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721.
Hydrous partial melting in the sheeted dike complex at fast spreading ridges: experimental and natural observations 总被引:5,自引:1,他引:4
Lydéric France Juergen Koepke Benoit Ildefonse Sarah B. Cichy Fabien Deschamps 《Contributions to Mineralogy and Petrology》2010,160(5):683-704
In ophiolites and in present-day oceanic crust formed at fast spreading ridges, oceanic plagiogranites are commonly observed
at, or close to the base of the sheeted dike complex. They can be produced either by differentiation of mafic melts, or by
hydrous partial melting of the hydrothermally altered sheeted dikes. In addition, the hydrothermally altered base of the sheeted
dike complex, which is often infiltrated by plagiogranitic veins, is usually recrystallized into granoblastic dikes that are
commonly interpreted as a result of prograde granulitic metamorphism. To test the anatectic origin of oceanic plagiogranites,
we performed melting experiments on a natural hydrothermally altered dike, under conditions that match those prevailing at
the base of the sheeted dike complex. All generated melts are water saturated, transitional between tholeiitic and calc-alkaline,
and match the compositions of oceanic plagiogranites observed close to the base of the sheeted dike complex. Newly crystallized
clinopyroxene and plagioclase have compositions that are characteristic of the same minerals in granoblastic dikes. Published
silicic melt compositions obtained in classical MORB fractionation experiments also broadly match the compositions of oceanic
plagiogranites; however, the compositions of the coexisting experimental minerals significantly deviate from those of the
granoblastic dikes. Our results demonstrate that hydrous partial melting is a likely common process in the root zone of the
sheeted dike complex, starting at temperatures exceeding 850°C. The newly formed melt can either crystallize to form oceanic
plagiogranites or may be recycled within the melt lens resulting in hybridized and contaminated MORB melts. It represents
the main MORB crustal contamination process. The residue after the partial melting event is represented by the granoblastic
dikes. Our results support a model with a dynamic melt lens that has the potential to trigger hydrous partial melting reactions
in the previously hydrothermally altered sheeted dikes. A new thermometer using the Al content of clinopyroxene is also elaborated. 相似文献
722.
Sarah K. Appleby Martin R. Gillespie Colin M. Graham Richard W. Hinton Grahame J. H. Oliver Nigel M. Kelly 《Contributions to Mineralogy and Petrology》2010,160(1):115-132
In contrast to I-type granites, which commonly comprise infracrustal and supracrustal sources, S-type granites typically incorporate
predominantly supracrustal sources. The initial aim of this study was to identify the sources of three Scottish Caledonian
(~460 Ma) S-type granites (Kemnay, Cove and Nigg Bay) by conducting oxygen, U–Pb and Hf isotope analyses in zircon in order
to characterise one potential end-member magma involved in the genesis of the voluminous late Caledonian (~430–400 Ma) I-type
granites. Field, whole-rock geochemical and isotopic data are consistent with the generation of the S-type granites by melting
their Dalradian Supergroup country rocks. While Hf isotope compositions of magmatic zircon, U–Pb data of inherited zircons,
and high mean zircon δ18O values of 9.0 ± 2.7‰ (2SD) and 9.8 ± 2.0‰ for the Kemnay and Cove granites support this model, the Nigg Bay Granite contains
zircons with much lower δ18O values (6.8 ± 2.1‰), similar to those found in Scottish I-type granites. This suggests that the Nigg Bay Granite contains
low-δ18O material representing either altered supracrustal material, or more likely, an infracrustal source component with mantle-like
δ18O. Mixing trends in plots of δ18O vs. εHf for S-type granite zircons indicate involvement of at least two sources in all three granites. This pilot study
of Scottish Caledonian S-type granites demonstrates that, while field and whole-rock geochemical data are consistent with
local melting of only supracrustal sources, the oxygen isotopic record stored in zircon reveals a much more complex petrogenetic
evolution involving two or more magma sources. 相似文献
723.
