Cement Deep Soil Mixing (CDSM) for Solidification of Soft Estuarine Sediments

A preliminary study was conducted to determine the potential for cement deep soil mixing (CDSM) technology as a method for in-situ solidification of contaminated river and estuarine sediments. The study was conducted in Newark Bay, near the mouth of the Passaic River, New Jersey. The primary objective of the study was to evaluate the viability of CDSM for the in-situ S/S with a focus on: 1) determining the correct mix of the cement slurry, which provides rapid stabilization of the sediment matrix, 2) potential resuspension of solids during CSDM operations, 3) the effects of high organic content on the solidification process, and 4) the feasibility of using conventional dredging/extraction methods once the sediments have been stabilized and allowed to cure. The results of the study show CDSM slurry mixtures, as low as 7% in cement content, result in significant solidification and strength gain of in-situ sediments under ambient conditions. In sediments with very high organic contents (> 20%), the slurry mix would need to be adjusted to account for retardation effects of organics on cement hydration. Sediment resuspension during application was shown to be minimal at a distance of as little as 75 feet from the mixing head. Strength gains were considerable, effectively consolidating the sediment particles in a secure matrix, but not so high as to preclude extraction of solidified sediments with conventional dredging equipment. Dredged solidified sediment exhibited characteristics of a stiff glacial clay, and as such was easier to handle and transport than untreated dredged sediments. This technique has high potential to be used as an interim remedial measure prior to either extraction and decontamination/disposal or proper capping.     

Field-Scale Evaluation of Bioaugmentation Dosage for Treating Chlorinated Ethenes

A field demonstration was performed to evaluate the impacts of bioaugmentation dosage for treatment of chlorinated ethenes in a sandy-to-silty shallow aquifer. Specifically, bioaugmentation using a commercially available Dehalococcoides (DHC)-containing culture was performed in three separate groundwater recirculation loops, with one loop bioaugmented with 3.9 × 10¹¹ DHC, the second loop bioaugmented with 3.9 × 10¹² DHC, and the third loop bioaugmented with 3.9 × 10¹³ DHC. Groundwater monitoring was performed to evaluate DHC growth and migration, dechlorination rates, and aquifer geochemistry. The loop inoculated with 3.9 × 10¹² DHC showed slower dechlorination rates and DHC migration/growth compared with the other loops. This relatively poor performance was attributed to low pH conditions. Results for the loops inoculated with 3.9 × 10¹¹ and 3.9 × 10¹³ DHC showed similar timeframes for dechlorination, as evaluated at a monitoring well approximately 10 feet downgradient of the DHC injection well. Application of a recently developed one-dimensional bioaugmentation fate and transport screening model provided a reasonable prediction of the data in these two loops. Overall, these results suggest that increasing bioaugmentation dosage does not necessarily result in decreased dechlorination timeframes in the field. The ability to predict results suggests that modeling potentially can serve as an effective tool for determining bioaugmentation dosage and predicting overall remedial timeframes.     

New insights into the size and timing of the Lawn Hill impact structure: relationship to the Century Zn – Pb deposit

The Lawn Hill circular structure in northwest Queensland contains unambiguous evidence of an extraterrestrial impact, including planar deformation features in quartz, impact diamonds, widespread shatter cone formation and impact melt breccia in the Mesoproterozoic basement. The question of its relevance to ore genesis is investigated because the world-class Century Zn – Pb deposit is situated at the conjunction of the 100+ km Termite Range Fault and the previously defined margin of the impact structure. The impact structure is considered to be a 19.5 km wide feature, this constrained in part by the outer margin of an annulus of brecciated and highly contorted limestone. New evidence is presented indicating impact into this Cambrian limestone, including: (i) ‘dykes’ of brecciated Cambrian limestone extending hundreds of metres into the Mesoproterozoic basement; (ii) highly contorted bedding in the limestone annulus compared with essentially undeformed limestone away from the impact site; as well as (iii) a 1 Mt megaclast of Mesoproterozoic Century-like ore suspended in the limestone. Through aerial photograph analysis, large-scale convoluted flow structures within the limestone are identified, and these are interpreted to indicate that parts of the Cambrian sequence may have been soft or only semi-consolidated at the time of impact. This highly contorted limestone bedding is suggested to represent slump-filling of an annular trough in response to impact-induced partial liquefaction of a sediment veneer. The age of impact is therefore considered to be concurrent with limestone formation during the Ordian to early Templetonian, at 520 – 510 Ma. Formation of the Century deposit is found to be unrelated to impact-generated hydrothermal activity, although some minor hydrothermal remobilisation of metals occurred. However, there was macro-scale remobilisation of gigantic ore fragments driven by impact-induced lateral and vertical injection of limestone into the Proterozoic sediments. The limestone-filled annular trough surrounds a 7.8 km diameter central uplift, consistent with formation of a complex crater morphology.     

