Uranium speciation and stability after reductive immobilization in aquifer sediments

It has generally been assumed that the bioreduction of hexavalent uranium in groundwater systems will result in the precipitation of immobile uraninite (UO₂). In order to explore the form and stability of uranium immobilized under these conditions, we introduced lactate (15 mM for 3 months) into flow-through columns containing sediments derived from a former uranium-processing site at Old Rifle, CO. This resulted in metal-reducing conditions as evidenced by concurrent uranium uptake and iron release. Despite initial augmentation with Shewanella oneidensis, bacteria belonging to the phylum Firmicutes dominated the biostimulated columns. The immobilization of uranium (∼1 mmol U per kg sediment) enabled analysis by X-ray absorption spectroscopy (XAS). Tetravalent uranium associated with these sediments did not have spectroscopic signatures representative of U-U shells or crystalline UO₂. Analysis by microfocused XAS revealed concentrated micrometer regions of solid U(IV) that had spectroscopic signatures consistent with bulk analyses and a poor proximal correlation (μm scale resolution) between U and Fe. A plausible explanation, supported by biogeochemical conditions and spectral interpretations, is uranium association with phosphoryl moieties found in biomass; hence implicating direct enzymatic uranium reduction. After the immobilization phase, two months of in situ exposure to oxic influent did not result in substantial uranium remobilization. Ex situ flow-through experiments demonstrated more rapid uranium mobilization than observed in column oxidation studies and indicated that sediment-associated U(IV) is more mobile than biogenic UO₂. This work suggests that in situ uranium bioimmobilization studies and subsurface modeling parameters should be expanded to account for non-uraninite U(IV) species associated with biomass.     

Experimental evidence of ion plasma oscillations in the apogee region of the Nike-Apache rocket

Several Nike-Apache rockets with Lang muir probe payloads were launched from Thumba (India) to study the disturbances produced by a moving rocket. The rockets were launched during different times of the day and night. It was found that low frequency ion plasma oscillations of the order of 1 KHz frequency were observed in the altitude region 145 to 200 km. This altitude region corresponds to the rocket apogee region where the rocket velocity is subsonic. The amplitude of the fluctuations was about 1 to 2% and was found to be dependant on rocket velocity electron density in the ambient medium, rocket spin and probe voltage. It was noticed that in the case of Centaure and Petrel rockets such types of oscillations were not observed. The Nike-Apache rockets are made of aluminium while Centaure and Petrel rockets are made of stainless steel.     

Non-radial oscillations in an axisymmetric MHD incompressible fluid

It is well known from Helioseismology that the Sun exhibits oscillations on a global scale, most of which are non-radial in nature. These oscillations help us to get a clear picture of the internal structure of the Sun as has been demonstrated by the theoretical and observational (such as GONG) studies. In this study we formulate the linearised equations of motion for non-radial oscillations by perturbing the MHD equilibrium solution for an axisymmetric incompressible fluid. The fluid motion and the magnetic field are expressed as scalarsU, V, P andT, respectively. In deriving the exact solution for the equilibrium state, we neglect the contribution due to meridional circulation. The perturbed quantitiesU *, V *, P *, T * are written in terms of orthogonal polynomials. A special case of the above formulation and its stability is discussed.     

Large-scale precipitation estimation using Kalpana-1 IR measurements and its validation using GPCP and GPCC data

Large-scale precipitation estimation is very important for climate science because precipitation is a major component of the earth's water and energy cycles. In the present study, the GOES precipitation index technique has been applied to the Kalpana-1 satellite infrared (IR) images of every three-hourly, i.e., of 0000, 0300, 0600,??., 2100?hours UTC, for rainfall estimation as a preparatory to the INSAT-3D. After the temperatures of all the pixels in a grid are known, they are distributed to generate a three-hourly 24-class histogram of brightness temperatures of IR (10.5?C12.5???m) images for a 1.0°?×?1.0° latitude/longitude box. The daily, monthly, and seasonal rainfall have been estimated using these three-hourly rain estimates for the entire south-west monsoon period of 2009 in the present study. To investigate the potential of these rainfall estimates, the validation of monthly and seasonal rainfall estimates has been carried out using the Global Precipitation Climatology Project and Global Precipitation Climatology Centre data. The validation results show that the present technique works very well for the large-scale precipitation estimation qualitatively as well as quantitatively. The results also suggest that the simple IR-based estimation technique can be used to estimate rainfall for tropical areas at a larger temporal scale for climatological applications.     