The extent to which leaf water D-enrichment (transpiration) and soil water D-enrichment (evaporation) affect the D/H ratio of plant leaf waxes remains a contentious issue, with important implications for paleohydrologic reconstructions. In this study we measure δD values of precipitation (δDp), groundwater (δDgw), plant xylem water (δDxw) and leaf water (δDlw) to understand their impact on the δD values of plant leaf wax n-alkanes (δDwax) in an arid ecosystem. Our survey includes multiple species at four sites across an aridity gradient (80-30% relative humidity) in southern California.We find that many species take up groundwater or precipitation without significant fractionation. D-enriched soil water is a minor source even in species known to perform and utilize waters from hydraulic lift, such as Larrea tridentata (+10‰). Measurements of leaf water isotopic composition demonstrate that transpiration is an important mechanism for D-enrichment of leaf waters (+74 ± 20‰, 1σ), resulting in the smallest net fractionation yet reported between source water and leaf waxes (L. tridentata −41‰; multi-species mean value is −94 ± 21‰, 1σ). We find little change in leaf water D-enrichment or net fractionation across the climatic gradient sampled by our study, suggesting that a net fractionation of ca. −90‰ may be appropriate for paleohydrologic reconstructions in semi-arid to arid environments. Large interspecies offsets in net fractionations (1σ = 21‰) are potentially troublesome, given the observed floristic diversity and the likelihood of species assemblage changes with climate shifts. 相似文献
724.
New 40Ar/39Ar thermochronology results and thermal modeling support the hypothesis of Hollister et al. (2004), that reheating of the mid-Cretaceous Ecstall pluton by intrusion of the Coast Mountains Batholith (CMB) was responsible for spatially variable remagnetization of the Ecstall pluton. 40Ar/39Ar ages from hornblende and biotite from 12 locations along the Skeena River across the northern part of the Ecstall pluton decrease with proximity to the Quottoon plutonic complex, the nearest member of the CMB to the Ecstall pluton. The oldest 40Ar/39Ar ages are found farthest from the Quottoon plutonic complex, and are 90 ± 3 Ma for hornblende, and 77.9 ± 1.2 Ma for biotite. The youngest 40Ar/39Ar ages are found closest to the Quottoon plutonic complex, and are 51.6 ± 1.2 Ma for hornblende, and 45.3 ± 1.7 Ma for biotite. No obvious relationship between grain size and age is seen in the Ecstall pluton biotites. Spatial trends in 40Ar/39Ar ages are consistent with model results for reheating by a thermal wall at the location of the Quottoon plutonic complex. Although no unique solution is suggested, our results indicate that the most appropriate thermal history for the Ecstall pluton includes both reheating and northeast side up tilting of the Ecstall pluton associated with intrusion of the Quottoon plutonic complex. Estimates of northward translation from shallow paleomagnetic inclinations in the western part of the Ecstall pluton are reduced to ∼3000 km, consistent with the Baja-BC hypothesis, when northeast side up tilting is accounted for. 相似文献
725.
We present a study of water vapour in the Venus troposphere obtained by modelling specific water vapour absorption bands within the 1.18 μm window. We compare the results with the normal technique of obtaining the abundance by matching the peak of the 1.18 μm window. Ground-based infrared imaging spectroscopy of the night side of Venus was obtained with the Anglo-Australian Telescope and IRIS2 instrument with a spectral resolving power of R ~ 2400. The spectra have been fitted with modelled spectra simulated using the radiative transfer model VSTAR. We find a best fit abundance of 31 ppmv (?6 +9 ppmv), which is in agreement with recent results by Bézard et al. (Bézard, B., Fedorova, A., Bertaux, J.-L., Rodin, A., Korablev, O. [2011]. Icarus, 216, 173–183) using VEX/SPICAV (R ~ 1700) and contrary to prior results by Bézard et al. (Bézard, B., de Bergh, C., Crisp, D., Maillard, J.P. [1990]. Nature, 345, 508–511) of 44 ppmv (±9 ppmv) using VEX/VIRTIS-M (R ~ 200) data analyses. Comparison studies are made between water vapour abundances determined from the peak of the 1.18 μm window and abundances determined from different water vapour absorption features within the near infrared window. We find that water vapour abundances determined over the peak of the 1. 18 μm window results in plots with less scatter than those of the individual water vapour features and that analyses conducted over some individual water vapour features are more sensitive to variation in water vapour than those over the peak of the 1. 18 μm window. No evidence for horizontal spatial variations across the night side of the disk are found within the limits of our data with the exception of a possible small decrease in water vapour from the equator to the north pole. We present spectral ratios that show water vapour absorption from within the lowest 4 km of the Venus atmosphere only, and discuss the possible existence of a decreasing water vapour concentration towards the surface. 相似文献
726.