COBE observations of the microwave counterpart of GRBs

We have used the data from the COBE satellite to search for delayed microwave emission (31 - 90 GHz) from Gamma Ray Bursts (GRBs). The large 7° beam of COBE is well matched to the large positional uncertainties in the GRB locations, although it also means that fluxes from (point source) GRB objects will be diluted. In view of this we are doing a statistical search of the GRBs which occurred during the currently released COBE DMR data (years 1990 and 1991), which overlap 200 GRBs recorded by GRO. Here we concentrate on just the top 10 GRBs (in peak counts/second). We obtain the limits on the emission by comparing the COBE fluxes before and after the GRB at the GRB location. Since it is thought that the microwave emission should lag the GRB event, we have searched the GRB position for emission in the few months following the GRB occurrence.     

Comparison of neutron and X-ray diffraction in texture analysis of deformed carbonate rocks

The paper compares pole figure determinations with neutron diffraction and X-ray diffraction on experimentally deformed carbonate rocks, a coarse grained marble and fine grained limestone. Neutron diffraction enables determination of complete pole figures on a single spherical specimen and is advantageous for coarse grained materials. Results obtained with both diffraction techniques agree satisfactorily, although uncertainties introduced by counting statistics are more serious for neutrons than for X-rays. Continuous detectors add new possibilities which are still little explored.     

Long‐Term Impacts on Groundwater and Reductive Dechlorination Following Bioremediation in a Highly Characterized Trichloroethene DNAPL Source Area

High‐resolution soil and groundwater monitoring was performed to assess the long‐term impacts of bioremediation using bioaugmentation with a dechlorinating microbial consortium (and sodium lactate as the electron donor) in a well‐characterized trichloroethene (TCE) dense nonaqueous phase liquid (DNAPL) source area. Monitoring was performed up to 3.7 years following active bioremediation using a high‐density monitoring network that included several discrete interval multi‐level sampling wells. Results showed that despite the absence of lactate, lactate fermentation transformation products, or hydrogen, biogeochemical conditions remained favorable for the reductive dechlorination of chlorinated ethenes. In locations where soil data showed that TCE DNAPL sources persisted, local contaminant rebound was observed in groundwater, whereas no rebound or continuous decreases in chlorinated ethenes were observed in locations where DNAPL sources were treated. While ethene levels measured 3.7 years after active treatment suggested relatively low (2 to 30%) dechlorination of the parent TCE and daughter products, carbon stable isotope analysis showed that the extent of complete dechlorination was much greater than indicated by ethene generation and that the estimated first‐order rate constant describing the complete dechlorination of TCE at 3.7 years following active bioremediation was approximately 3.6 y–1. Overall, results of this study suggest that biological processes may persist to treat TCE for years after cessation of active bioremediation, thereby serving as an important component of remedial treatment design and long‐term attenuation.     

Quantification of contemporary storm-induced boulder transport on an intertidal shore platform using radio frequency identification technology

