Bioaugmentation and Propane Biosparging for In Situ Biodegradation of 1,4‐Dioxane

Propane biosparging and bioaugmentation were applied to promote in situ biodegradation of 1,4‐dioxane at Site 24, Vandenberg Air Force Base (VAFB), CA. Laboratory microcosm and enrichment culture testing demonstrated that although native propanotrophs appeared abundant in the shallow water‐bearing unit of the aquifer (8 to 23 ft below ground surface [bgs]), they were difficult to be enriched from a deeper water‐bearing unit (82 to 90 feet bgs). Bioaugmentation with the propanotroph Rhodococcus ruber ENV425, however, supported 1,4‐dioxane biodegradation in microcosms constructed with samples from the deep aquifer. For field testing, a propane‐biosparging system consisting of a single sparging well and four performance monitoring wells was constructed in the deep aquifer. 1,4‐dioxane biodegradation began immediately after bioaugmentation with R. ruber ENV425 (36 L; 4 × 10⁹ cells/mL), and apparent first‐order decay rates for 1,4‐dioxane ranged from 0.021 day^?1 to 0.036 day^?1. First‐order propane consumption rates increased from 0.01 to 0.05 min^?1 during treatment. 1,4‐dioxane concentrations in the sparging well and two of the performance monitoring wells were reduced from as high as 1090 µg/L to <2 µg/L, while 1,4‐dioxane concentration was reduced from 135 µg/L to 7.3 µg/L in a more distal third monitoring well. No 1,4‐dioxane degradation was observed in the intermediate aquifer control well even though propane and oxygen were present. The demonstration showed that propane biosparging and bioaugmentation can be used for in situ treatment of 1,4‐dioxane to regulatory levels.     

Pluto's light curve in 1933-1934

The Pluto-Charon system has complex photometric variations on all time scales; due to rotational modulations of dark markings across the surface, the changing orientation of the system as viewed from Earth, occultations and eclipses between Pluto and Charon, as well as the sublimation and condensation of frosts on the surface. The earliest useable light curve for Pluto is from 1953 to 1955 when Pluto was 35 AU from the Sun. Earlier data on Pluto has the potential to reveal properties of the surface at a greater heliocentric distance with nearly identical illumination and viewing geometry. We are reporting on a new accurate photographic light curve of Pluto for 1933-1934 when the heliocentric distance was 40 AU. We used 43 B-band and V-band images of Pluto on 32 plates taken on 15 nights from 19 March 1933 to 10 March 1934. Most of these plates were taken with the Mount Wilson 60″ and 100″ telescopes, but 7 of the plates (now at the Harvard College Observatory) were taken with the 12″ and 16″ Metcalf doublets at Oak Ridge. The plates were measured with an iris diaphragm photometer, which has an average one-sigma photometric error on these plates of 0.08 mag as measured by the repeatability of constant comparison stars. The modern B and V magnitudes for the comparison stars were measured with the Lowell Observatory Hall 1.1-m telescope. The magnitudes in the plate's photographic system were converted to the Johnson B- and V-system after correction with color terms, even though they are small in size. We find that the average B-band mean opposition magnitude of Pluto in 1933-1934 was 15.73±0.01, and we see a roughly sinusoidal modulation on the rotational period (6.38 days) with a peak-to-peak amplitude of 0.11±0.03 mag. With this, we show that Pluto darkened by 5% from 1933-1934 to 1953-1955. This darkening from 1933-1934 to 1953-1955 cannot be due to changing viewing geometry (as both epochs had identical sub-Earth latitudes), so our observations must record a real albedo change over the southern hemisphere. The later darkening trend from 1954 to the 1980's has been explained by changing viewing geometry (as more of the darker northern hemisphere comes into view). Thus, we now have strong evidence for albedo changes on the surface of Pluto, and these are most easily explained by the systematic sublimation of frosts from the sunward pole that led to a drop in the mean surface albedo.     

