembridge, Isle of Wight (UK). Fifteen topographic surveys were conducted between July 2015 and May 2017 to relocate and record tagged boulder locations (tag recovery rate: 91%). The relocated boulder coordinate data from both sites identified 164 individual transport events in 63% of the tagged boulder array amounting to 184.6 m of transport, including the displacement of a boulder weighing more than 10 tonnes. Incidents of boulder quarrying and overturning during transport were also recorded, demonstrating that despite the relatively sheltered location, intertidal boulders are created and regularly transported under moderate storm conditions. This suggests that contemporary storm events have a greater propensity to mobilise boulders in the intertidal range than has previously been realised. Consequently, by documenting our methodology we provide guidance to others and promote further use of RFID technology to enable new hypotheses on boulder transport to be tested in a range of field settings and wave regimes. © 2018 John Wiley & Sons, Ltd.     

Regional beryllium-10 production rate calibration for late-glacial northeastern North America

The major uncertainty in relating cosmogenic-nuclide exposure ages to ages measured by other dating methods comes from extrapolating nuclide production rates measured at globally scattered calibration sites to the sites of unknown age that are to be dated. This uncertainty can be reduced by locating production rate calibration sites that are similar in location and age to the sites to be dated. We use this strategy to reconcile exposure age and radiocarbon deglaciation chronologies for northeastern North America by compiling ¹⁰Be production rate calibration measurements from independently dated late-glacial and early Holocene ice-marginal landforms in this region. ¹⁰Be production rates measured at these sites are 6–12% lower than predicted by the commonly accepted global ¹⁰Be calibration data set used with any published production rate scaling scheme. In addition, the regional calibration data set shows significantly less internal scatter than the global calibration data set. Thus, this calibration data set can be used to improve both the precision and accuracy of exposure dating of regional late-glacial events. For example, if the global calibration data set is used to calculate exposure ages, the exposure-age deglaciation chronology for central New England is inconsistent with the deglaciation chronology inferred from radiocarbon dating and varve stratigraphy. We show that using the regional data set instead makes the exposure age and radiocarbon chronologies consistent. This increases confidence in correlating exposure ages of ice-marginal landforms in northeastern North America with glacial and climate events dated by other means.     

In situ cosmogenic 10Be production-rate calibration from the Southern Alps,New Zealand

We present a ¹⁰Be production-rate calibration derived from an early Holocene debris-flow deposit at about 1000 m above sea level in the central Southern Alps, New Zealand, in the mid-latitude Southern Hemisphere. Ten radiocarbon ages on macrofossils from a soil horizon buried by the deposit date the deposit to 9690 ± 50 calendar years before AD2008. Surface ¹⁰Be concentrations of seven large boulders partially embedded in the stable surface of the deposit are tightly distributed, yielding a standard deviation of ～2%. Conversion of the ¹⁰Be measurements to sea level/high-latitude values using each of five standard scaling methods indicates ¹⁰Be production rates of 3.84 ± 0.08, 3.87 ± 0.08, 3.83 ± 0.08, 4.15 ± 0.09, and 3.74 ± 0.08 atoms g^?1 a^?1, relative to the ‘07KNSTD’ ¹⁰Be AMS standard, and including only the local time-integrated production-rate uncertainties. When including a sea level high-latitude scaling uncertainty the overall error is ～2.5% (1σ) for each rate. To test the regional applicability of this production-rate calibration, we measured ¹⁰Be concentrations in a set of nearby moraines deposited before 18 060 ± 200 years before AD2008. The ¹⁰Be ages are only consistent with minimum-limiting ¹⁴C age data when calculated using the new production rates. This also suggests that terrestrial in situ cosmogenic-nuclide production did not change significantly from Last Glacial Maximum to Holocene time in New Zealand. Our production rates agree well with those of a recent calibration study from northeastern North America, but are 12–14% lower than other commonly adopted values. The production-rate values presented here can be used elsewhere in New Zealand for rock surfaces exposed during or since the last glacial period.