Response of estuarine meio- and macrofauna to in situ bioremediation of oil-contaminated sediment

Numerous studies have demonstrated the efficacy of bioremediation for enhancing oil removal but the ecological effect on shoreline biota is unclear. Therefore, a field experiment was designed at an intertidal sandflat in SW England to assess the effects of nutrient addition to oiled sediments on meio- and macrofauna for a period of up to 45 weeks. Natural assemblages were exposed to different types of experimental treatments (no oil, oil alone, oil treated with slow-release fertiliser or liquid fertiliser). Bioremediation stimulated the microbial population and increased oil biodegradation. This, however, did not result in faster recolonisation rates of fertilised versus non-fertilised oiled sediments. Mild effects of oil and bioremediation treatments on benthic fauna were observed, including short-term shifts in dominance patterns. Decreased abundance of dominant species in the oiled compared to unoiled sediments resulted in significantly higher evenness of benthic assemblages within the first 11 weeks of the experiment.     

The Geochemistry of Supraglacial Streams of Canada Glacier,Taylor Valley (Antarctica), and their Evolution into Proglacial Waters

We have investigated the geochemistry of supraglacial streams on the Canada Glacier, Taylor Valley, Antarctica during the 2001–2002 austral summer. Canada Glacier supraglacial streams represent the link between primary precipitation (i.e. glacier snow) and proglacial Lake Hoare. Canada Glacier supraglacial stream geochemistry is intermediate between glacier snow and proglacial stream geochemistry with average concentrations of 49.1 μeq L⁻¹ Ca2+, 19.9 μeq L⁻¹ SO₄²⁻, and 34.3 μeq L⁻¹ HCO₃⁻. Predominant west to east winds lead to a redistribution of readily soluble salts onto the glacier surface, which is reflected in the geochemistry of the supraglacial streams. Western Canada Glacier supraglacial streams have average SO₄²⁻:HCO₃⁻ equivalent ratios of 1.0, while eastern supraglacial streams average 0.5, suggesting more sulfate salts reach and dissolve in the western supraglacial streams. A graph of HCO₃⁻ versus Ca2+ for western and eastern supraglacial streams had slopes of 0.87 and 0.72, respectively with R2 values of 0.84 and 0.83. Low concentrations of reactive silicate (> 10 μmol L⁻¹) in the supraglacial streams suggested that little to no silicate weathering occurred on the glacier surface with the exception of cryoconite holes (1000 μmol L⁻¹). Therefore, the major geochemical weathering process occurring in the supraglacial streams is believed to be calcite dissolution. Proglacial stream, Anderson Creek, contains higher concentrations of major ions than supraglacial streams containing 5 times the Ca²⁺ and 10 times the SO₄²⁻. Canada Glacier proglacial streams also contain higher concentrations (16.6–30.6 μeq L⁻¹) of reactive silicate than supraglacial streams. This suggests that the controls on glacier meltwater geochemistry switch from calcite and gypsum dissolution to both salt dissolution and silicate mineral weathering as the glacier meltwater evolves. Our chemical mass balance calculations indicate that of the total discharge into Lake Hoare, the final recipient of Canada Glacier meltwater, 81.9% is from direct glacier runoff and 19.1% is from proglacial Andersen Creek. Although during a typical, low melt ablation season Andersen Creek contributes over 40% of the water added to Lake Hoare, its overall chemical importance is diluted by the direct inputs from Canada Glacier during high flow years. Decadal warming events, such as the 2001–2002 austral summer produce supraglacial streams that are a major source of water to Lake Hoare.     

Investigating Late Holocene Climate Variability in Central Mexico using Carbon Isotope Ratios in Organic Materials and Oxygen Isotope Ratios from Diatom Silica within Lacustrine Sediments

Previous studies have shown that moisture availability in the central highlands of Mexico during the last 3000 years has been highly variable, but evidence remains ambiguous since the climatic signal is partially masked by that of human activity. Here we use two isotope systems to provide evidence for environmental change in Laguna Zacapu, Michoacán covering this time period. Carbon isotope ratios of organic material suggest that there have been fluctuations in the carbon pool related to plant productivity, possibly as a result of changes in the abundance of aquatic plants around the lake margins. The drainage basin and lake have been managed intensively during the 20th century. Lake level apparently fell during the early part of the century, but has been artificially controlled since the 1950s. The oxygen isotope ratios from diatom silica should provide the more unambiguous climate signal, although we show that the interpretation of the diatom oxygen isotope record is far from straight forward. Zacapu is a spring-fed, non-evaporating system and changes in δ¹⁸O_diatom are likely to be a function of changes in δ¹⁸O of precipitation, due to either temperature and salinity variation in the Gulf of Mexico (associated with changes in the Bond cycles from the North Atlantic or the Loop current from the Carribean) and/or changing moisture contributions from different air masses (Gulf of Mexico vs. Pacific). Changes in the Gulf of Mexico are possibly at a resolution comparable to the periodicity we see in the δ¹⁸O_diatom record, although without better dating the comparison is speculative.     