Elevated lateral stress in unlithified sediment, Midcontinent, United States—geotechnical and geophysical indicators for a tectonic origin

Indirect and direct geotechnical measurements revealed the presence of high lateral earth pressure (K_o) in shallow, unlithified sediment at a site in the northernmost Mississippi embayment region of the central United States. Results from pile-load and pressuremeter tests showed maximum K_o values greater than 10; however, the complex geologic environment of the Midcontinent made defining an origin for the anomalous K_o based solely on these measurements equivocal. Although in situ sediment characteristics indicated that indirect tectonic or nontectonic geologic mechanisms that include transient overburden loads (e.g., fluvial deposition/erosion, glacial advance/retreat) and dynamic shear loads (e.g., earthquakes) were not the dominant cause, they were unable to provide indicators for a direct tectonic generation. Localized stresses induced anthropogenically by the geotechnical field tests were also considered, but ruled out as the primary origin. A high-resolution shear-wave (SH) reflection image of geologic structure in the immediate vicinity of the test site revealed compression-style neotectonism, and suggested that the elevated stress was a tectonic manifestation. Post-Paleozoic reflectors exhibit a Tertiary (?) structural inversion, as evidenced by post-Cretaceous fault displacement and pronounced positive folds in the hanging wall of the interpreted faults. The latest stratigraphic extent of the stress effects (i.e., all measurements were in the Late Cretaceous to Tertiary McNairy Formation), as well as the relationship of stress orientation with the orientation of local structure and regional stress, remain unknown. These are the subjects of ongoing studies.     

Organic matter maturation under the influence of a deep intrusive heat source: A natural experiment for quantitation of hydrocarbon generation and expulsion from a petroleum source rock (Toarcian shale, northern Germany)

Four shallow boreholes were drilled in the Hils syncline, northern Germany, in order to determine quantitatively the amount of hydrocarbons generated and expelled during maturation of a typical kerogen-type-II-bearing source rock. The holes penetrated the carbonceous Lias shales (Posidonia shale, Lower Toarcian) and part of the adjacent Dogger α and Lias δ mudstones. The maturity of the organic matter in the cores recovered ranges from immature (0.48% R̄₀) to overmature 1.45% R̄₀) due to location of the Hils syncline in the vicinity of the Vlotho Massif, which is deep-seated intrusive body. Facies variations of the Lias within the short geographical distances in the study area are negligible.Organic matter mass balance calculations were based on detailed organic geochemical analyses of residual material in the Lias shales (kerogen, bitumen etc.) and on the evidence of a uniform initial composition of these sediments in the study area. Dead carbon determinations supported this latter criterion but were not used as a parameter in the calculations.About 50% of the initial kerogen was transformed into oil, gas and inorganic compounds during the vitrinite reflectance increase from 0.48 to 0.88% R̄_o and only marginally more during the maturity increase from 0.88 to 1.45% R̄_o. Only a small portion of the generated material remained in the source rock even at a relatively early stage of generation (0.68% R̄_o). Expulsion efficiency of oil plus gas reached a value of 86% at the end of the main generation stage (0.88% R̄_o).     

Seismo-engineering parameters for sites of interim storages for spent nuclear fuel at German nuclear power plants

Within the scope of the licensing procedure for 12 interim storage facilities for spent nuclear fuel at nuclear power plants (NPP) and one for the dismantling of a NPP in Germany, site-specific expert reports were carried out to determine seismo-engineering design parameters. Our work was based on the German nuclear safety standard KTA 2201 part 1 “Design of Nuclear Power Plants against Seismic Events” which requires the derivation of the design earthquake in terms of (macroseismic) intensity. The intensity of the particular design earthquake was evaluated by the deterministic method stipulated in KTA 2201 part 1. According to the current state-of-the-art of science and technology supplementary to the deterministic approach, probabilistic evaluations were done setting a probability of exceedance for the occurrence of the design earthquake of 10⁻⁵ year⁻¹. Geological development and neotectonic conditions of the site surrounding areas were included in the evaluations. For 13 interim storage facility sites, soil-dependent design spectra and corresponding strong-motion duration values were determined.For sites with low seismic hazard site-specific design spectra from the literature were used. In the case of sites with higher seismic hazard (design earthquakeVII 1/2 MSK) strong-motion registrations representative for the site were selected from world wide data and subsequently evaluated to derive site-specific design spectra.     