The HIV/AIDS epidemic remains a major public health issue across the globe, and it is of particular concern in sub-Saharan Africa. Utilization of sexual and reproductive health (SRH) services can significantly impact HIV prevention, transmission, and treatment. SRH service utilization may be determined by individual characteristics, such as education and economic status, but also by the location and accessibility of health care facilities. Using population-based survey data, this study applies exploratory spatial analysis techniques to examine spatial patterns of SRH service utilization among rural married women in southern Mozambique. Clustering among those using services is found as are spatial associations, indicating significant spatial variability in the utilization of health services. The findings provide valuable insights for current and future health care program planning and configuration. 相似文献
727.
Tidal asymmetry is a key factor in the geomorphology of many coastal lagoons. Whilst tidal asymmetry in semi-diurnal tidal regimes has been extensively studied, its occurrence in mixed tidal regimes is less well understood, and has a number of unique causes and characteristics. Tidal phase duration analysis and least squares harmonic analysis have been used to study the temporal and spatial nature of asymmetry in both offshore and coastal lagoon tides at the Murray Mouth in south-eastern Australia. GIS analysis of bathymetric survey data has been used to study the roles of lagoon bathymetry on tidal distortion.Tidal asymmetry in the Murray Mouth coastal lagoon results from frequency relationships between major astronomical driving tides as well as bathymetry-induced tidal transformations. The frequency difference between the K1 and S2 tides produces an important 6-monthly ebb/flood-dominant asymmetry cycle in the incoming oceanic tides, whilst phase relationships between the K1 and K2 tides contribute to persistent asymmetry. The use of standard relationships between the M2 and M4 tides as asymmetry indicators is shown to be invalid for this mixed tidal regime. In this shallow, microtidal system, the impacts of bathymetry on tidal asymmetry within the lagoon are profound, with inlet and channel configurations identified as the most important controlling factors.The results of this study may inform the strategic management of tidal inlets in mixed tidal regimes, such as the Murray Mouth, that are subject to intermittent or long-term constriction. 相似文献
728.
Thomas A. M. Pugh James Ryder A. Robert MacKenzie Sarah J. Moller James D. Lee Carole Helfter Eiko Nemitz Douglas Lowe C. Nicholas Hewitt 《Journal of Atmospheric Chemistry》2010,65(2-3):89-110
Measurements of atmospheric composition have been made over a remote rainforest landscape. A box model has previously been demonstrated to model the observed daytime chemistry well. However the box model is unable to explain the nocturnal measurements of relatively high [NO] and [O3], but relatively low observed [NO2]. It is shown that a one-dimensional (1-D) column model with simple O3-NOx chemistry and a simple representation of vertical transport is able to explain the observed nocturnal concentrations and predict the likely vertical profiles of these species in the nocturnal boundary layer (NBL). Concentrations of tracers carried over from the end of the night can affect the atmospheric chemistry of the following day. To ascertain the anomaly introduced by using the box model to represent the NBL, vertically-averaged NBL concentrations at the end of the night are compared between the 1-D model and the box model. It is found that, under low to medium [NOx] conditions (NOx?<?1 ppbv), a simple parametrisation can be used to modify the box model deposition velocity of ozone, in order to achieve good agreement between the box and 1-D models for these end-of-night concentrations of NOx and O3. This parametrisation would could also be used in global climate-chemistry models with limited vertical resolution near the surface. Box-model results for the following day differ substantially if this effective nocturnal deposition velocity for ozone is implemented; for instance, there is a 9% increase in the following days peak ozone concentration. However under medium to high [NOx] conditions (NOx > 1 ppbv), the effect on the chemistry due to the vertical distribution of the species means no box model can adequately represent chemistry in the NBL without modifying reaction rate coefficients. 相似文献
729.
