Diel Patterns in Chlorophyll <Emphasis Type="Italic">a</Emphasis> Specific Absorption Coefficient and Absorption Efficiency Factor of Picoplankton

Diel patterns in the chlorophyll a specific absorption coefficient of surface picoplankton, a*_pico (γ) (m²·[mg chlorophyll a]⁻¹), were studied at 7 stations under daily cycle of in situ light condition in the western subarctic Pacific and Japan Sea. All the data were normalized by dividing the anomaly with daily averaged a*_pico (γ). Opposite diel patterns were observed for the normalized a*_pico (443) and a*_pico (675) with maximum toward dawn or dusk and minimum toward midday at 4 stations under low-irradiance (LI) conditions and vice versa at 3 stations under high-irradiance (HI) conditions. The absorption efficiency factors at red absorption peak, Q _a (675), were determined by reconstruction with intracellular chlorophyll a concentration and cell diameter. The normalized Q _a (675) also showed diel pattern with maximum toward midday and minimum toward dawn or dusk under LI. The diel pattern in a*_pico (675) and Q _a (675) were primarily caused by changes in intracellular chlorophyll a concentration due to photoadaptation under LI. The diel pattern in a*_pico (443) was influenced by pigmentation, as recognized by blue to red ratio [a*_pico (443)/a*_pico (675)] under HI. This study proposed that the opposite diel pattern in a*_pico (γ) might occur for a wide range of algal species. The results presented here have important consequences for the interpretation of diel variations in optical properties observed in the open ocean.     

Lunar photometric properties at wavelengths 0.5-1.6 μm acquired by SELENE Spectral Profiler and their dependency on local albedo and latitudinal zones

The lunar photometric function, which describes the dependency of the observed radiance on the observation geometry, is used for photometric correction of lunar visible/near-infrared data. A precise photometric correction parameter set is crucial for many applications including mineral identification and reflectance map mosaics. We present, for the first time, spectrally continuous photometric correction parameters for both sides of the Moon for wavelengths in the range 0.5-1.6 μm and solar phase angles between 5° and 85°, derived from Kaguya (SELENE) Spectral Profiler (SP) data. Since the measured radiance also depends on the surface albedo, we developed a statistical method for selecting areas with relatively uniform albedos from a nearly 7000-orbit SP data set. Using the selected data set, we obtained empirical photometric correction parameter sets for three albedo groups (high, medium, and low). We did this because the photometric function depends on the albedo, especially at phase angles below about 20° for which the shadow hiding opposition effect is appreciable. We determined the parameters in 160 bands and discovered a small variation in the opposition effect due to the albedo variation of mafic mineral absorption. The consistency of the photometric correction was checked by comparing observations made at different times of the same area on the lunar surface. Variations in the spectra obtained were lower than 2%, except for the large phase angle data in mare. Lastly, we developed a correction method for low solar elevation data, which is required for high latitude regions. By investigating low solar elevation data, we introduced an additional correction method. We used the new photometric correction to generate a 1° mesh global lunar reflectance map cube in a wavelength range of 0.5-1.6 μm. Surprisingly, these maps reveal that high latitude (?75°) regions in both the north and south have much lower spectral continuum slopes (color ratio r_1547.7nm/r_752.8nm ? 1.8) than the low and medium latitude regions, which implies lower degrees of space weathering.     

Regional 3-D heterogeneities by waveform inversion – application to the Atlantic area

The waveform inversion method described in Woodhouse & Dziewonski (1984) was modified to retrieve regional scale 3-D heterogeneities by using the minor arc part of seismograms. The lateral heterogeneities are expanded horizontally into blocks (10°× 10°) and radially into Legendre polynomials up to order 3 (0–670 km), and thus the results show much fine details of lateral variation than previous global scale studies. We assumed that the heterogeneities produce the perturbation of eigenfrequencies which are the minor arc average of local eigenfrequency shift. We applied the method to the upper mantle beneath the Atlantic Ocean and its environments. Care was taken about the weighting of the data set. We found that the fit of each seismogram became better when the weighting of each seismogram is proportional to the inverse of initial data residuals. Resolution is good in the triangular region surrounded by South America, Europe, and North America. Resolution is not good in the South Atlantic because of the poor path coverage. Depth resolution is not clear, because of the use of Legendre polynomials, though the results suggest a broad half-width of the order of 200 km or more. We found some similarities between previous global studies and our results. For example, low velocities beneath the East Pacific Rise, Chile Rise and Azores triple junction and a high velocity Canadian shield are obtained. However, there are also differences; the high-velocity zone beneath the Brazilian shield at shallow depth is not a prominent feature in this study. Instead, we found a somewhat unexpected feature near the Romanche and Vema fracture zones where shallow positive anomalies exist. Smoothed results calculated by the spherical harmonic expansion are also shown for the purpose of comparison with global studies.     