The pattern and influence of low dissolved oxygen in the Patuxent River,a seasonally hypoxic estuary

Increased nutrient loadings have resulted in low dissolved oxygen (DO) concentrations in bottom waters of the Patuxent River, a tributary of Chesapeake Bay. We synthesize existing and newly collected data to examine spatial and temporal variation in bottom DO, the prevalence of hypoxia-induced mortality of fishes, the tolerance of Patuxent River biota to low DO, and the influence of bottom DO on the vertical distributions and spatial overlap of larval fish and fish eggs with their gelatinous predators and zooplankton prey. We use this information, as well as output from watershed-quality and water-quality models, to configure a spatially-explicit individual-based model to predict how changing land use within the Patuxent watershed may affect survival of early life stages of summer breeding fishes through its effect on DO. Bottom waters in much of the mesohaline Patuxent River are below 50% DO saturation during summer. The system is characterized by high spatial and temporal variation in DO concentrations, and the current severity and extent of hypoxia are sufficient to alter distributions of organisms and trophic interactions in the river. Gelatinous zooplankton are among the most tolerant species of hypoxia, while several of the ecologically and economically important finfish are among the most sensitive. This variation in DO tolerances may make the Patuxent River, and similar estuaries, particularly susceptible to hypoxia-induced alterations in food web dynamics. Model simulations consistently predict high mortality of planktonic bay anchovy eggs (Anchoa mitchilli) under current DO, and increasing survival of fish eggs with increasing DO. Changes in land use that reduce nutrient loadings may either increase or decrease predation mortality of larval fish depending on the baseline DO conditions at any point in space and time. A precautionary approach towards fisheries and ecosystem management would recommend reducing nutrients to levels at which low oxygen effects on estuarine habitat are reduced and, where possible, eliminated.     

Space Operation and Performance of Doped Germanium Photo-Conducting Detectors in the Far Infrared: Experience from the ISO LWS

The performance of the ten doped germaniumphotoconducting detectors on the Infrared SpaceObservatory Long Wavelength Spectrometer is discussed. This instrument was designed to make spectroscopicmeasurements of astronomical sources in the wavelengthrange from 43 to 198 m. It employed^* a combination of stressed and unstressed Ge:Ga detectorsand one Ge:Be detector coupled to Infrared Labs JF-4integrating amplifiers. The performance of thedetectors was affected by the ionising radiation inthe space environment. The Noise Equivalent Power ofthe detectors increased by a factor of 4 compared tothat measured during ground testing. We show thatthis was the result of reducing the operating bias,and therefore the responsivity, of the detectors andusing shorter integration ramps to alleviate theeffects of the ionising radiation impacts. ^ast ISO exhausted its helium supply on 8 April 1998.     

Gated communities in England: historical perspectives and current developments

It is important to analyse the growth of gated communities and the drivers for their supply and demand, within the context specific to each country’s history. This article uses findings from recent studies of gated communities in England, together with historical material, to explore their typology. It considers the changing social, economic and political conditions which may lead to the emergence of defended collective housing, together with the history of property relations and the concept of public/private land within the English context.     

Determination of melt influence on divalent element partitioning between anorthite and CMAS melts

We propose a theory for crystal-melt trace element partitioning that considers the energetic consequences of crystal-lattice strain, of multi-component major-element silicate liquid mixing, and of trace-element activity coefficients in melts. We demonstrate application of the theory using newly determined partition coefficients for Ca, Mg, Sr, and Ba between pure anorthite and seven CMAS liquid compositions at 1330 °C and 1 atm. By selecting a range of melt compositions in equilibrium with a common crystal composition at equal liquidus temperature and pressure, we have isolated the contribution of melt composition to divalent trace element partitioning in this simple system. The partitioning data are fit to Onuma curves with parameterizations that can be thermodynamically rationalized in terms of the melt major element activity product (a_Al2O3)(a_SiO2)² and lattice strain theory modeling. Residuals between observed partition coefficients and the lattice strain plus major oxide melt activity model are then attributed to non-ideality of trace constituents in the liquids. The activity coefficients of the trace species in the melt are found to vary systematically with composition. Accounting for the major and trace element thermodynamics in the melt allows a good fit in which the parameters of the crystal-lattice strain model are independent of melt composition.     

The contribution of Very Long Baseline Interferometry to ITRF2005

The contribution of the International VLBI Service for Geodesy and Astrometry (IVS) to the ITRF2005 (International Terrestrial Reference Frame 2005) has been computed by the IVS Analysis Coordinator’s office at the Geodetic Institute of the University of Bonn, Germany. For this purpose the IVS Analysis Centres (ACs) provided datum-free normal equation matrices in Solution INdependent EXchange (SINEX) format for each 24 h observing session to be combined on a session-by-session basis by a stacking procedure. In this process, common sets of parameters, transformed to identical reference epochs and a prioris, and especially representative relative weights have been taken into account for each session. In order to assess the quality of the combined IVS files, Earth orientation parameters (EOPs) and scaling factors have been derived from the combined normal equation matrices. The agreement of the EOPs of the combined normal equation matrices with those of the individual ACs in terms of weighted root mean square (WRMS) is in the range of 50–60 μas for the two polar motion components and about 3 μs for UT1−UTC. External comparisons with International GNSS Serive (IGS) polar motion components is at the level of 130–170 μas and 21 μs/day for length of day (LOD). The scale of the terrestrial reference frame realized through the IVS SINEX files agrees with ITRF2000 at the level of 0.2 ppb.