Extreme storm events are known to produce, entrain, transport and deposit sizable boulders along rocky coastlines. However, the extent to which these processes occur under moderate, fetch-limited wave conditions is seldom considered. In this study we quantify boulder transport at a relatively sheltered location subject to high-frequency, low-magnitude storm activity. This was achieved by deploying radio frequency identification (RFID) tags within 104 intertidal limestone boulders ranging in size from fine to very coarse (intermediate axis: 0.27–2.85 m). The study was conducted over 3 years (July 2015–July 2018) and encompassed numerous storm events. Tagged boulders were relocated during 17 field surveys and their positions recorded using a differential global positioning navigation satellite system (DGNSS). On completion, we identified boulder displacement in 69% of the tagged array. The accrued boulder transport distance amounted to 233.0 m from 195 incidents of displacement, including the movement of a boulder weighing an estimated 11.9 t. Transport was not confined to autumn and winter storms alone, as displacement was also recorded during summer months (April–September), despite the seasonally reduced wave magnitude. Boulder production by wave quarrying was documented in three tagged clasts, confirming observations that the shore platform is actively eroding. Incidents of overturning during transport were also recorded, including multiple overturning of clasts weighing up to 5 t. We further identify a statistically significant difference (maximum p-value ≤ 0.03) between the transport distances attributed to constrained and unconstrained boulders, suggesting that the pre-transport morphological setting exerts considerable control over boulder transport potential. The findings establish low to moderate storm waves as a key component in the evolution of the study site. More broadly, we claim that high-frequency, low-magnitude storms regularly modify these overlooked rocky coastal locations, suggesting that the hydrodynamic capability at such sites may previously have been underestimated. © 2020 John Wiley & Sons, Ltd.     

Application of 1013 Ω Amplifiers in Low‐Signal Plasma‐Source Isotope Ratio Measurements by MC‐ICP‐MS: A Case Study with Pt Isotopes

Recent developments in amplifier hardware enable low‐noise measurements of exceedingly small ion beams in isotope ratio analysis, yielding higher precision from smaller samples than ever before. To date, these amplifiers have largely been employed in thermal ionisation instruments, with few applications using plasma‐source (i.e., MC‐ICP‐MS) instruments. Here, we demonstrate the utility of these new generation 10¹³ Ω amplifiers in MC‐ICP‐MS, employing Pt isotopes as a case study, a system that could greatly benefit from the promised advances. The data demonstrate that for samples with low Pt abundance, for a modest increase in uncertainties, the amount of sample required can be reduced by a factor of 50–100. This technique thereby opens up new possibilities for analysis of samples that have low Pt mass fractions or were otherwise impossible to obtain in sufficient quantities.     

Preliminary 10Be chronology for the last deglaciation of the western margin of the Greenland Ice Sheet

The now acknowledged thinning of the Greenland Ice Sheet raises concerns about its potential contribution to future sea level rise. In order to appreciate the full extent of its contribution to sea level rise, reconstruction of the ice sheet's most recent last deglaciation could provide key information on the timing and the height of the ice sheet at a time of rapid climate readjustment. We measured ¹⁰Be concentrations in 12 samples collected along longitudinal and altitudinal transects from Sisimiut to within 10 km of the Isunguata Sermia Glacier ice margin on the western coast of Greenland. Along the longitudinal transect, we collected three perched boulders and two bedrocks. In addition, we sampled seven perched boulders along a vertical transect in a valley within 10 km of the Isunguata Sermia Glacier ice margin. Our pilot dataset constrains the height of the ice sheet during the Last Glacial Maximum (LGM) between 500 m and 840 m (including the 120 m relative sea level depression at the time of the LGM, 21 ka BP). From the transect we estimate the thinning of the ice sheet at the end of the deglaciation between 12.3 ± 1.5 ¹⁰Be ka (n = 2) and 8.3 ± 1.2 ¹⁰Be ka (n = 3) to be ～6 cm a^?1 over this time period. Direct dating of the retreat of the western margin of the Greenland Ice Sheet has the potential to better constrain the retreat rate of the ice margin, the thickness of the former ice sheet as well as its response to climate change. Copyright © 2008 John Wiley & Sons, Ltd.     

Galactic mass determinations from incomplete rotation curves

Given an incomplete rotation curve of a spiral galaxy, various assumptions about the Galaxy beyond the last observed point are made: (A) the force falls off as 1/r ², (B) the mass density is zero, and (C) the mass density falls off as 1/r ³. The msss distributions obtained from each of these assumptions are all well behaved, and it is impossible to choose the correct curve from considerations of the resulting mass distributions alone. The correct mass distribution in the disk system of a galaxy cannot be deduced from an incomplete rotation curve.