Interstadial coral reef terraces and relative sea-level changes during marine oxygen isotope stages 3–4, Kikai Island, central Ryukyus, Japan

Coral reef terraces are one of the best recorders of relative sea-level changes during the last glacial cycle. Thus far, knowledge of relative sea-level record based on coral reefs during the marine Oxygen Isotope Stage (OIS) 3 has been limited to studies of the Huon Peninsula, Papua New Guinea. High-precision a α-spectrometric ²³⁰Th/²³⁴U dating demonstrated an offlapping sequence of five coral reef complexes, ages of which are 66, 64, 62, 55 and 52 ka, in the northern part of Kikai Island, central Ryukyus of Japan. Interstadial reefs, characterized by deepening-upward sequences of coral assemblages, recorded three hemicycles from transgression to highstand at 52, 62, and 66 ka, during which these reefs were drowned. These highstands in the relative sea-level record can be correlated with the eustatic record reconstructed from the Huon reef terraces and with the interstadials 14, 18, and 19 of the GISP 2 oxygen isotope record. This consistency confirms the Huon sea-level record of OIS 3 and implies that the eustatic sea level responded to the millennial-scale climate changes even during the glacial period of OIS 4.     

Uranium and Thorium Isotope Distribution in an Offshore Bottom Sediment Core of the Selenga Delta, Lake Baikal, Siberia

Distribution of uranium and thorium isotopes in a short sediment core obtained offshore of the Selenga Delta in Lake Baikal, Siberia, was investigated to establish their sedimentary behaviors and to look for a linkage to paleoenvironmental changes. The sediments were composed of dominantly fine detrital materials (70–85%) and a relatively high sedimentation rate (ca. 0.03 cm y⁻¹). The depth profile of ²³⁸U content in bulk sediment samples showed a large variation of 70–123 Bq kg⁻¹, while ²³²Th profile showed a relatively narrow range from 36 to 56 Bq kg⁻¹. The observed ²³⁴U/²³⁸U activity ratios revealed a marked disequilibrium ranging from 1.53 to 1.84 with a mean value of 1.71 ± 0.07, demonstrating the presence of 50–80% authigenic ²³⁸U in the bulk sediments. The distribution of this authigenic ²³⁸U did not display any clear correlation with variations in sediment composition (organic, carbonate, Bio-SiO₂ and mineral contents) including grain size median. The profile of terrigenous ²³⁸U showed a relatively similar pattern to that of ²³²Th. Results of sequential leaching indicate that ²³⁸U in Fe–Mn oxyhydroxides fractions were responsible for the distribution of authigenic ²³⁸U rather than in Bio-SiO₂ fraction. The distribution of authigenic ²³⁸U in the bottom sediments may be explained by the fluctuation of U adsorption capacity on particles including organic matter and Fe–Mn oxyhydroxides before they entered the lake. This study highlights the potential use of authigenic and terrigenous U (Th) signatures in sediments to trace the behavior of U (Th) and to reconstruct environmental (e.g., hydrological) changes in the lake catchment area.     

230Th/234U and 14C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.     

Phase F,a new hydrous magnesium silicate synthesized at 1000 °C and 17 GPa: Crystal structure and estimated bulk modulus

The structure of phase F, a non-stoichiometric hydrous silicate synthesized in a uniaxial, split-sphere, multi-anvil apparatus at conditions of 17 GPa and 1000° C, has been solved and refined in space group P6₃cm, using synchrotron X-ray data for a single crystal of a size 18 × 24 × 30 μm. The composition and unit cell for phase F are Mg_3.35Si_5.51H_7.26O₁₈, a=5.073(3) Å, c=14.013(9) Å, 7= 312.3(5) ų. The structure contains layers with many similarities to superhydrous phase B. The layers of oxygen atoms are stacked in the ABCBAC-type double cubic closest packing arrangement. The bulk modulus of phase F was estimated from the structural and compositional relationship to superhydrous phase B and periclase.     

The dust distribution in some smallHII regions

Based on the calibrated maps in the Hα andV bands, simple shell models for the distributions of ionized gas and dust are calculated for the smallHii regions S237 and S254–S257. In deriving the dust distribution from theV-band maps, it is assumed that scattering particles are made of dirty ice. The results of calculation show that a dust depletion zone should be placed in the central region of each of the observedHii regions. The formation of this dust depletion zone and the evolutionary state of theseHii regions are briefly discussed.     

Petrographic features of a high-temperature granite just newly solidified magma at the Kakkonda geothermal field, Japan

A 3729-m-deep geothermal research well, WD-1a, provides us with a unique opportunity to study initial petrographic features of a high-temperature granite just after solidification of magma. The well succeeded in collecting three spot-cores of the Kakkonda Granite that is a pluton emplaced at a shallow depth and regarded as a heat source of the active Kakkonda geothermal system. The core samples were collected at the present formation temperatures of 370, 410 and over 500°C. These samples are granodiorite to tonalite consisting mainly of plagioclase, quartz, hornblende, biotite and K-feldspar. A sample collected at a formation temperature of over 500°C possesses the following remarkable petrographic features compared to the other two samples. Interstitial spaces are not completely sealed. K-feldspar exhibits no perthite by the exsolution of albite lamella. Quartz includes glassy melt inclusions without devitrification. Hornblende is less intensively altered to actinolite, and biotite is not altered. This study directly confirmed that perthite in K-feldspar is a recrystallization texture formed at 410–500°C based on a comparison of the in situ temperatures of the samples. Chemical compositions of minerals were analyzed to compare temperatures determined from geothermometers in several publications to the in situ temperatures of the samples.     