Increasing trend of northeast monsoon rainfall over the equatorial Indian Ocean and peninsular India

Peninsular India and Sri Lanka receive major part of their annual rainfall during the northeast monsoon season (October–December). The long-term trend in the northeast monsoon rainfall over the Indian Ocean and peninsular India is examined in the vicinity of global warming scenario using the Global Precipitation Climatology Project (GPCP) dataset available for the period 1979–2010. The result shows a significant increasing trend in rainfall rate of about 0.5 mm day^?1 decade^?1 over a large region bounded by 10 °S–10 °N and 55 °E–100 °E. The interannual variability of seasonal rainfall rate over peninsular India using conventional rain gauge data is also investigated in conjunction to the Indian Ocean dipole. The homogeneous rain gauge data developed by Indian Institute of Tropical Meteorology over peninsular India also exhibit the considerable upward rainfall trend of about 0.4 mm day^?1 decade^?1 during this period. The associated outgoing longwave radiation shows coherent decrease in the order of 2 W?m^?2 decade^?1 over the rainfall increase region.     

On anomalously high sub-surface dissolved oxygen in the Indian sector of the Southern Ocean

The Southern Ocean (SO) plays a critical role in global ocean productivity and carbon cycling. Bio-Argo floats deployed in the Indian sector of the Southern Ocean provides new insights into the biogeochemical processes. Here we report significantly higher dissolved oxygen(DO) (~?310 μmol/kg) in summer of 2014–2015 for one float (F1) and winter of 2014 in other float (F2) at sub-surface layer in the subantarctic region of the SO. The summer DO peak in F1 was 10% higher than those during the summer of succeeding year, while the winter DO peak in F2 was 20% higher than those during the winter of succeeding year. Temperature and dynamic height structure show that cyclonic eddies play an important role in the observed increase in the dissolved oxygen: the high DO is a manifestation of the co-occurrence of a cold core eddy which transported the cold oxygen rich water from deep to the surface during winter, while, during summer, the high chlorophyll below the mixed layer depth (MLD) also contributed to the elevated DO. Low apparent oxygen utilisation suggests that the observed high oxygen concentration was due to high production rates over the consumption.

     

Relationship between northeast monsoon rainfall and near-surface atmospheric wind convergence over the North Indian Ocean using multisatellite data

The northeast monsoon rainfall (NEMR) contributes about 20–40 % of annual rainfall over the North Indian Ocean (NIO). In the present study, the relationship between the NEMR and near-surface atmospheric wind convergence (NSAWC) over the NIO is demonstrated using high-resolution multisatellite data. The rainfall product from the Tropical Rainfall Measuring Mission Multisatellite Precipitation Analysis and near-surface wind product from the Cross-Calibration Multi-Platform available at 0.25° × 0.25° spatial resolution are used for the study. Large-scale NSAWC and divergence maps over the tropical Indian Ocean are generated at monthly scale from the wind product for the period of 1988–2010. A preliminary analysis is carried out for two consecutive anomalous Indian Ocean Dipole (IOD) years 2005 (negative) and 2006 (positive). The distinct spatial patterns of rainfall rate and NSAWC fields over the NIO clearly show the evolution of the anomalous IOD events in the south eastern equatorial Indian Ocean (EEIO). The spatially averaged time-series of pentad NSAWC over the south EEIO box suggests that the variability occurs in phase with rainfall rate during both the northeast monsoon years. Furthermore, the scatter plot between area-averaged pentad rainfall and convergence over the south EEIO box for the period of 1998–2010 shows statistically significant linear correlation which reveals that NSAWC plays a key role in regulating the NEMR.