The influence of multiple diffraction on the space group determination of orthopyroxene,spodumene, low omphacite and pigeonite

Forbidden reflections of some pyroxenes described as having a lower symmetry than Pbca or C2/c have been examined, mainly using the detailed ψ-scanning method of the four-circle automated diffractometer. All reflections violating the systematic absences of Pbca orthopyroxene, C2/c spodumene, P2/n omphacite and P2₁/c pigeonite were found to be due to the Umweganregung process of multiple diffraction; the Umweganregung peaks observed for the ψ azimuth were indexed in terms of a four-circle geometry. Thus, the space groups of orthopyroxene, α spodumene, low omphacite and low pigeonite were confirmed to be Pbca, C2/c, P2/n and P2₁/c, respectively.     

Effects of a physical librations of the moon caused by a liquid core,and determination of the fourth mode of a free libration

An analytical theory of lunar physical librations based on its two-layer model consisting of a non-spherical solid mantle and ellipsoidal liquid core is developed. The Moon moves on a high-precision orbit in the gravitational field of the Earth and other celestial bodies. The defined fourth mode of a free libration is caused by the influence of the liquid core, with a long period of 205.7 yr, with amplitude S = 0″0395 and with an initial phase Π₀ = ?134° (for the initial epoch 2000.0). Estimates of dynamic (meridional) oblatenesses of a liquid core of the Moon have been estimated: ?_D = 4.42 × 10^?4, μ_D = 2.83 × 10^?4 (?_D + μ_D = 7.24 × 10^?4). These results have been obtained as a result of comparison of the developed analytical theory of physical librations of the Moon with the empirical theory of librations of the Moon constructed on the basis of laser observations.     

Estimation of urban heat island intensity using biases in surface air temperature simulated by a nonhydrostatic regional climate model

This study demonstrates that urban heat island (UHI) intensity can be estimated by comparing observational data and the outputs of a well-developed high-resolution regional climate model. Such an estimate is possible because the observations include the effects of UHI, whereas the model used does not include urban effects. Therefore, the errors in the simulated surface air temperature, defined as the difference between simulated and observed temperatures (simulated minus observed), are negative in urban areas but 0 in rural areas. UHI intensity is estimated by calculating the difference in temperature error between urban and rural areas. Our results indicate that overall UHI intensity in Japan is 1.5 K and that the intensity is greater in nighttime than in daytime, consistent with the previous studies. This study also shows that root mean square error and the magnitude of systematic error for the annual mean temperature are small (within 1.0 K).     

Characterization of drying-induced deformation behaviour of Opalinus Clay and tuff in no-stress regime

The drying-induced deformation behaviour of Opalinus Clay and tuff, which are being investigated under international and local collaborative projects for nuclear waste disposal in Switzerland and Japan, was investigated under a no-stress condition in the laboratory to evaluate their generic susceptibility to the formation of excavation damaged zone. The cylindrical core samples of Opalinus Clay and tuff were prepared to a one-dimensional drying condition and submitted to an uncontrolled laboratory environment. The strain evolution, evaporative water loss and environmental entities, such as temperature and relative humidity, were recorded simultaneously and quasi-continuously. It was observed that the drying phase induced significant strain magnitude and damage in Opalinus Clay samples, which was evidenced by the formation of hairy cracks on the surface parallel to the bedding. On the contrary, the strain occurrences in tuff samples were relatively insignificant, and no tendency of cracking was observed. In addition, the quasi-continuous availability of volumetric strains was further used in poroelastic relation for the estimation of capillary suction evolution. The calculated results were validated with pore size distributions obtained from mercury intrusion porosimetry.