Evaluation of the budget for silicic acid in Cascadia Basin deep water

Between 2 and 3 km depth, North Pacific deep waters contain a plume of water with high silicic acid concentrations. The plume extends outward from Cascadia Basin (the Washington Margin), where waters can contain in excess of 200 μM off the coast of Oregon and Washington. To identify the source of the high Si concentrations in Cascadia Basin, we measured silicic acid and germanium concentrations in deep waters, and their fluxes from sediments using incubated cores. The mean flux of silicic acid into bottom waters is 0.81±0.05 mmol/m²-day, and the Ge/Si ratio of this flux is 0.7±0.1 μmol/mol. A box model, incorporating these results with hydrographic data, indicates that (1) no more than 5% of the silicic acid added to Basin deep waters can have a hydrothermal source (either hot or warm seeps), and (2) the total input of silicic acid to Basin deep waters is 0.06±0.02 Tmol/y. This input is nearly all from remineralized biogenic debris and should contribute about 0.5% of the 14 Tmol/y that are estimated to be necessary to maintain the North Pacific plume.     

Theoretical plasma distributions consistent with Ulysses magnetic field observations in a solar wind tangential discontinuity

The overall multi-layer structure of the magnetic field profile observed by Ulysses across a broad solar wind tangential discontinuity can be reproduced fairly well by means of a kinetic model. Such a simulation provides complementary information about the velocity distribution functions, which are not always available from the plasma experiment due to the low time resolution inherent in plasma measurements. The success of such a simulation proves that the kinetic model can be used as a realistic basis for further studies of the structure and stability of solar wind tangential discontinuities.     

Archaean lode gold mineralisation in banded iron formation at the Kalahari Goldridge deposit, Kraaipan Greenstone Belt, South Africa

The Kalahari Goldridge Mine is located within the Archaean Kraaipan Greenstone Belt, about 60 km southwest of Mafikeng in the North West Province, South Africa. The ore body thickness varies from 15 to 45 m along a strike length of about 1.5 km within approximately N–S striking banded iron formation (BIF). The stratabound ore body is hosted primarily by BIF, which consists of alternating chert and magnetite–chlorite–stilpnomelane–sulphide–carbonate bands of millimetre- to centimetre scale. A footwall of sericite–carbonate–chlorite schist underlain by mafic amphibolite occurs to the west and carbonaceous metapelites in the hanging wall to the east. Overlying the hanging wall, carbonaceous metapelites, units of coarse-grained metagreywackes fining upwards, become increasingly conglomeratic up the stratigraphy. Small-scale isoclinal folds, brecciation, extension fractures and boudinage of cherty BIF units reflect brittle-ductile deformation. Fold axial planes have foliation, with subvertical plunges parallel to prominent rodding and mineral lineation in the footwall rocks. Gold mineralisation is associated with two generations of quartz–carbonate veins, dipping approximately 20° to 40° W. The first generation consists of ladder-vein sets (group IIA) preferentially developed in centimetre-scale Fe-rich mesobands, whereas the second generation consists of large quartz–carbonate veins (group IIB), which locally crosscut the entire ore body and extend into the footwall and hanging wall. The ore body is controlled by mesoscale isoclinal folds approximately 67° E, orthogonal to the plane of mineralised, gently dipping veins, defining the principal stretching direction and development of fluid-focussing conduits. The intersections of the mineralised veins and foliation planes of the host rock plunges approximately 08° to the north. Pervasive hydrothermal alteration is characterised by chloritisation, carbonatisation, sulphidation and K-metasomatism. Gold is closely associated with sulphides, mainly pyrite and pyrrhotite, and to a lesser extent, with bismuth tellurides and carbonate minerals. Mass balance transfer calculations indicate that hydrothermal alteration of BIF involved enrichment of Au, Ag, Bi, Te, S and CO₂ (LOI), MgO, Ba, K and Rb, but significant depletion of SiO₂ and, to a lesser extent, Fe₂O₃. Extensive replacement of magnetite and chlorite in BIF and other pelitic sedimentary rocks by sulphide and carbonate minerals, both on mesoscopic and microscopic scales, is evidence of interaction of CO₂- and H₂S-bearing fluids with the Fe-rich host rocks. The fineness of gold grains ranges from 823 to 921, similar to that of other epigenetic Archaean BIF-hosted gold deposits, worldwide.     

The calculation of the statistical counting error for 222Rn scintillation counting

The calculation of the statistical counting error for alpha-scintillation counting of²²²Rn is complicated by the fact that two of the short-lived daughter products of²²²Rn are alpha emitters. All observed daughter-product counts attributable to parent decays that have already been detected must be excluded in the calculation of this error. An equation is derived which takes this into consideration.     

