Cation distribution in pentlandites (Fe,Ni)9S8: Dependence on pressure and temperature and kinetics of the cation exchange reaction

This paper describes the distribution of Fe and Ni between the octahedral and tetrahedral sites in pentlandite (Fe,Ni)₉S₈. The dependence of the distribution on pressure and temperature and the activation energy of the cation exchange reaction were determined through annealing experiments. Synthetic crystals were annealed at 433–723 K and pressures up to 4 GPa, and natural crystals were annealed at 423, 448 and 473 K in evacuated silica capillary tubes for various durations. The cation distributions in the synthetic crystals were determined with an X-ray powder method employing the anomalous dispersion effect of CuK. and FeK radiations, while those of natural crystals were calculated from the cell dimensions. The values of U, S and V for the Fe/Ni exchange reaction are –6818 J mol^–1, 20.52 J K^–1 mol^–1, and 6.99 × 10^–6 m³ mol^–1, respectively. The dependence of the Fe/Ni distribution on pressure (Pa) and temperature (Kelvin) was determined as lnK = 2.47+8.20 × 10² T ^–1+8.41 x 10^–7 T ^–1 P, where K = (Fe/Ni)_octahedral /(Fe/Ni)_tetrahedral. The activation energy of the cation exchange reaction was 185 kJ mol^–1.     

Determination of the electromagnetic field produced by a magnetic oblique-rotator

The electromagnetic field produced by a magnetic dipole moment, , which is rotating obliquely surrounded by a corotating plasma sphere, is investigated. This corotating-plasma approximation has the same order of accuracy as the force-free one but has somewhat different physical implications. In the former the effect of non-electromagnetic forces such as the inertial force are included, though in somewhat artificial manner, as a departure from the strict MHD condition and this fact seems to guarantee the existence of physical solutions.Analogous to the relativistic force-free equation, a set of two differential equations (the corotation equation) are derived for the scalar functions associated with the electric and magnetic fields. A self-consistent solution of these equations is given and it is shown that this solution has no singularity, in spite of apparent divergence in the formal solution, on the light cylinder. It is concluded from this solution that, even in the extreme case of the largest possible corotation-radius (i.e.b=r _L , wherer _L is the light radius), the existence of a corotating plasma does not alter the field structure drastically from the vacuum case. It is also suggested through this treatment that inclusion of the inertial term in generalized Ohm's law might be essential in considering the centrifugal-wind problem.     

Controlled experiment in the ionosphere with a rocket-borne plasma gun

A controlled active experiment was performed by a plasma gun on-board a rocket to study the plasma stream across the magnetic field in space. A mother and daughter system was employed. An 8 kV 0.8 μF (25 J) capacitor bank on the daughter rocket was discharged every 12 s and about 10¹⁶ ion and electron pairs were ejected. A plasma signal was detected on the electron temperature probe. The propagation speed of the plasma stream is estimated to be 10⁶ cm/s, considerably lower than that obtained in the prelaunch test. The amplitude of the plasma signal decays as the inverse square of the mutual distance between the mother and daughter rockets and this decay is much slower than the free streaming. The importance of the geomagnetic field on the plasma propagation in space is discussed.     

Remote sensing parameterization of the processes of energy and water cycle over desertification areas

In order to understand the processes of land surface-atmosphere interaction over desertification area, it is indispensable to utilize of satellite remote sensing. Two scenes of Landsat TM were used to produce a set of maps of surface reflectance, MSAVI, vegetation coverage, surface temperature, net radiation, soil heat flux, sensible heat flux and latent heat flux. Statistical analysis based on these maps revealed some quantitative significant land surface characteristics. Future developments of the method are also discussed.     

GPS-measured land subsidence in Ojiya City, Niigata Prefecture, Japan

Land subsidence caused by compression of clay layers in Ojiya City, Japan was measured by global positioning system (GPS) between 1 April 1996 and 31 December 1998.

Three baselines were selected in and around the city, and height difference on a WGS-84 ellipsoid was measured by GPS on each baseline. The ground at the GPS station in the city subsides and rebounds 7 cm every winter and spring, respectively. Measurement accuracy was 9.5 mm standard deviation. Ground water level was observed at a well near the GPS station. Regression analysis between total strain, calculated as ratio of the height difference displacement to the total thickness of the clay layers, and the layers' effective stress change with ground water level change gave good correlation. The slope of regression line 7.0×10⁻¹¹ m²/N was obtained as an average apparent coefficient of volume compressibility of the layers.     

Internal Microanatomy and Zoological Affinity of the Early Cambrian Olivooides

The early Cambrian pentamerous microfossil Olivooides/Punctatus in South China, which is characterized by a diagnostic stellate tubular apex, has been well-known for its almost complete development sequence that can be confidently traced from embryos and hatched juveniles, to conical adults. However, its zoological affinity remains highly controversial. Here we describe the internal microanatomic structures of the soft-body inside the peridermal theca of Olivooides multisulcatus Qian, 1977, including interradial pairs of tentacles, adradial and perradial frenula, perradial oral marginal lappets and twins of perradial gastric saccule-like humps as well as a circular velarium with striated coronal muscles. Particularly, one specimen shows bifurcated velarial canals along the bell aperture. Both the components of the soft-body and the external theca (or cyst) are arranged in perfect pentaradial symmetry. These characteristics are more compatible with those of living cubomedusans and co-occurring Cambrian athecate embryonic cubozoans. Concerning the presence of peridermal theca, Olivooides most likely represents an extinct thecate stem-group cubomedusae but devoid of both perradial eyes and specialized pedalia. The well-grown soft body inside the peridermal tube displays a set of mixed features of both polyp and medusa.     

Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.     

Dynamical downscaling of future sea level change in the western North Pacific using ROMS

The future regional sea level (RSL) rise in the western North Pacific is investigated by dynamical downscaling with the Regional Ocean Modeling System (ROMS) with an eddy-permitting resolution based on three global climate models—MIROC-ESM, CSIRO-Mk3.6.0, and GFDL-CM3—under the highest greenhouse-gas emission scenario. The historical run is forced by the air-sea fluxes calculated from Coordinated Ocean Reference Experiment version 2 (COREv2) data. Three future runs—ROMS-MIROC, ROMS-CSIRO, and ROMS-GFDL—are forced with an atmospheric field constructed by adding the difference between the climate model parameters for the twenty-first and twentieth century to fields in the historical run. In all downscaling, the RSL rise along the eastern coast of Japan is generally half or less of the RSL rise maxima off the eastern coast. The projected regional (total) sea level rises along the Honshu coast during 2081–2100 relative to 1981–2000 are 19–25 (98–104), 6–15 (71–80), and 8–14 (80–86) cm in ROMS-MIROC, ROMS-CSIRO, and ROMS-GFDL, respectively. The discrepancies of the RSL rise along the Honshu coast between the climate models and downscaling are less than 10 cm. The RSL changes in the Kuroshio Extension (KE) region in all downscaling simulations are related to the changes of KE (northward shift or intensification) with climate change.