Effects of water-borne copper on metallothionein and lipid peroxidation in the marine amphipod Gammarus locusta

The aim of the current work was to determine over 10 days the effects of water-borne exposure of the marine amphipod Gammarus locusta to 4 microgCu l(-1) on the metallothionein (MT; measured by differential pulse polarography) protection system and lipid peroxidation (LP: thiobarbituric acid-reactive malondialdehyde equivalents) as a measure of oxidative damage. MT levels in exposed animals increased significantly at day 2 (36% > control; P < 0.001) and remained high at days 6 and 10 (55 and 38%, respectively, P < 0.001). The maximum level of MT at day 6 coincided with the highest Cu body-burden. LP increased within I day of exposure, indicative of Cu as an oxidative stressor. However, in contrast to MT, the highest LP level was seen at day 4 (68% > control, P < 0.001) before returning to control values by day 6, indicating a protective role of MT against the pro-oxidant effects of Cu.     

Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO₃ with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L^− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L^− 1 and 0.1 nmol L^− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO₃ + HCl, followed by H₂O₂, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used.     

Morphology and structure of the Galapagos Rise

Geophysical data collected on three U.S. Naval Oceanographic Office cruises to the Galapagos Rise are presented. These data allow definition of the morphology and structure of the Galapagos Rise.A postulated “hot spot” beneath the Galapagos platform is suggested as the cause of: (1) decreased seismicity along the spreading center for a 400 km E—W distance from the islands; (2) distinctive petro-chemistry of tholeiites from the islands and adjacent oceanic crust generated by the Galapagos Rise; (3) high-amplitude magnetic anomalies in a 1,000 km E—W band including and just north of the Galapagos platform; and (4) morphologic shape and the regionally elevated sea floor of the Galapagos Rise as it approaches the insular platform.     

32Si dating of sediments from Lake Baikal

We applied the ³²Si dating technique to a sediment core from Lake Baikal to obtain the sediment chronology for the last millennium. The core was recovered about 4 km offshore from the north slope of the South Basin in 1,366 m water depth. The sediment material consisted of continuously accumulated diatom-rich geogenic-terrigenous mud, intercalated with a number of dark olive-grey turbidite layers. The sediment layers containing the turbidites were excluded from ³²Si sampling to obtain the chronology that is representative of the continuous sedimentation. The initial ³²Si activity of 31.3 dpm kg^?1 SiO₂, measured in sediment trap samples, confirms the trend of ³²Si specific activities of biogenic silica found in other Northern Hemisphere lakes. The four sediment core samples from depth 0–48 cm have ³²Si specific activities between 23.5 and 0.5 dpm kg^?1 SiO₂, with corresponding ages between 60 and 860 years and constant sedimentation rate of 0.036 ± 0.004 cm year^?1 over the most recent 800 years. ³²Si allowed us for the first time to date the uppermost turbidites in the South Basin of Lake Baikal, to 1030, 1310 and 1670 ad. Given these dates, the last long-distance turbidity current triggered by slope instabilities had occurred 330 years before 2000 ad, and the intervals between the 1310 and 1670 ad event and between the 1030 and 1310 ad event were 360 and 280 years, respectively. The ³²Si ages allow unprecedented time resolution for reconstruction of the former environmental and climatic conditions during the past millennium.     

Late Cainozoic geology,soils, and landscape evolution of the Torrens Creek area,North Queensland

The major features of the geology and geomorphology of the semi‐arid, tropical Torrens Creek area of North Queensland are described. The evolution of the landscape through the late Cainozoic is discussed with reference to three phases of landscape instability and erosion, each separated by phases of stability during which weathering and soil formation proceeded. These erosional periods were probably initiated by episodic uplift of the Great Divide region. Tentative correlations with landscape events in the nearby Nulla Basalt Province suggest that soil profile development probably occurred during late Pliocene (2.3–2.0 m.y. ago), mid‐Pleistocene (1.3–1.1 m.y. ago), and in Quaternary (less than 0.1 m.y. ago) times.     