The use of carbon and sulfur isotopes as correlation parameters for the source identification of beach tar in the southern California borderland

Carbon and sulfur isotope ratios and total sulfur content are used to correlate beach tars depositing near Los Angeles with their probable sources. Analysis is confined strictly to the asphaltene fraction of petroleum owing to the insensitivity of this fraction to weathering processes.The δ¹³C, δ³⁴S and % S of the asphaltene fraction of natural offshore seep oils range from ?22.51 to ?23.20%., +7.75 to + 15.01%. and 4.45 to 8.27%, respectively. Values for local offshore production wells overlapped those for the natural seepage, ranging from ?22.10 to ?22.85%., ?2.96 to 13.90%., and 0.81 to 8.00%. Analytical values for these parameters show that tanker crudes imported into the area are not similar to the California oils. Analysis of the same parameters in beach tars collected during 1976–1977 indicates a close match with the potential source oils, thus it is concluded that these parameters are useful for identifying petroleum sources, even after 2–4 weeks of weathering. Results indicate that 55% of the tars in Santa Monica Bay are derived from natural oil seepage 150km to the northwest at Coal Oil Point, 26% are derived from natural oil seepage in Santa Monica Bay, and 19% are derived from unknown sources.Models of tar transport are inferred which are consistent with the seasonal deposition pattern. Tar from Coal Oil Point natural oil seeps is transported southward in the southern California gyre during the spring, summer and fall seasons, but probably undergoes northward transport during the winter season due to the surfacing of the Davidson Current. Tar from the Santa Monica Bay natural oil seeps moves onshore, but deposition rate seems to depend on seepage flow rate.     

Geochemistry and petrogenesis of Proterozoic diabase in the southern Death Valley region of California

Diabase sills and dikes of Proterozoic age intrude crystalline basement and the overlying Crystal Spring Formation in the southern Death Valley region of California. Despite pervasive deuteric alteration, analyses of relict plagioclase (An_66-45), titaniferous augite, and ilmenite permit the calculation of initial crystallization temperatures of 1,165±25° C for plagioclase and 1,110±25° C for augite with an oxygen fugacity of 10^–11 atm. The early crystallization of plagioclase is consistent with the generally subophitic texture of the diabase.Geochemical arguments show that deuteric alteration has had little effect on the whole rock chemistry which has a mildly alkaline, transitional character. Mathematical models support the interpretation that chemical variations are principally the result of flow differentiation. Also, about 15 to 25% olivine or augite may have fractionated from the melt prior to intrusion. The mildly LREE enriched composition (normalized La/Yb=4.27 to 6.13) is best modelled by a 5% melt fraction from a moderately LREE-enriched source. Melt derived from a model garnet peridotite with accessory amphibole is compatible with the observed major and trace element chemistry. The diabase is compositionally akin to other middle Proterozoic basaltic rocks in North America which formed in extensional settings, and it is interpreted as a manifestation of widespread extensional tectonism.     

The chemistry of sublimates collected directly from lava fountains at Kilauea Volcano,Hawaii

During 1970, it was occasionally feasible to collect sublimate from directly above the lava fountain in the crater of Mauna Ulu on the east rift zone of Kilauea Volcano, when the level of the lava pool had dropped within the crater. Collecting equipment was suspended down the steep wall to a position above the fountain. Collections were made on quartz wool held within open-ended quartz tubes and, for silica detection, on stainless steel wool in a stainless steel tube. The main components in the sublimate were, in order of decreasing concentration for the best sample, Na, Ca, Al, Fe, Mg, K, B, Si, Ti, Zn, H⁺, NH₄⁺, Cu, Ni in the form of sulfates, chlorides and fluorides.In order to investigate the forms in which the sublimate ions occur under different conditions of temperature and oxidation, the equilibrium compositions of the compounds most likely to be present were calculated. This was done for those important components for which thermodynamic data are available, using a computer program to calculate the minimum free energy for the mixture. The results indicate that, for primary conditions of high temperature and low oxygen partial pressure, the halides were the most likely form of the metallic compounds. Particulate sulfates appear under increasing oxidizing conditions caused by the access of air. These conclusions were reinforced by collections made from holes drilled through the thin crust of a lava lake formed during the same eruption.     

Gulf stream ground truth project: Results of the NRL airborned sensors

Results of an airborne study of the waves in the Gulf Stream are presented. These results show that the active microwave sensors (high-flight radar and wind-wave radar) provide consistent and accurate estimates of significant wave height and surface wind speed, respectively. The correlation between the wave height measurements of the high-flight radar and a laser profilometer is excellent.