Influence of non-photosynthetic pigments on light absorption and quantum yield of photosynthesis in the western equatorial Pacific and the Subarctic North Pacific

Regional variations in the contribution of non-photosynthetic pigments (ā _np^*) to the total light absorption of phytoplankton (ā _ph^*) and its influence on the maximum quantum yield of photosynthesis (φ _m) were investigated. In the western equatorial Pacific, the surface ā _np^* : ā _ph^* ratio was higher in the western warm pool than that in the upwelling region. This difference appears to be attributable to severe nitrate depletion and higher percentage of prokaryotes, which can accumulate very high concentrations of zeaxanthin in the western warm pool. In the subarctic North Pacific, the ā _np^* : ā _ph^* ratio was expected to be higher in the Alaskan Gyre where the thermocline is sharper and iron limitation may possibly be more severe than in the Western Subarctic Gyre. However, the ratio was actually higher in the Western Subarctic Gyre, contradictory to our expectations. This east-west variation appears to be attributable to changes in the taxonomic composition; cyanobacteria were more abundant in the Western Subarctic Gyre. The values of ā _np^* : ā _ph^* and its vertical variations were relatively small in the subarctic North Pacific compared to those in the western equatorial Pacific. These inter-regional variations appear to be attributable to the lower solar radiation intensity, smaller percentage of cyanobacteria, and relatively strong vertical mixing in the subarctic North Pacific. The spatial variations in ā _np^* : ā _ph^* significantly influence φ _m. In comparison with φ _m based on the total light absorption (φ _{m ph}), the values corrected for the contribution of non-photosynthetic pigments (φ _{m ps}) showed an increase in both the western equatorial Pacific and the subarctic North Pacific.     

Impact of vertical mixing induced by small vertical scale structures above and within the equatorial thermocline on the tropical Pacific in a CGCM

Oceanic vertical mixing is known to influence the state of the equatorial ocean which affects the climate system, including the amplitude of El Niño/Southern Oscillation (ENSO). Recent measurements of ocean currents at high vertical resolution capture numerous small vertical scale structures (SVSs) within and above the equatorial thermocline that contribute significantly to vertical mixing but which are not sufficiently resolved by coarse resolution ocean models. We investigate the impact of the vertical mixing induced by the SVSs on the mean state and interannual variability in the tropical Pacific by using a coupled general circulation model. The vertical mixing induced by the SVSs is represented as an elevated vertical diffusivity from the surface down to the 20 °C isotherm depth, a proxy for the depth of the thermocline. We investigate different forms for the elevated mixing. It is found that the SVS-induced mixing strongly affect the mean state of the ocean leading to a warming of sea surface temperature (SST) and associated deepening and sharpening of the thermocline in the eastern equatorial Pacific. We find that the SST warming induced by the elevated mixing is further strengthened through the Bjerknes feedback and SST-shortwave flux feedback. We also find a reduction in the number of large amplitude ENSO events and in certain cases an increase in the skewness of ENSO.     

Mineralogy and petrography of C asteroid regolith: The Sutter's Mill CM meteorite

Based upon our characterization of three separate stones by electron and X‐ray beam analyses, computed X‐ray microtomography, Raman microspectrometry, and visible‐IR spectrometry, Sutter's Mill is a unique regolith breccia consisting mainly of various CM lithologies. Most samples resemble existing available CM2 chondrites, consisting of chondrules and calcium‐aluminum‐rich inclusion (CAI) set within phyllosilicate‐dominated matrix (mainly serpentine), pyrrhotite, pentlandite, tochilinite, and variable amounts of Ca‐Mg‐Fe carbonates. Some lithologies have witnessed sufficient thermal metamorphism to transform phyllosilicates into fine‐grained olivine, tochilinite into troilite, and destroy carbonates. One finely comminuted lithology contains xenolithic materials (enstatite, Fe‐Cr phosphides) suggesting impact of a reduced asteroid (E or M class) onto the main Sutter's Mill parent asteroid, which was probably a C class asteroid. One can use Sutter's Mill to help predict what will be found on the surfaces of C class asteroids such as Ceres and the target asteroids of the OSIRIS‐REx and Hayabusa 2 sample return missions (which will visit predominantly primitive asteroids). C class asteroid regolith may well contain a mixture of hydrated and thermally dehydrated indigenous materials as well as a significant admixture of exogenous material would be essential to the successful interpretation of mineralogical and bulk compositional data.