Jeffrey L. Collett Jr. Pierre Herckes Sarah Youngster Taehyoung Lee 《Atmospheric Research》2008,87(3-4):232
Considerable effort has been put into characterizing the ionic composition of fogs and clouds over the past twenty-five years. Recently it has become evident that clouds and fogs often contain large concentrations of organic material as well. Here we report findings from a series of studies examining the organic composition of radiation fogs in central California. Organic compounds in these fogs comprise a major fraction of total solute mass, with total organic carbon sometimes reaching levels of several tens of mg/L. This organic matter is comprised of a wide variety of compounds, ranging from low molecular weight organic acids to high molecular weight compounds with molecular masses approaching several hundred to a thousand g/mole. The most abundant individual compounds are typically formic acid, acetic acid, and formaldehyde. High concentrations are also observed of some dicarboxylic acids (e.g., oxalate) and dicarbonyls (e.g., glyoxal and methylglyoxal) and of levoglucosan, an anhydrosugar characteristically emitted by biomass combustion. Many other compounds have been identified in fog water by GC/MS, including long chain n-alkanoic acids, n-alkanes, PAH, and others, although these compounds typically comprise a total of only a few percent of fog TOC. Measurements of fog scavenging of organic and elemental carbon reveal preferential scavenging of organic carbon. Tracking of individual organic compounds utilized as source type markers suggests the fogs differentially scavenge carbonaceous particles from different source types, with more active processing of wood smoke than vehicle exhaust. Observations of high deposition velocities of fog-borne organic carbon, in excess of 1 cm/s, indicate that fogs in the region represent an important mechanism for cleansing the atmosphere of pollution. 相似文献
730.
Bernard Bourdon Sarah Bureau Morten B. Andersen Eric Pili Amélie Hubert 《Chemical Geology》2009,258(3-4):275-287
This study investigates U-series, Sr isotopes, major and trace elements in a chalk aquifer system located in Eastern France. Soil and rock samples were collected along depth profiles down to 45 m in four localities as an attempt to investigate the weathering processes in the soil, the unsaturated zone and the saturated zone of the aquifer. Interstitial water was extracted from soils and rocks by a centrifugation technique. U-series offer a powerful tool to calculate weathering rates because the relative mobility of the U- and Th-isotopes can be precisely measured and it does not require the determination of a reference state as in other approaches. As expected, the data show very large mobile element depletion in the soil with large 230Th excess relative to 238U, while the rocks show more limited but not insignificant mobile element depletion. The U-series data have been used to constrain weathering rates based on a 1-D reactive transport model. Weathering rates in the near surface are about 10–100 times faster than at depth. However, when integrated over the depth of the cores, including the unsaturated and the saturated zones, this underground weathering represents more than 30% of the total weathering flux, assuming congruent dissolution of carbonates. The (234U/238U) ratios in interstitial water are consistent with solid samples showing 234U depletion near the surface and an excess 234U at depth. A leaching experiment performed on chalk shows that the excess 234U in natural waters percolating through carbonate rocks results both from preferential 234U leaching and direct recoil in the interstitial water. A new approach was used to derive the recoil ejection factor based on BET measurements and the fractal dimension of chalk surface. Consideration of preferential leaching and recoil allows a more accurate modeling of weathering rates. 相似文献