A cost–benefit appraisal of coastal managed realignment policy

European coasts are coming under increasing threat as a result of climate change from erosion and flooding. While coastal defences such as sea walls have been constructed since Roman times to protect human settlements from the sea, it is now increasingly recognised that these defences are unsustainable. The security provided by ‘hard’ engineered defences has encouraged development on the coast, and the defences themselves have led to the loss of intertidal habitat and the natural protection it provides.An alternative to maintaining ‘hard’ defences (hold-the-line) to protect land from increasing sea levels is managed realignment, where the engineered defences are deliberately breached. By allowing the coastline to recede to a new line of defence further inland, intertidal habitat is created providing natural protection from flooding and erosion.The study evaluates the economic efficiency—using cost–benefit analysis—of various managed realignment scenarios compared to a strategy of holding-the-line within the Humber estuary in North-east England. The results of this analysis show that managed realignment can be more economically efficient than holding-the-line over a sufficiently long time period—generally greater than 25 years. Sensitivity analysis demonstrates that results are more sensitive to the amount and value of intertidal habitat generated than they are to the amount and value of carbon stored by this habitat. Cost–benefit analysis is viewed as one component of a wider policy appraisal process within integrated coastal management.     

Evidence for long-term asymmetries in the Earth's magnetic field and possible implications for dynamo theories

Paleomagnetic data indicate that there is a north-south asymmetry in the time-averaged magnetic field and that there are small but significant differences between the normal and reverse polarity states. The geographical variation is most likely due to spatial variation in the boundary conditions at the core-mantle interface. The difference in the magnetic fields of the reverse and normal polarity states can be modeled in terms of a “standing field”. The paleomagnetic data are insufficient to determine whether or not this “standing field” is of core origin. However, consideration of mechanisms, including thermoelectric currents, indicates that there probably are important differences in core processes between the two polarity states. At first glance this interpretation is difficult to reconcile with the fact that the magnetic induction equation is antisymmetric with respect to the magnetic field. A way around this problem is the possibility that only certain transitions are allowed between acceptable eigenstates in dynamo models of the Earth's magnetic field.     

Structure,Matter Composition,and Deep Structure of the Oceanic Slope of the Central Kuril Islands: New Evidence

The results of reinterpretation of the geophysical data obtained during the study of the central sector of the Kuril Island Arc (2005–2010) are reported. The new boundaries of the shallow bedding of the basement and its block uplifts of varied composition are defined within the previously discovered zone of tectonic stretching and destruction of the Vityaz submarine ridge and interarc trough. Interblock depressions filled with sedimentary and volcanogenic-sedimentary rocks are distinguished. Areas represented by volcanoplutonic complexes including basic and sialic series (up to granite) are distinguished within the unbroken basement of the Vityaz Ridge. Intrusions and volcanic edifices composed of basic rocks are registered on the whole area studied. The relationship between the formation of the destruction zone and the geodynamic processes in the mantle is illustrated by the map of the Moho relief and structural-density model of the Earth’s crust.     

Coseismic and other short-term strain changes recorded with Sacks-Evertson strainmeters in a deep mine, South Africa

Summary. During 1977 March and April, three Sacks-Evertson borehole dilatometers were installed at the ends of boreholes drilled into the sidewall of an experimental tunnel at a depth of 3.1 km in the ERPM gold mine near Johannesburg. In the following year coseismic strain changes ranging from 5 ± 10⁻¹⁰ to values exceeding 5 ± 10⁻⁶ were recorded for hundreds of mine tremors in the magnitude range -1 to 3.7 and at hypocentral distances of 50 m to about 2 km. Hypocentral coordinates and magnitudes were determined from seismograms recorded from an underground array of geophones. Amplitudes and polarities of the coseismic strain steps are generally in excellent agreement with theoretical expectations based on point-source dislocation theory; specifically, the strain steps are proportional to the seismic moment divided by the cube of hypocentral distance. At a strain level of 5 ± 10⁻⁹ or greater the tremors do not appear to be preceded by any short-term indications of instability even for tremors producing coseismic steps greater than 5 ± 10⁻⁶ and for which the strainmeters were within a source radius of the hypocentre. Continuous strain changes observed at the times when the mine excavation, at a distance of about 100 m, is extended are in good agreement with calculated changes based on the theory of elasticity. A similar calculation is consistent with post-seismic strain changes observed to follow some of the closer tremors. These post-seismic strains show a logarithmic dependence on time following the tremor and appear to be due to the interaction of a tremor with the adjacent mine excavation rather than to deformation within the actual seismic source region.     

A note on a non-stationary model for seismic P-waves

Further evidence supporting a non-stationary model for seismic P-waves from underground nuclear explosions are given. Results of fitting this model are compared with findings of Töksoz, Ben-Menaheim and Harkrider (1964) and Helmberger and Harkrider (1972). A method of studying dependence of the principle parameters of this model on yield of event is briefly discussed.