Numerical simulations of mantle flow around slab edges

A simple kinematic-dynamic model of mantle flow around the slab-edge is constructed in order to understand the flow complexity there. The flow velocity on the top and the small boundary region around the shallow plate boundary is kinematically imposed in order to achieve a subduction-like feature and the flow in other part is dynamically calculated. The geometry of the plate mimics the region around the junction of Aleutian Islands and Kamchatka, that are examples of the convergent-transform fault plate boundaries. In a simple model in which the overlying plate is almost stationary, the lateral flow from the mantle under the subducting slab to the mantle under the neighboring plate is of minor importance, once the slab penetrates into the high viscosity layer where the downward flow encounters the resistance. Similar situation was found when the trench is advancing, that is, the trench moves toward the overlying plate. For the case with retreating trench, that is, the trench moves toward the subducting plate, a lateral flow exists even after the slab penetrates into the high viscosity layer, although its magnitude is significantly smaller than that of the plate velocity. The presence of a low viscosity layer just beneath the subducting plate may promote the emergence of lateral flow. A significant lateral flow is observed when the high temperature anomaly, that is, buoyant and low viscosity block carried by the movement of subducting plate, approaches the slab. These results may have important implications for the possible existence of trench parallel flow in the sub-slab mantle.     

Degradation and utilization of protein derived from <Emphasis Type="Italic">Pseudomonas aeruginosa</Emphasis> by marine microbial community

Microbial degradation and utilization of proteins derived from bacterial detritus were investigated in a microcosm experiment using Pseudomonas aeruginosa detritus as a substrate. To assess the effects of natural marine microbial communities on degradation and utilization of protein derived from P. aeruginosa cells, four microcosms were prepared: natural seawater (containing the natural microbial community) with P. aeruginosa detritus (N+Pa), autoclaved seawater with P. aeruginosa detritus (A+Pa), natural seawater (N) and autoclaved seawater (A) without adding anything as a control. The numbers of total and growing bacterial cells, protease activity, and transition of P. aeruginosa proteins were monitored in the four microcosms. Changes in the numbers of total and growing bacterial cells and protease activities indicated that bacterial detritus significantly stimulated the microbial community in the microcosms. Both the surviving P. aeruginosa in A+Pa and natural microbial community in N+Pa microcosms were able to degrade and utilize P. aeruginosa detritus; however, the community in N+Pa including various microbes maintained high activity longer, indicating that diversity is an important factor in keeping the community active. Even under the very high protease activity in N+Pa, 39-kDa and 48-kDa proteins from P. aeruginosa remained in the microcosm during the entire experiment (150 days). Immunoblotting suggested the 48-kDa protein was an intact molecule of OprP, which had been detected from the dissolved fraction of natural seawater in previous studies. This result suggests that the protein molecules that had been detected from natural seawater actually had a high tolerance to microbial degradation.     

Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.     

Seasonal variation in the transport of suspended matter in the East China Sea

Seasonal variation in the transport of suspended matter across the East China Sea is investigated with the use of results of field observations and diagnostic numerical experiments. Suspended matter is transported from the shelf edge to the inner shelf in summer and from the inner shelf to the shelf edge in autumn and winter due to the vertical circulation mainly induced by the monsoon wind. The maximum transport of suspended matter from the inner shelf to the shelf edge occurs in autumn.     

Sound velocity and density of liquid Ni68S32 under pressure using ultrasonic and X-ray absorption with tomography methods

A new experimental setup for simultaneous P-wave velocity (V_P) and density (ρ) measurements for liquid alloys is developed using ultrasonic and X-ray absorption methods combined with X-ray tomography at high pressures and high temperatures. The new setup allows us to directly determine adiabatic bulk moduli (K_S) and to discuss the correlation between the V_P and ρ of the liquid sample. We measured V_P and ρ of liquid Ni₆₈S₃₂ up to 5.6 GPa and 1045 K using this technique. The effect of pressure on the V_P and ρ values of liquid Ni₆₈S₃₂ is similar to that of liquid Fe₅₇S₄₃. (Both compositions correspond to near-eutectic ones.) The obtained K_S values are well fitted to the finite strain equation with a $K_{{\text{S}}_0}$ value (K_S at ambient pressure) of 31.1 GPa and a dK_S/dP value of 8.44. The measured V_P was found to increase linearly with increasing ρ, as approximated by the relationship: V_P [m/s] = 1.29 ρ [kg/m³] – 5726, suggesting that liquid Ni–S follows an empirical linear relationship, Birch's law. The dV_P/dρ slope is similar between Ni₆₈S₃₂ and Fe₅₇S₄₃ liquids, while the V_P–ρ plot of liquid Ni–S is markedly different from that of liquid Fe–S, which indicates that the effect of Ni on Birch's law is important for understanding the V_P–ρ relation of planetary and Moon's molten cores.     

Seasonal variation of circulations in the East China Sea and the Yellow Sea

Seasonal variation of the water circulations in the East China Sea and the Yellow Sea is investigated with use of a robust diagnostic numerical model. Water circulations in four season are calculated diagnostically from the observed water temperature and salinity data from JODC (Japan Oceanographic Data Center) and wind data from COADS (Comprehensive Ocean-Atmosphere Data Set). Counter-clockwise circulations are developed at the upper and middle layers and a clockwise one at the lower layer in the central part of he Yellow Sea in summer. On the other hand, a clockwise circualtion is developed from the surface to the bottom in the Yellow Sea and a counter-clockwise one in, the northern part of the East China Sea in winter.