Thermal–mechanical modeling of cooling history and fracture development in inflationary basalt lava flows

Thermal–mechanical analyses of isotherms in low-volume basalt flows having a range of aspect ratios agree with inferred isotherm patterns deduced from cooling fracture patterns in field examples on the eastern Snake River Plain, Idaho, and highlight the caveats of analytical models of sheet flow cooling when considering low-volume flows. Our field observations show that low-volume lava flows have low aspect ratios (width divided by thickness), typically < 5. Four fracture types typically develop: column-bounding, column-normal, entablature (all of which are cooling fractures), and inflation fractures. Cooling fractures provide a proxy for isotherms during cooling and produce patterns that are strongly influenced by flow aspect ratio. Inflation fractures are induced by lava pressure-driven inflationary events and introduce a thermal perturbation to the flow interior that is clearly evidenced by fracture patterns around them. Inflation fracture growth occurs incrementally due to blunting of the lower tip within viscoelastic basalt, allowing the inflation fracture to pivot open. The final stage of growth involves propagation beyond the blunted tip towards the stress concentration at the tapered tip of a lava core, resulting in penetration of the core that causes quenching of the lava and the formation of a densely fractured entablature. We present numerical models that include the effects of inflation fractures on lava cooling and which support field-based inferences that inflation fractures depress the isotherms in the vicinity of the fracture, cause a subdivision of the lava core, control the location of the final portion of the lava flow to solidify, and cause significant changes in the local cooling fracture orientations. In addition to perturbing isotherms, inflation fractures cause a lava flow to completely solidify in a shorter amount of time than an identically shaped flow that does not contain an inflation fracture.     

Interferometry in the era of time-domain astronomy

The physical nature of time variable objects is often inferred from photometric light-curves and spectroscopic variations. Long-baseline optical interferometry has the power to resolve the spatial structure of time variable sources directly in order to measure their physical properties and test the physics of the underlying models. Recent interferometric studies of variable objects include measuring the angular expansion and spatial structure during the early stages of novae outbursts, studying the transits and tidal distortions of the components in eclipsing and interacting binaries, measuring the radial pulsations in Cepheid variables, monitoring changes in the circumstellar discs around rapidly rotating massive stars, and imaging starspots. Future applications include measuring the image size and centroid displacements in gravitational microlensing events, and imaging the transits of exoplanets. Ongoing and upcoming photometric surveys will dramatically increase the number of time-variable objects detected each year, providing many potential targets to observe interferometrically. For short-lived transient events, it is critical for interferometric arrays to have the flexibility to respond rapidly to targets of opportunity and optimize the selection of baselines and beam combiners to provide the necessary resolution and sensitivity to resolve the source as its brightness and size change. We discuss the science opportunities made possible by resolving variable sources using long baseline optical interferometry.     

2004年4月1日磁通量传输事件特性的研究——通量管内电流密度、粒子运动与管轴方向的对比分析

本文利用Cluster四颗卫星上磁通门磁力计(FGM)的同时观测,采用旋度器方法(Curlometer),计算和分析了2004年4月1日12:24到12:54UT期间Cluster卫星观测的多个磁通量传输事件(FTEs)的特性。结果表明:磁通量管内电流密度较大,可达到约10-7A/m2。应用最小方向微分法(MDD),发现这些FTE事件具有准二维结构,即为圆柱形结构,其通量管轴线方向与管内电流方向及粒子运动方向基本平行。